journal article·2006-02

Variations in the chemical composition within pine (Pinus sylvestris) trunks determined by diffuse reflectance infrared spectroscopy and chemometrics

Timo-Jaakko Toivanen, Raimo Alén

Cellulose· Volume 13· Issue 1
Publisher page

Abstract

The feasibility of using DRIFT (diffuse reflectance infrared Fourier transform) spectroscopy combined with a multivariate analysis method (a PLS (projection to latent structures), regression) for predicting the distribution of the main organic constituents (cellulose, glucomannan, xylan, lignin, and extractives) within the Scots pine (Pinus sylvestris) stemwood was examined. PLS calibrations were carried out to establish a mathematical correlation between the data sets of conventional (“wet-chemistry-based”) wood analysis and the DRIFT spectra of the corresponding wood samples. Based on this approach, different surface maps on variations in the content of the main organic constituents within the stemwood matrix were shown.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Spectroscopy and Chemometric Analyses · Wood Treatment and Properties · Fermentation and Sensory Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (27)

Show source-provided references
1. Agarwal U.P., Weinstock I.A., Atalla R.H. (2003), FT-Raman spectroscopy for direct measurement of lignin concentrations in kraft pulps. Tappi J. 1(2):22–26
2. Alén R. (2000) Structure and chemical composition of wood. In: Stenius P., (eds), Forest Products Chemistry. Fapet, Helsinki, Finland, pp. 11–57
3. Argyropoulos D.S., (eds), (1999) Advances in Lignocellulosics Characterization. Tappi Press, Atlanta, USA, pp. 382
4. Back E.L., Allen L.H., (eds), (2000) Pitch Control, Wood Resin and Deresination. Tappi Press, Atlanta, USA, pp. 392
5. Broderick G., Paris J., Valade J.L. (1995) A composite representation of pulp quality, Chemom. Intell. Lab. Syst. 29(1):19–2810.1016/0169-7439(95)80076-L ↗
6. Browning B.L. (1967) Methods of Wood Chemistry, Volumes I and II. John Wiley & Sons, New York, USA, pp. 882
7. Faix O., Böttcher J.H. (1993) Determination of phenolic hydroxyl group contents in milled wood lignins by FTIR spectroscopy applying partial least-squares (PLS) and principal components regression (PCR). Holzforschung 47(1):45–4910.1515/hfsg.1993.47.1.45 ↗
8. Friese M.A., Banerjee S. (1995) FT-IR spectroscopy. In: Conners T.E., Banerjee S., (eds), Surface Analysis of Paper. CRC Press, Boca Raton, USA, pp. 119–141
9. Geladi P., MacDougall D., Martens H. (1985) Linearization and scatter-correction for near-infrared reflectance spectra of meat. Appl. Spectrosc. 39(3):491–50010.1366/0003702854248656 ↗
10. Goldschmid O. (1971) Ultraviolet spectra. In: Sarkanen K.V., Ludwig C.H., (eds), Lignins - Occurrence, Formation, Structure and Reactions. John Wiley & Sons, New York, USA, pp. 241–266
11. Jääskeläinen A.-S., Nuopponen M., Axelsson P., Tenhunen M., Löijä M., Vuorinen T. (2003) Determination of lignin distribution in pulps by FTIR ATR spectroscopy. J. Pulp Pap. Sci. 29(10):328–331
12. Kotilainen R., Toivanen T.-J., Alén R.J. (2000) FTIR monitoring of chemical changes in softwood during heating. J. Wood Chem. Technol. 20(3):307–32010.1080/02773810009349638 ↗
13. Lennholm H., Wallbäcks T., Iversen A. (1995) 13C-CP/MAS-NMR-spectroscopic study on the effect of laboratory kraft cooking on cellulose structure. Nordic Pulp Pap. Res. J. 10(1):46–5010.3183/npprj-1995-10-01-p046-050 ↗
14. Lin S.Y., Dence C.W., (eds), (1992) Methods in Lignin Chemistry. Springer, Heidelberg Germany, pp. 578
15. Malkavaara P., 2000. Chemometric Adaptations in Wood Processing Chemistry, Doctoral Thesis. University of Jyväskylä, Laboratory of Applied Chemistry, Jyväskylä, Finland, 2000, 56 p
16. Malkavaara P., Alén R. (1998) A spectroscopic method for determining lignin content of softwood and hardwood kraft pulps. Chemom. Intell. Lab. Syst. 44(1–2):287–29210.1016/S0169-7439(98)00068-9 ↗
17. Martens H., Naes T. (1989) Multivariate Calibration. John Wiley & Sons, Chichester, USA, pp. 345
18. Michell A.J. 1994. Vibrational spectroscopy – a rapid means of estimating plantation pulp wood quality? Appita J. 47(1): 29–37
19. Olsson R., Tomani M., Karlsson M., Josefsson T., Sjöberg K., Björklund C. (1995) Multivariate characterization of chemical and physical descriptors in pulp using NIRR. Tappi J. 78(10):158–166
20. Ona T., Sonoda T., Ohshima J., Yokota S., Yoshizawa N. (2003) A rapid quantitative method to asses Eucalyptus wood properties for kraft pulp production by FT-Raman Spectroscopy. J. Pulp Pap. Sci., 29(1):6–10
21. Pope J.M. (1995) Near-infrared spectroscopy of wood products. In: Conners T.E., Banerjee S., (eds), Surface Analysis of Paper. CRC Press, Boca Raton, USA, pp. 142–151
22. Ristolainen M., Alén R., Malkavaara P., Pere J. (2002) Reflectance FTIR microspectroscopy for studying effect of xylan removal on unbleached and bleached birch kraft pulps. Holzforschung, 56(5):513–52110.1515/HF.2002.079 ↗
23. Schimleck L., Wright P., Michell A., Wallis A. (1997) Near-infrared spectra and chemical composition of E. globules and E. nitens plantation woods. Appita J. 50(1):40–46
24. Sjöström E., (1993) Wood Chemistry, Fundamentals and Applications. Academic Press, San Diego, USA, pp. 63–67
25. Sjöström E., Alén R., (eds), (1999) Analytical Methods in Wood Chemistry, Pulping, and Papermaking. Springer, Heidelberg, German, pp. 316
26. Wallbäcks L., Edlund U., Nordén B., Berglund I. (1991) Multivariate characterization of pulp using solid-state carbon-13 NMR, FTIR, and NIR. Tappi J. 74(10):201–206
27. Zakis G.F. (1994) Functional Analysis of Lignins and Their Derivatives. Tappi Press, Atlanta, USA, pp. 94