Lattice Distortions Drive Electron–Hole Correlation within Micrometer-Size Lead-Iodide Perovskite Crystals
Source abstract
Abstract
We use ultrafast transient absorption microscopy to map the effect of structural disorder on the photophysical properties within a micrometer-sized crystal of methylammonium lead iodide (CH 3 NH 3 PbI 3 ) perovskite. We reveal a spatial inhomogeneity of the structural and photophysical behavior on the submicrometer scale induced by a local distortion of the crystal lattice, which affects the electron–hole correlation over the hundreds of nanometers length scale.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Perovskite Materials and Applications · Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Center for Nano Science and Technology @ Polimi, Istituto Italiano di Tecnologia, via Giovanni Pascoli 70/3, 20133 Milan, Italy
IFN-CNR, Dipartimento di Fisica, Politecnico di Milano, Piazza L. da Vinci, 32, 20133 Milano, Italy
Institute of Crystallography, National Research Council, via Amendola 122/O, Bari 70126, Italy
Funding
H2020 European Research Council · Seventh Framework Programme
References (38)
Show source-provided references
1. 10.1126/science.aah555710.1126/science.aah5557 ↗
2. 10.1038/nenergy.2015.1710.1038/nenergy.2015.17 ↗
3. 10.1126/science.124398210.1126/science.1243982 ↗
4. 10.1038/nnano.2015.9010.1038/nnano.2015.90 ↗
5. 10.1021/acs.accounts.5b0041110.1021/acs.accounts.5b00411 ↗
6. 10.1021/ja506624n10.1021/ja506624n ↗
7. 10.1038/nmat427110.1038/nmat4271 ↗
8. 10.1126/science.aad181810.1126/science.aad1818 ↗
9. 10.1038/nnano.2014.14910.1038/nnano.2014.149 ↗
10. 10.1038/ncomms640410.1038/ncomms6404 ↗
11. 10.1038/nphoton.2015.8210.1038/nphoton.2015.82 ↗
12. 10.1039/c3ee43619e10.1039/c3ee43619e ↗
13. 10.1038/nature1234010.1038/nature12340 ↗
14. 10.1038/nature1250910.1038/nature12509 ↗
15. 10.1021/jz501877h10.1021/jz501877h ↗
16. 10.1038/nphoton.2015.15110.1038/nphoton.2015.151 ↗
17. 10.1021/ja511198f10.1021/ja511198f ↗
18. 10.1126/science.aaa533310.1126/science.aaa5333 ↗
19. 10.1021/acs.jpclett.5b0132710.1021/acs.jpclett.5b01327 ↗
20. 10.1002/advs.20150013610.1002/advs.201500136 ↗
21. 10.1039/C5SC02542G10.1039/C5SC02542G ↗
22. 10.1038/nphys335710.1038/nphys3357 ↗
23. 10.1038/ncomms458610.1038/ncomms4586 ↗
24. 10.1021/acs.jpclett.5b0140610.1021/acs.jpclett.5b01406 ↗
25. 10.1126/science.aaa272510.1126/science.aaa2725 ↗
26. 10.1002/adma.20090438710.1002/adma.200904387 ↗
27. 10.1021/jz200389b10.1021/jz200389b ↗
28. 10.1039/C5EE02925B10.1039/C5EE02925B ↗
29. 10.1021/jz402589q10.1021/jz402589q ↗
30. 10.1002/lpor.20150018110.1002/lpor.201500181 ↗
31. 10.1021/jz500528510.1021/jz5005285 ↗
32. 10.1038/ncomms942010.1038/ncomms9420 ↗
33. 10.1038/nphoton.2014.17110.1038/nphoton.2014.171 ↗
34. 10.1039/C5CP01973G10.1039/C5CP01973G ↗
35. 10.1021/acs.jpcc.5b0014810.1021/acs.jpcc.5b00148 ↗
36. 10.1103/PhysRevLett.114.11660110.1103/PhysRevLett.114.116601 ↗
37. 10.1103/PhysRevB.71.20530610.1103/PhysRevB.71.205306 ↗
38. 10.1038/ncomms1168310.1038/ncomms11683 ↗