journal article·2025-12

High-strength cellulose fibers based on magnetic field-induced alignment of Fe3O4 nanoparticles

Bin Li, Jun Song, Jicheng Shan, Xuerong Wang, Haijing Zhu, Xiaosheng Qian, Chunzu Cheng, Ting Li

Cellulose· Volume 32· Issue 18
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advanced Cellulose Research Studies · Natural Fiber Reinforced Composites · Polysaccharides and Plant Cell Walls

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (68)

Show source-provided references
1. Andersson Trojer M, Olsson C, Bengtsson J, Hedlund A, Bordes R (2019) Directed self-assembly of silica nanoparticles in ionic liquid-spun cellulose fibers. J Colloid Interface Sci 553:167–176. https://doi.org/10.1016/J.JCIS.2019.05.08410.1016/J.JCIS.2019.05.084 ↗
2. Araújo-Custódio S, Gomez-Florit M, Tomás AR et al (2019) Injectable and magnetic responsive hydrogels with bioinspired ordered structures. ACS Biomater Sci Eng 5:1392–1404. https://doi.org/10.1021/acsbiomaterials.8b0117910.1021/acsbiomaterials.8b01179 ↗
3. Bai ZX, Jia K, Liu CC et al (2021) A solvent regulated hydrogen bond crosslinking strategy to prepare robust hydrogel paint for oil/water separation. Adv Funct Mater. https://doi.org/10.1002/adfm.20210470110.1002/adfm.202104701 ↗
4. Chan HT, Do YY, Huang PL, Chien PL, Chan TS, Liu RS, Huang CY, Yang SY, Horng HE (2006) Preparation and properties of bio-compatible magnetic Fe3O4 nanoparticles. J Magn Magn Mater 304(1):e415. https://doi.org/10.1016/j.jmmm.2006.01.12610.1016/j.jmmm.2006.01.126 ↗
5. Chang C, Zhang L, Zhou J, Kennedy JF (2010) Structure and properties of hydrogels prepared from cellulose in NaOH/urea aqueous solutions. Carbohydr Polym 82(1):122–127. https://doi.org/10.1016/j.carbpol.2010.04.03310.1016/j.carbpol.2010.04.033 ↗
6. Chen X, Zhang Z, Chen B et al (2021) Crystalline grain refinement toughened isotactic polypropylene through rapid quenching of stretched melt. Polymer 216:123435. https://doi.org/10.1016/j.polymer.2021.12343510.1016/j.polymer.2021.123435 ↗
7. Chen B, Yuan M, Ma R et al (2022) High performance piezoelectric polymer film with aligned electroactive phase nanofibrils achieved by melt stretching of slightly crosslinked poly(vinylidene fluoride) for sensor applications. Chem Eng J 433:134475. https://doi.org/10.1016/j.cej.2021.13447510.1016/j.cej.2021.134475 ↗
8. Cui HC, Li DC, Zhang ZL (2015) Preparation and characterization of Fe3O4 magnetic nanoparticles modified by perfluoropolyether carboxylic acid surfactant. Mater Lett 143:38–40. https://doi.org/10.1016/j.matlet.2014.12.03710.1016/j.matlet.2014.12.037 ↗
9. Dhar P, Tarafder D, Kumar A, Katiyar V (2015) Effect of cellulose nanocrystal polymorphs on mechanical, barrier and thermal properties of poly(lactic acid) based bionanocomposites. RSC Adv 5:60426–60440. https://doi.org/10.1039/c5ra06840a10.1039/c5ra06840a ↗
10. Dhar P, Kumar A, Katiyar V (2016) Magnetic cellulose nanocrystal based anisotropic polylactic acid nanocomposite films: influence on electrical, magnetic, thermal, and mechanical properties. ACS Appl Mater Interfaces 8:18393–18409. https://doi.org/10.1021/acsami.6b0282810.1021/acsami.6b02828 ↗
11. Eichhorn SJ, Etale A, Wang J et al (2022) Current international research into cellulose as a functional nanomaterial for advanced applications. J Mater Sci 57:5697–5767. https://doi.org/10.1007/s10853-022-06903-810.1007/s10853-022-06903-8 ↗
12. French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896. https://doi.org/10.1007/s10570-013-0030-410.1007/s10570-013-0030-4 ↗
13. Gao Q, Wang J, Liu J et al (2021) High mechanical performance based on the alignment of cellulose nanocrystal/chitosan composite filaments through continuous coaxial wet spinning. Cellulose 28:7995–8008. https://doi.org/10.1007/s10570-021-04009-z10.1007/s10570-021-04009-z ↗
14. Gawali SL, Barick KC, Shetake NG et al (2019) PH-labile magnetic nanocarriers for intracellular drug delivery to tumor cells. ACS Omega 4:11728–11736. https://doi.org/10.1021/acsomega.9b0106210.1021/acsomega.9b01062 ↗
15. Guo Z, Li Y, Pan S, Xu J (2015) Fabrication of Fe3O4@cyclodextrin magnetic composite for the high-efficient removal of Eu(III). J Mol Liq 206:272–277. https://doi.org/10.1016/j.molliq.2015.02.03410.1016/j.molliq.2015.02.034 ↗
16. Hu T, Xie H, Xiao J et al (2010) Design, synthesis, and characterization of a combined main-chain/side-chain liquid-crystalline polymer based on ethyl cellulose. Cellulose 17:547–558. https://doi.org/10.1007/s10570-009-9392-z10.1007/s10570-009-9392-z ↗
17. Huang Y, Fang Y, Chen L et al (2017) One-step synthesis of size-tunable gold nanoparticles immobilized on chitin nanofibrils via green pathway and their potential applications. Chem Eng J 315:573–582. https://doi.org/10.1016/j.cej.2017.01.06510.1016/j.cej.2017.01.065 ↗
18. Jain V, Biesinger MC, Linford MR (2018) The Gaussian-Lorentzian sum, product, and convolution (Voigt) functions in the context of peak fitting X-ray photoelectron spectroscopy (XPS) narrow scans. Appl Surf Sci 447:548–553. https://doi.org/10.1016/j.apsusc.2018.03.19010.1016/j.apsusc.2018.03.190 ↗
19. Jiang Z, Tang Y, Rieger J et al (2010) Two lamellar to fibrillar transitions in the tensile deformation of high-density polyethylene. Macromolecules 43:4727–4732. https://doi.org/10.1021/ma100303d10.1021/ma100303d ↗
20. Jiang G, Huang W, Li L et al (2012) Structure and properties of regenerated cellulose fibers from different technology processes. Carbohydr Polym 87:2012–2018. https://doi.org/10.1016/j.carbpol.2011.10.02210.1016/j.carbpol.2011.10.022 ↗
21. Kang J, Hu C, Liu X et al (2024) One-pot synthesis of magnetic nanocellulose/Fe3O4 hybrids using FeCl3 as cellulose hydrolytic medium and Fe3O4 precursor. ACS Sustain Chem Eng 12:5917–5926. https://doi.org/10.1021/acssuschemeng.3c0858210.1021/acssuschemeng.3c08582 ↗
22. Kassie BB, Daget TM, Tassew DF (2024) Synthesis, functionalization, and commercial application of cellulose-based nanomaterials. Int J Biol Macromol 278:134990. https://doi.org/10.1016/j.ijbiomac.2024.13499010.1016/j.ijbiomac.2024.134990 ↗
23. Kim T, Kim D, Park Y (2022) Recent progress in regenerated fibers for “green” textile products. J Clean Prod 376:134226. https://doi.org/10.1016/j.jclepro.2022.13422610.1016/j.jclepro.2022.134226 ↗
24. Kimura F, Kimura T, Tamura M et al (2005) Magnetic alignment of the chiral nematic phase of a cellulose microfibril suspension. Langmuir 21:2034–2037. https://doi.org/10.1021/la047572810.1021/la0475728 ↗
25. Lee WJ, Clancy AJ, Kontturi E et al (2016) Strong and stiff: high-performance cellulose nanocrystal/poly(vinyl alcohol) composite fibers. ACS Appl Mater Interfaces 8:31500–31504. https://doi.org/10.1021/acsami.6b1157810.1021/acsami.6b11578 ↗
26. Li J, Song J, Cao L et al (2023) Preparation and UV resistance of biphenyl liquid crystal modified cellulose film. J Funct Polym 36:7. https://doi.org/10.14133/j.cnki.1008-9357.2022092600110.14133/j.cnki.1008-9357.20220926001 ↗
27. Men Y, Rieger J, Lindner P et al (2005) Structural changes and chain radius of gyration in cold-drawn polyethylene after annealing: small- and wide-angle X-ray scattering and small-angle neutron scattering studies. J Phys Chem B 109:16650–16657. https://doi.org/10.1021/jp052723g10.1021/jp052723g ↗
28. Michud A, Tanttu M, Asaadi S et al (2016) Ioncell-F: ionic liquid-based cellulosic textile fibers as an alternative to viscose and Lyocell. Text Res J 86:543–552. https://doi.org/10.1177/004051751559177410.1177/0040517515591774 ↗
29. Mu J, Chen B, Guo Z et al (2011) Highly dispersed Fe3O4 nanosheets on one-dimensional carbon nanofibers: synthesis, formation mechanism, and electrochemical performance as supercapacitor electrode materials. Nanoscale 3:5034–5040. https://doi.org/10.1039/C1NR10972C10.1039/C1NR10972C ↗
30. Nishiyama Y, Sugiyama J, Chanzy H, Langan P (2003) Crystal structure and hydrogen bonding system in cellulose Iα from synchrotron X-ray and neutron fiber diffraction. J Am Chem Soc 125:14300–14306. https://doi.org/10.1021/ja037055w10.1021/ja037055w ↗
31. Northolt MG, Boerstoel H, Maatman H et al (2001) The structure and properties of cellulose fibres spun from an anisotropic phosphoric acid solution. Polymer 42:8249–8264. https://doi.org/10.1016/S0032-3861(01)00211-710.1016/S0032-3861(01)00211-7 ↗
32. Nypelö T (2022) Magnetic cellulose: does extending cellulose versatility with magnetic functionality facilitate its use in devices? J Mater Chem C 10:805–818. https://doi.org/10.1039/D1TC02105B10.1039/D1TC02105B ↗
33. O’Brien J (1984) Process for preparing high strength cellulosic fibers. US4464323A
34. Picken SJ, van der Zwaag S, Northolt MG (1992) Molecular and macroscopic orientational order in aramid solutions: a model to explain the influence of some spinning parameters on the modulus of aramid yarns. Polymer 33:2998–3006. https://doi.org/10.1016/0032-3861(92)90087-D10.1016/0032-3861(92)90087-D ↗
35. Poletto M, Junior HLO, Zattera AJ (2014) Native cellulose: structure, characterization and thermal properties. Materials 7:6105–6119. https://doi.org/10.3390/ma709610510.3390/ma7096105 ↗
36. Qian H, Jeppe M, Liyun Y et al (2018) Highly anisotropic glassy polystyrenes are flexible. ACS Macro Lett 7:1126–1130. https://doi.org/10.1021/acsmacrolett.8b0048510.1021/acsmacrolett.8b00485 ↗
37. Qin J, Asempah I, Laurent S, Fornara A, Muller RN, Muhammed M (2009) Injectable superparamagnetic ferrogels for controlled release of hydrophobic drugs. Adv Mater 21(13):1354–1357. https://doi.org/10.1002/adma.20080076410.1002/adma.200800764 ↗
38. Robbes A-S, Cousin F, Meneau F et al (2011) Nanocomposite materials with controlled anisotropic reinforcement triggered by magnetic self-assembly. Macromolecules 44:8858–8865. https://doi.org/10.1021/ma201096u10.1021/ma201096u ↗
39. Sayyed AJ, Mohite LV, Deshmukh NA, Pinjari DV (2019) Structural characterization of cellulose pulp in aqueous NMMO solution under the process conditions of lyocell slurry. Carbohydr Polym 206:220–228. https://doi.org/10.1016/j.carbpol.2018.11.00410.1016/j.carbpol.2018.11.004 ↗
40. Shen H, Sun T, Zhou J (2023) Recent progress in regenerated cellulose fibers by wet spinning. Macromol Mater Eng 308(10):2300089. https://doi.org/10.1002/mame.20230008910.1002/mame.202300089 ↗
41. Song J, Liu F, Cheng B et al (2018a) Phase transition and rheological behaviors of a novel cellulose solution with 4-(ω-(methylimidazole)alkyloxy)-4′-(cyano)-biphenyls as a mesogenic unit. Cellulose 25:941–951. https://doi.org/10.1007/s10570-017-1616-z10.1007/s10570-017-1616-z ↗
42. Song P, Dai J, Chen G et al (2018b) Bioinspired design of strong, tough, and thermally stable polymeric materials via nanoconfinement. ACS Nano 12:9266–9278. https://doi.org/10.1021/acsnano.8b0400210.1021/acsnano.8b04002 ↗
43. Song J, Wang L, Shan J et al (2024) Effect of methylene lengths of 4-(ω-(methylimidazole)-alkyloxy)-4’-(cyano)-biphenyl on cellulose liquid crystal solution and its phase transition properties. Cellulose 31:6141–6153. https://doi.org/10.1007/s10570-024-05993-810.1007/s10570-024-05993-8 ↗
44. Sun N, Swatloski RP, Maxim ML et al (2008) Magnetite-embedded cellulose fibers prepared from ionic liquid. J Mater Chem A 18:283–290. https://doi.org/10.1039/B713194A10.1039/B713194A ↗
45. Tang F, Li YZ, Huang JW et al (2021) An environmentally friendly and economical strategy to cyclically produce cellulose nanocrystals with high thermal stability and high yield. Green Chem 23:4866–4872. https://doi.org/10.1039/d1gc01392k10.1039/d1gc01392k ↗
46. Tang XQ, Chang XL, Zhang SQ et al (2023) Self-assembly and magnetorheological performance of Fe3O4-based liquid-crystalline composites. J Mol Liq. https://doi.org/10.1016/j.molliq.2022.12092710.1016/j.molliq.2022.120927 ↗
47. Tian C, Fu SY, Habibi Y, Lucia LA (2014) Polymerization topochemistry of cellulose nanocrystals: a function of surface dehydration control. Langmuir 30:14670–14679. https://doi.org/10.1021/la503990u10.1021/la503990u ↗
48. Wang Y, Luo QP, Peng BH, Pei CH (2008) A novel thermotropic liquid crystalline - benzoylated bacterial cellulose. Carbohydr Polym 74:875–879. https://doi.org/10.1016/j.carbpol.2008.05.00710.1016/j.carbpol.2008.05.007 ↗
49. Wang ZH, Wu YP, Luo PY, Wang Z, Wu Y, Luo P, Tian Y, Lin Y, Guo Q (2018) Poly (sodium p-styrene sulfonate) modified Fe3O4 nanoparticles as effective additives in water-based drilling fluids. J Pet Sci Eng 165:786–797. https://doi.org/10.1016/j.petrol.2018.03.00110.1016/j.petrol.2018.03.001 ↗
50. Wang K, Chang X, Diao Y et al (2024) Fabrication of liquid crystal Fe3O4 composites and their magnetorheological properties. Polym Adv Technol. https://doi.org/10.1002/pat.634910.1002/pat.6349 ↗
51. Wang XR, Song J, Shan JC et al (2025) Liquid crystal properties of cellulose/4-(ω-(methylimidazole)hexyloxy)-4’-(cyano)-biphenyl/amine-modified graphene solution and its high-strength fiber. Cellulose 32:2195–2208. https://doi.org/10.1007/s10570-025-06398-x10.1007/s10570-025-06398-x ↗
52. Wu T, Huang ZX, Wang DZ, Qu JP (2019) Effect of continuous elongational flow on structure and properties of short glass fiber reinforced polyamide 6 composites. Adv Ind Eng Polym Res 2:93–101. https://doi.org/10.1016/j.aiepr.2019.06.00310.1016/j.aiepr.2019.06.003 ↗
53. Xu F, Inci F, Mullick O et al (2012) Release of magnetic nanoparticles from cell-encapsulating biodegradable nanobiomaterials. ACS Nano 6:6640–6649. https://doi.org/10.1021/nn300902w10.1021/nn300902w ↗
54. Xue T, Tang J, Liu C et al (2025) Ultra-strong skin-core polymer aerogel fibers via wet-freeze spinning. Matter. https://doi.org/10.1016/j.matt.2025.10215510.1016/j.matt.2025.102155 ↗
55. Yamamoto A, Uddin AJ, Gotoh Y et al (2011) Dry jet-wet spinning of bagasse/N-methylmorpholine-N-oxide hydrate solution and physical properties of lyocell fibres. J Appl Polym Sci 119:3152–3161. https://doi.org/10.1002/app.3315110.1002/app.33151 ↗
56. Yan M, Liu W, Fang Z et al (2024) Ultrastrong nanocomposites reinforced by cellulose nanofiber and lignosulfonate via swelling-assisted prestretching orientation. ACS Sustain Chem Eng 12:5753–5765. https://doi.org/10.1021/acssuschemeng.3c0647210.1021/acssuschemeng.3c06472 ↗
57. Yang W, Tian H, Liao J et al (2020) Flexible and strong Fe3O4/cellulose composite film as magnetic and UV sensor. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2019.14509210.1016/j.apsusc.2019.145092 ↗
58. Yang H, Zhang P, Zheng Q et al (2024) Synergistically active Fe3O4 magnetic and EDTA modified cellulose cotton fabric using chemical method and their effective pollutants removal ability from wastewater. Int J Biol Macromol 274:132996. https://doi.org/10.1016/j.ijbiomac.2024.13299610.1016/j.ijbiomac.2024.132996 ↗
59. Yoonessi M, Gaier JR, Peck JA, Meador MA (2015) Controlled direction of electrical and mechanical properties in nickel tethered graphene polyimide nanocomposites using magnetic field. Carbon 84:375–382. https://doi.org/10.1016/j.carbon.2014.12.03310.1016/j.carbon.2014.12.033 ↗
60. Yuan M, Ma R, Ye Q, Bai X, Li H, Yan F, Liu C, Ren Y, Wang Z (2023) Melt-stretched poly(vinylidene fluoride)/zinc oxide nanocomposite films with enhanced piezoelectricity by stress concentrations in piezoelectric domains for wearable electronics. Chem Eng J 455:140771. https://doi.org/10.1016/j.cej.2022.14077110.1016/j.cej.2022.140771 ↗
61. Zeng B, Byrne N (2021) The effect of drying method on the porosity of regenerated cellulose fibres. Cellulose 28:8333–8342. https://doi.org/10.1007/s10570-021-04068-210.1007/s10570-021-04068-2 ↗
62. Zhang Y, Yang B, Zhang X, Xu L, Tao L, Li S, Wei Y (2012) A magnetic self-healing hydrogel. Chem Commun 48(74):9305–9307. https://doi.org/10.1039/C2CC34745H10.1039/C2CC34745H ↗
63. Zhang J, Tominaga K, Yamagishi N, Gotoh Y (2020) Comparison of regenerated cellulose fibers spun from ionic liquid solutions with lyocell fiber. J Fiber Sci Technol 76:257–266. https://doi.org/10.2115/fiberst.2020-002910.2115/fiberst.2020-0029 ↗
64. Zhang Y (2021) Preparation and properties of cellulose@Fe3O4 composites. Doctoral dissertation, University of Science and Technology of China
65. Zheng Y-h, Cheng Y, Bao F, Wang Y-s (2006) Synthesis and magnetic properties of Fe3O4 nanoparticles. Mater Res Bull 41:525–529. https://doi.org/10.1016/j.materresbull.2005.09.01510.1016/j.materresbull.2005.09.015 ↗
66. Zhou J, Li R, Liu S, Li Q, Zhang L, Guan J (2009) Structure and magnetic properties of regenerated cellulose/Fe3O4 nanocomposite films. J Appl Polym Sci 111(5):2477–2484. https://doi.org/10.1002/app.2923610.1002/app.29236 ↗
67. Zhou L, Kang Z, Nie Y, Li L (2021) Fabrication of regenerated cellulose fibers with good strength and biocompatibility from green spinning process of ionic liquid. Macromol Mater Eng 306:2000741. https://doi.org/10.1002/mame.20200074110.1002/mame.202000741 ↗
68. Zoppe JO, Grosset L, Seppälä J (2013) Liquid crystalline thermosets based on anisotropic phases of cellulose nanocrystals. Cellulose 20:2569–2582. https://doi.org/10.1007/s10570-013-0008-210.1007/s10570-013-0008-2 ↗