journal article·2026-06-21

Architected Carbon Nanotube Macrostructure–Interleaved UHMWPE Composites for Impact and Ballistic Protection

Mamta Rani, Manoj Sehrawat, Sushant Sharma, Sony Bharadwaj, Navin Kumar, Abhijit Majumdar, Bhanu Pratap Singh

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Abstract

ABSTRACT Insufficient adhesion between the fiber and matrix leading to fiber slippage within ultra‐high molecular weight polyethylene (UHMWPE) composites often undermines their impact performance. The effectiveness of pristine and amine‐modified carbon nanotube (CNT) films in improving mechanical properties of UHMWPE composites under various loading conditions is examined in this study. The results show improvements in tensile strength (over 15%), puncture resistance (over 45%), and dynamic impact energy absorption (over 70%) in UHMWPE composites, led by amine‐functionalized CNT buckypaper (BPA) and floating catalyst chemical vapor deposition (FC‐CVD) derived CNT sheets (SHA). This improved performance is attributed to increased interlaminar bonding facilitated by the amine groups on the CNT surface. Weight analysis revealed that SHA interleaved composites achieved a superior 67.6% increase in dynamic impact energy absorption compared to 6.6% for BPA composites, indicating substantial performance gains with minimal weight increase. Further 8% reduction in back face signature (BFS) with SHA incorporation was confirmed by ballistic testing, highlighting the substantial potential of functionalized CNT sheets for enhancing the impact resistance of lightweight UHMWPE composites in ballistic applications.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Fiber-reinforced polymer composites · Polymer crystallization and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Advanced Carbon Products and Metrology, CSIR‐National Physical Laboratory New Delhi India

Academy of Scientific and Innovative Research (AcSIR) Ghaziabad India

Department of Aerospace Engineering School of Engineering, RMIT University Melbourne Victoria Australia

Department of Material Science and Engineering Hanyang University Ansan Republic of Korea

Department of Mechanical Engineering Indian Institute of Technology Rupnagar India

Department of Textile and Fibre Engineering Indian Institute of Technology Delhi New Delhi India

References (58)

Show source-provided references
1. Natarajan V. D. · 2021 · 5510.1016/B978-0-12-821984-3.00010-3 ↗
2. Advances in Polymer/Inorganic Nanocomposite Fabrics for Lightweight and High‐Strength Armor and Ballistic‐Proof Materials10.1016/j.cej.2024.152422 ↗
4. Anti‐Ballistic Properties of Hybrid UHMWPE Fiber‐Reinforced Composite Armour10.1016/j.compscitech.2024.110941 ↗
5. Impact Response and Energy Absorption Mechanisms of UHMWPE Fabric and Composites in Ballistic Applications: A Comprehensive Review10.1016/j.compositesa.2024.108314 ↗
6. Carbon Nanotube‐Based Soft Body Armor: Advancements, Integration Strategies, and Future Prospects10.1016/j.diamond.2024.111446 ↗
7. Catechol and Epoxy Functionalized Ultrahigh Molecular Weight Polyethylene (UHMWPE) Fibers With Improved Surface Activity and Interfacial Adhesion10.1016/j.compscitech.2015.03.017 ↗
8. A Study of the Influence of Controlled Corona Treatment on UHMWPE Fibres in Reinforced Vinylester Composites10.1002/pi.1372 ↗
9. Radiation‐Induced Oxidation of Ultra‐High Molecular Weight Polyethylene (UHMWPE) Powder by Gamma Rays and Electron Beams: A Clear Dependence of Dose Rate10.1016/j.radphyschem.2015.06.012 ↗
10. Relationship Between Surface Properties and Adhesion for Etched Ultra‐High‐Molecular‐Weight Polyethylene Fibers10.1016/0266-3538(93)90131-Y ↗
11. Effects of Electron Beam Irradiation on Structure and Properties of Ultra‐High Molecular Weight Polyethylene Fiber10.1177/1528083717690612 ↗
12. The Effect of the Oxygen‐Plasma Treatment of UHMWPE Fiber on the Transverse Properties of UHMWPE‐Fiber/Vinylester Composites10.1016/S0266-3538(98)00093-1 ↗
13. Surface Modification of UHMWPE Fibers by Ozone Treatment and UV Grafting for Adhesion Improvement10.1080/00218464.2016.1229603 ↗
14. Synergistic Effect of MWCNTs Functionalization on Interfacial and Mechanical Properties of Multi‐Scale UHMWPE Fibre Reinforced Epoxy Composites10.1016/j.compscitech.2016.07.026 ↗
15. Mechanical Properties and Failure of Etched UHMW‐PE Fibres10.1007/BF00351246 ↗
16. Interfacial Shear Strength Characterization of GMA‐Grafted UHMWPE Fiber/Epoxy/Nano Clay Hybrid Nanocomposite Materials10.1039/C6RA05027A ↗
17. Surface‐Conductive UHMWPE Fibres via in Situ Reduction and Deposition of Graphene Oxide10.1016/j.matdes.2018.03.069 ↗
18. Augmenting the Mechanical Performance of Three‐Dimensional Woven Composites by the Synergistic Effect of Fabric Architecture and Interfacial Interaction of Carbon Nanotubes10.1002/pc.27944 ↗
19. Ballistic Resistance Capacity of Carbon Nanotubes10.1088/0957-4484/18/47/475701 ↗
20. Enhanced Interfacial Adhesion of CF/PEEK‐Titanium Hybrid Laminates via Introducing Micro‐Nano Layers With Multi‐Walled Carbon Nanotube Networks10.1016/j.compscitech.2022.109418 ↗
21. Role of Carbon Nanotubes in the Ballistic Properties of Boron Carbide/Carbon Nanotube/Ultrahigh Molecular Weight Polyethylene Composite Armor10.1016/j.ceramint.2019.10.129 ↗
22. Flexural and Shear Properties of CFRP Laminates Reinforced With Functionalized Multiwalled CNTs
23. Excellent Mechanical Properties of Long Multiwalled Carbon Nanotube Bridged Kevlar Fabric10.1016/j.carbon.2018.05.017 ↗
24. Enhanced Mode I Fracture Toughness of UHMWPE Fabric/Thermoplastic Laminates With Combined Surface Treatments of Polydopamine and Functionalized Carbon Nanotubes10.1016/j.compositesb.2019.107450 ↗
25. Interlaminar Properties of GFRP Laminates Toughened by CNTs Buckypaper Interlayer10.1016/j.compstruct.2018.10.002 ↗
26. Mechanical Properties of CFRP Composites With CNT Film Interlayer Under Different Strain Rates
27. Impact and Post‐Impact Properties of Multiscale Carbon Fiber Composites Interleaved With Carbon Nanotube Sheets10.1016/j.compositesb.2019.107711 ↗
28. Using Ultra‐Thin Interlaminar Carbon Nanotube Sheets to Enhance the Mechanical and Electrical Properties of Carbon Fiber Reinforced Polymer Composites10.1016/j.compositesb.2021.108842 ↗
29. Improved Static and Dynamic Mechanical Properties of Multiscale Bucky Paper Interleaved Kevlar Fiber Composites10.1016/j.carbon.2019.06.055 ↗
30. Ballistic Impact Performance of Ultra‐High Molecular Weight Polyethylene With Multiphase Shear Thickening Fluids Impregnation and Hybrid Configuration10.1002/pc.70439 ↗
31. Study on the Enhancement Mechanism of Ballistic Properties of Shear Thickening Fluid Impregnated Aramid Fabric Composite Plates10.1002/pc.28201 ↗
32. Mode I Interlaminar Fracture Toughness of Thin‐Ply Laminates With CNT Webs at the Crack Interface10.1016/j.compstruct.2019.111178 ↗
33. Enhancing the Fracture Toughness of Hierarchical Composites Through Amino–Functionalised Carbon Nanotube Webs10.1016/j.compositesb.2019.02.001 ↗
34. Growth of Carbon Nanotubes on Carbon Fibre Substrates to Produce Hybrid/Phenolic Composites With Improved Mechanical Properties10.1016/j.compscitech.2008.02.020 ↗
35. Effect of Length of Carbon Nanotubes on Electromagnetic Interference Shielding and Mechanical Properties of Their Reinforced Epoxy Composites10.1007/s11051-013-2161-9 ↗
36. Tailoring the Physical Characteristics of Buckypaper via Controlling the Surfactant Concentration10.1016/j.surfin.2023.102713 ↗
37. One Step Fabrication of Aligned Carbon Nanotube Sheet via FC‐CVD Technique10.1155/2022/8318217 ↗
38. Stab/Puncture Resistance Performance of Needle Punched Nonwoven Fabrics: Effects of Filament Reinforcement and Thermal Bonding10.1007/s12221-022-3968-8 ↗
39. High Strain Rate Testing of Hybrid TPMS Structures10.1007/s40430-024-05002-w ↗
40. An Attempt to Predict Transparent Armor Ballistic Performance Through Quasi‐Static Punch Shear Test10.1007/s11340-024-01123-4 ↗
41. Carbon Film Produced From Microwave‐Driven Methane Pyrolysis10.1016/j.cartre.2023.100283 ↗
42. Using XPS and FTIR Spectroscopies to Investigate Polyamide 11 Degradation on Aging Flexible Risers10.1016/j.polymdegradstab.2021.109787 ↗
43. Aerosol Based Synthesis of Highly Conducting Carbon Nanotube Macro Assemblies by Novel Mist Assisted Precursor Purging System10.1016/j.jallcom.2022.166634 ↗
44. Nano‐Welded Carbon Nanotube Sponges for Efficient Oil Spill Remediation10.1016/j.jclepro.2024.142841 ↗
45. Combination Mechanism of the Ternary Composite Based on Fe3O4‐Chitosan‐Graphene Oxide Prepared by Solvothermal Method10.1016/j.ijbiomac.2023.123337 ↗
46. Enhancing Structural Integrity and Adsorption Performance of Carbon Nanotube Buckypaper for Water Remediation Through Innovative Densification Strategy10.1016/j.surfin.2024.104636 ↗
47. Electric Field‐Assisted Alignment of Carbon Nanotubes in the Interlayers of CFRP Composites to Enhance the Properties10.1016/j.compositesa.2024.108706 ↗
48. Understanding Mode I Interlaminar Toughening of Unidirectional CFRP Laminates Interleaved With Aligned Ultrathin CNT Fiber Veils: Thickness and Orientation Effects10.1016/j.compositesb.2023.110578 ↗
49. Polymer Nanocomposites for High‐Velocity Impact Applications‐A Review10.1016/j.coco.2019.11.013 ↗
50. Plasma Actuating Modified Multiwalled Carbon Nanotubes (MWCNTs) to Strengthen Interface of MWCNTs/Polylactic Acid Composites by Constructing Interlaminar Stress‐Transfer Bridge10.1016/j.polymertesting.2023.108261 ↗
51. Mechanical Properties and Structural Health Monitoring Performance of Carbon Nanotube‐Modified FRP Composites: A Review10.1515/ntrev-2021-0104 ↗
52. Amino‐Functionalized Carbon Nanotubes for Binding to Polymers and Biological Systems10.1021/cm048357f ↗
53. Strengthening Sandwich Composites by Laminating Ultra‐Thin Oriented Carbon Nanotube Sheets at the Skin/Core Interface10.1016/j.compositesb.2024.111496 ↗
54. Synergistic Effect of CNT Films Impregnated With CNT Modified Epoxy Solution Towards Boosted Interfacial Bonding and Functional Properties of the Composites10.1016/j.compositesa.2018.04.011 ↗
55. An Experimental Investigation on Low‐Velocity Impact Response and Compression After Impact of a Stochastic, Discontinuous Prepreg Tape Composite10.1016/j.compositesa.2021.106524 ↗
56. Drop‐Weight Impact Behaviour of Stitched Composites: Influence of Stitching Pattern and Stitching Space10.1016/j.compositesa.2023.107612 ↗
57. Energy Dissipation and High‐Strain Rate Dynamic Response of E‐Glass Fiber Composites With Anchored Carbon Nanotubes10.1016/j.compositesb.2015.10.028 ↗
58. M.Shazly D.Nathenson andV.Prakash “Modeling of High‐Strain‐Rate Deformation Fracture and Impact Behavior of Advanced Gas Turbine Engine Materials at Low and Elevated Temperatures ” 2003.