journal article·2026-06-19

Optimal Preparation and Interface Strengthening of High‐Temperature Resistance Sizing Agents for Carbon Fiber Reinforced Poly(Ether Ether Ketone) Composites: A Mini‐Review

Zheng Liu, Xiaojuan He

Publisher page

Abstract

ABSTRACT Carbon fiber reinforced polyetheretherketone (CF/PEEK) composites have attracted significant attention in recent years for use in large aviation structures, driven by the growth of green and sustainable aviation. These composites offer high toughness, fatigue resistance, long‐term stability, fast molding, and recyclability. However, the smooth surface and low surface energy of CF hinder effective impregnation by viscous PEEK resin, leading to poor interlaminar shear strength (ILSS). Based on the principle of like dissolves like, designing polymers with tailored molecular structures as sizing agents for CFs is an environmentally friendly and engineering‐feasible approach to improve interfacial bonding. However, conventional sizing agents, such as epoxy, polyurethane, and polyamide, degrade under the high temperatures and pressures of CF/PEEK processing, resulting in carbonization and weak fiber–matrix interfaces. This paper reviews factors affecting interfacial performance, common characterization and simulation methods, and focuses on advances in molecular design and synthesis of polyaryletherketone‐based and polyimide‐based sizing agents. It also discusses progress in multifunctional organic–inorganic hybrid sizing agents, compares lab‐scale fiber sizing with continuous industrial processes, and analyzes key factors influencing composite performance. Finally, the high‐performance and heat‐resistant sizing agents are promoted for the development and engineering validation, thereby accelerating the adoption of CF/PEEK composites in next‐generation green aircraft and power systems.
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Research context

OpenAlex topics: Fiber-reinforced polymer composites · Epoxy Resin Curing Processes · Mechanical Behavior of Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Taihang Laboratory Chengdu Sichuan People's Republic of China

Funding

China Association for Science and Technology

References (91)

Show source-provided references
1. Additive Manufacturing and Characterization of High Temperature Thermoplastic Blends for Potential Aerospace Applications10.1016/j.compscitech.2022.109839 ↗
2. Impact Performance Comparison of Carbon Fiber Reinforced Polyamide 6 and Fast‐Curing Epoxy Composites Manufactured by Resin Transfer Molding10.1002/pc.29317 ↗
3. Construction of “Rigid‐And‐Flexible” Interphase by Waterborne Carboxylated Polyimide Sizing Agent for Interfacial Enhancement of Carbon Fiber/Poly Ether Ether Ketone (CF/PEEK) Composites10.1016/j.compositesb.2025.112388 ↗
4. Preparation of CCF/PEEK Filaments Together With Property Evaluation for Additive Manufacturing10.1016/j.compstruct.2021.114975 ↗
5. High‐Content Continuous Carbon Fibers Reinforced PEEK Matrix Composite With Ultra‐High Mechanical and Wear Performance at Elevated Temperature10.1016/j.compstruct.2022.115837 ↗
6. Interfacial Strengthening and Processing of Carbon Fibers Reinforced Poly(Ether‐Ether‐Ketone) Composites: A Mini‐Review10.1002/pc.28289 ↗
7. Sulfur‐Driven Reactive Processing of Multiscale Graphene/Carbon Fiber‐Polyether Ether Ketone (PEEK) Composites With Tailored Crystallinity and Enhanced Mechanical Performance10.1016/j.compositesb.2025.112180 ↗
8. Micro‐Structure and Tensile Property Analyses of 3D Printed Short Carbon Fiber Reinforced PEEK Composites10.1016/j.coco.2023.101655 ↗
9. Full‐Process Multi‐Scale Morphological and Mechanical Analyses of 3D Printed Short Carbon Fiber Reinforced Polyetheretherketone Composites10.1016/j.compscitech.2023.109999 ↗
10. CaO‐Catalyzed Simplified Synthesis of Fully Bio‐Based Self‐Cross‐Linkable MB‐Polyether Ether Ketone Toward Waterborne Carbon Fiber Sizing Agent to Enhance the Interfacial Properties and Solvent‐Resistance of Carbon Fiber/Polyether Ether Ketone Composites10.1002/pc.28815 ↗
11. Synergistic Enhancement of Interfacial Adhesion for CF/PEEK Composites Through Carbene Chemistry and Water‐Based Self‐Catalyzed Cross‐Linkable PENK‐NH2 Sizing Agent10.1002/pc.28129 ↗
12. Optimal Preparation and Inherent Mechanism of Advanced Integrated Structural/Electromagnetic Wave‐Absorbing Polymer‐Based Composites for Aeronautical Applications: A Review10.1002/pc.70121 ↗
13. Intrinsic Mechanism, Preparation and Application of Noise Reduction Polymer‐Based Composites for Aviation Noise: A Mini‐Review10.1016/j.compositesa.2025.109246 ↗
14. Mechanical and Thermal Characterization of Additively Manufactured Carbon/Nylon 12 and Carbon/PEEK Composites10.1007/s10443-025-10363-z ↗
15. Process Parameter‐Mechanical Property Relationships and Influence Mechanism of Advanced CFF/PEEK Thermoplastic Composites10.1002/pc.26801 ↗
16. High‐Performance Carbon Fiber Reinforced Polyether‐Ether‐Ketone Composite Pellets 3D‐Printed via Screw‐Extrusion Additive Manufacturing10.1016/j.compscitech.2023.110362 ↗
17. A Mini‐Review of Ultra‐Low Dielectric Constant Intrinsic Epoxy Resins: Mechanism, Preparation, and Application10.1002/pat.6241 ↗
18. A Review on Optimal Preparation of Multi‐Component Fillers and Fibers With Excellent Wideband Microwave Absorbing Performance Through the Electromagnetic Loss Engineering10.1016/j.jallcom.2025.181352 ↗
19. Effect of Material and Processing Parameters on Fiber Pinning Effect and Resultant Interfacial Bonding Strength of CF/PEEK Bilayer Parts in Overmolding Process10.1016/j.polymertesting.2022.107509 ↗
20. Improved Wave‐Transparent Performances and Enhanced Mechanical Properties for Fluoride‐Containing PBO Precursor Modified Cyanate Ester Resins and Their PBO Fibers/Cyanate Ester Composites10.1016/j.compositesb.2019.107466 ↗
21. Water‐Based PES‐NaPSS Sizing Agent Without Surfactant for Interface Enhancement of CF/PEEK Composites10.1016/j.compscitech.2024.110892 ↗
22. Improving Mechanical Performances at Room and Elevated Temperatures of 3D Printed Polyether‐Ether‐Ketone Composites by Combining Optimal Short Carbon Fiber Content and Annealing Treatment10.1016/j.compositesb.2023.111067 ↗
23. Strength‐Plasticity Synergetic CF/PEEK Composites Obtained by Adjusting Melt Flow Rate10.1016/j.polymer.2024.127186 ↗
24. Bio‐Based Hyperbranched Poly (Aryl Ether Ketone) Sizing Agent to Enhance the Interfacial Property of Carbon Fiber/Poly Ether Ether Ketone Composites
25. Thermally Conductive and Insulating Epoxy Composites by Synchronously Incorporating Si‐Sol Functionalized Glass Fibers and Boron Nitride Fillers10.1007/s10118-020-2391-0 ↗
26. Improving the Comprehensive Properties of PBO Fibres/Cyanate Ester Composites Using a Hyperbranched Fluorine and Epoxy Containing PBO Precursor10.1016/j.compositesa.2021.106596 ↗
27. Enhanced Mechanical and Tribological Properties of Carbon Fiber/PEEK Composites by Hydroxylated Boron Nitride Nanosheets and Polyetherimide Sizing Agents10.1016/j.compscitech.2022.109851 ↗
28. Optimization of PBO Fibers/Cyanate Ester Wave‐Transparent Laminated Composites via Incorporation of a Fluoride‐Containing Linear Interfacial Compatibilizer10.1016/j.compscitech.2021.108838 ↗
29. Low Dielectric Constant and Highly Intrinsic Thermal Conductivity Fluorine‐Containing Epoxy Resins With Ordered Liquid Crystal Structures10.1002/sus2.172 ↗
30. Interfacial Reinforcement of Composites by the Electrostatic Self‐Assembly of Graphene Oxide and NH3 Plasma‐Treated Carbon Fiber10.1016/j.apsusc.2022.152717 ↗
31. High‐Strength Carbon Fiber‐Reinforced Polyether‐Ether‐Ketone Composites With Longer Fiber Retention Length Manufactured via Screw Extrusion‐Based 3D Printing10.1016/j.addma.2024.104200 ↗
32. Strengthening and Toughening Behaviours and Mechanisms of Carbon Fiber Reinforced Polyetheretherketone Composites (CF/PEEK)10.1016/j.coco.2022.101397 ↗
33. Hybrid Polymer Membrane Functionalized PBO Fibers/Cyanate Esters Wave‐Transparent Laminated Composites10.1007/s42765-021-00125-4 ↗
34. Improving the Interfacial Properties of Carbon Fiber/Low Melting Point PAEK Composites by Embellishing of Bio‐Based PAEK Sizing Agent10.1016/j.compscitech.2024.110741 ↗
35. Improved the Surface Properties of Carbon Fiber Through Hyperbranched Polyaryletherketone Sizing10.1002/pc.26510 ↗
36. Direct Electrochemical Grafting of Crystalline PAEK Macromolecule on Carbon Fiber to Enhance the Interfacial Properties of PEEK/CF Composites10.1016/j.compscitech.2022.109262 ↗
37. Effect of Interface Modification on Mechanical Properties and Friction and Wear Properties of Carbon Fiber/Polyetheretherketone Composites
38. Experimental Study on the Mechanical and Thermal Properties of PEEK, CF/PEEK, and GF/PEEK Thin‐Walled Cylinders Under Static Compressive Tests10.1016/j.tws.2025.113032 ↗
39. Synthesis and Characterisation of ASA‐PEEK Composites for Fused Filament Fabrication10.3390/polym14030496 ↗
40. Enhancing Interfacial Solvent Resistance and Mechanical Properties of Carbon Fiber/Polyether Ether Ketone Composites With Water‐Borne Sizing Agents Based on Cross‐Linkable Polyphthalonitrile10.1002/pc.28191 ↗
41. Construction of a Double‐Crosslinked Interphase to Optimize the Interfacial Properties of Carbon Fiber‐Reinforced Polyether Ether Ketone Composites10.1016/j.compositesa.2025.108939 ↗
42. An Investigation of the Influence of Matrix Properties and Fibre‐Matrix Interface Behaviour on the Mechanical Performance of Carbon Fibre‐Reinforced PEKK and PEEK Composites10.1016/j.compositesa.2022.107359 ↗
43. Cyclic (Phenylene Sulfide) Treated Carbon Fiber for Facile Preparation of High Performance PEEK Based Anti‐Wear Composites10.1016/j.matchemphys.2021.125665 ↗
44. Improvement of the Interfacial Properties of CF/PEEK Composites by Introducing Aminated Polyphenylene Sulphide (PPS‐NH2) as a Sizing Agent10.1002/pc.27070 ↗
45. Preparation of CF/PEEK Composites With High Mechanical Performance Using PEEK Derivatives as the Sizing Agent10.1002/marc.202200738 ↗
46. 3D‐Printed High Performance PEEK/CF‐PEEK Polymer Composites‐An Investigation on Microstructural Characteristics and Mechanical Performance10.1177/09544089241284469 ↗
47. Branched Fluorine/Adamantane Interfacial Compatibilizer for PBO Fibers/Cyanate Ester Wave‐Transparent Laminated Composites10.1002/cjoc.202200749 ↗
48. The Synergistic Effects of Modified Carbon Fiber and Multiwalled Carbon Nanotubes on the Tribological Properties of Polyetheretherketone Composites10.1021/acsapm.5c01764 ↗
49. Review on Recycling of Carbon Fibre Reinforced Thermoplastics With a Focus on Polyetheretherketone10.1016/j.compositesa.2024.108236 ↗
50. Preparing Water‐Based Phosphorylated PEEK Sizing Agent for CF/PEEK Interface Enhancement10.1016/j.compscitech.2021.109096 ↗
51. Water‐Based SPEKK Sizing Agent for Improving the Mechanical Properties of CF/PEKK Composites
52. Effect of PEK‐C Water‐Based Sizing Agent on Interface Properties of CCF/PEEK Composites
53. Improved Mechanical Properties of Carbon Fiber Reinforced Polyetheretherketone Composites via Polyethersulfone Sizing Agent10.1002/app.57677 ↗
54. “Lock‐Anchor Chain” Structure Inspired Double‐Crosslinked Interface for Improving the Interfacial Adhesion of CF/PEEK Composites10.1016/j.compositesa.2025.109319 ↗
55. Enhancing the Electromagnetic Shielding and Mechanical Properties of CF/PEEK Composites via Low‐Concentration Fluff and Ni‐Co Alloy Plating10.1016/j.tws.2024.112563 ↗
56. Preparation of Self‐Emulsifying Waterborne Polyamide‐Imide Sizing for Carbon Fiber and Improvement on Mechanical Performances of Carbon Fiber Reinforced Thermoplastic Polymer10.1002/pc.26969 ↗
57. Effect of Polyetherimide Sizing on Surface Properties of Carbon Fiber and Interfacial Strength of Carbon Fiber/Polyetheretherketone Composites10.1002/pc.25876 ↗
58. Enhancing the Interfacial Properties of Carbon Fiber Reinforced Poly (Ether Ether Ketone) Composites: Effect of pH and Molecular Weight of Poly (Amic Acid) Based Sizing Agents10.1016/j.coco.2026.102712 ↗
59. PBO Fibers/Fluorine‐Containing Liquid Crystal Compound Modified Cyanate Ester Wave‐Transparent Laminated Composites With Excellent Mechanical and Flame Retardance Properties10.1016/j.jmst.2023.01.007 ↗
60. Interfacial Enhancement of CF/PEEK Composites by Coating Sulfonated PEEK Sizing Agent10.1016/j.surfin.2023.102652 ↗
61. The Construction of Gradient Load‐Bearing Structure on CF Surface Employing Novel S‐PI Sizing Agent for Interfacial and Mechanical Properties Enhancements of CFRTPs10.1016/j.compositesb.2025.112612 ↗
62. 10.1002/pc.7060310.1002/pc.70603 ↗
63. Tg‐Mismatch Driven Dual Polyamicacid Interphase: A Morphology‐Guided Approach to Strengthen Carbon Fiber/Thermoplastic Interfaces10.1016/j.compositesb.2025.112924 ↗
64. Dual‐Factor Decoupling Strategy: Independent Quantification of Crystallization and Infiltration Effects in PAEK‐Sized CF/PEEK Composites10.1016/j.compositesb.2025.112864 ↗
65. Enhanced Interfacial Bonding of AF/PEEK Composite Based on CNT/Aramid Nanofiber Multiscale Flexible‐Rigid Structure10.1016/j.jmst.2024.02.015 ↗
66. The Impact of Crystalline PEEK Sizing Agent on the Interfacial Crystallization Behavior and Interfacial Properties of Carbon Fiber Reinforced PEEK Composites10.1016/j.compositesb.2025.112307 ↗
67. High Improvement of Interfacial and Mechanical Properties in Reinforced PP Composite by Grafting Polyethyleneimine Modified Carboxylic Multi‐Walled Carbon Nanotubes on Short Carbon Fiber10.1002/app.53462 ↗
68. Environmental Protection and Thermostability Modified Sizing Agent Based on Fluorenyl Poly(Aryl Ether Ketone) for Carbon Fiber/Poly(Ether Ether Ketone) Composite Interfacial Enhancement10.1002/pc.29704 ↗
69. Interfacial Improvement of Carbon Fiber/Poly (Ether Ether Ketone) Composites by Coating Water‐Based Sulfonated Poly (Ether Ether Ketone) and Carbon Nanotube Composite Sizing Agent10.1002/app.57384 ↗
70. A Novel High‐Temperature Resistant Poly(Arylene Ether Ketone) Sizing Agent Containing Graphene Oxide: Achieve Multiscale Interfacial Enhancement in CF/PEEK Composites10.1016/j.compscitech.2025.111363 ↗
71. The PEEK Sizing Agents Modified by Different Dimensions Nanomaterials of MXene and CNTs for Enhancing the Interfacial and Mechanical Properties of Carbon Fiber Composites10.1016/j.colsurfa.2025.137997 ↗
72. Enhanced Mechanical Properties of CF/PEEK and CF/Epoxy Composites With Micro‐/Nano‐Aramid Pulp Interleaves10.1016/j.compositesa.2025.108964 ↗
73. Surface Functionalization of Carbon Fibers With NiCo Nanosheets and Nanoneedles: Multifunctional Interfacial and Electromagnetic Protection Performances of PEEK Composites10.1016/j.compositesb.2025.113212 ↗
74. Improved Interfacial Compatibility of Carbon Fibers/PEEK Laminated Composites via Incorporating Biphenyl‐Branched Poly(Aryl‐Ether‐Nitrile)10.1016/j.jmst.2025.09.003 ↗
75. Interface Strengthening for Carbon Fiber‐Reinforced Poly(Ether‐Ether‐Ketone) Laminated Composites by Introducing Fluorene‐Containing Branched Poly(Aryl‐Ether‐Ketone)10.1002/idm2.12200 ↗
76. Learning From Nature: Flexible Cross‐Linkable Full‐Bio‐Based Waterborne S‐PEEK Sizing Agent for Constructing “Hard‐Soft” Structure on CF Surface Towards Superior Performance of CF/PEEK Composites10.1016/j.porgcoat.2025.109056 ↗
77. Synergistic Cooperation of a Magnolol‐Based Waterborne Cross‐Linkable PEEK Sizing Agent and Click Chemistry to Construct Exceptional Solvent‐Resistance and Interfacial Properties of CF/PEEK Composites10.1016/j.porgcoat.2024.108479 ↗
78. Constructing Regulable Soft‐Rigid Active Interface Structure of CF/PEEK Composites Using Aqueous Sizing Agent With HA Nanomaterial10.1002/pc.29753 ↗
79. Constructing Coordination‐Connected Flexible‐Rigid Structures for the Interfacial Enhancement of CF/Polyetheretherketone Composites10.1016/j.surfin.2024.104964 ↗
80. Effects of Multi‐Walled Carbon Nanotube/Graphene Oxide‐Based Sizing on Interfacial and Tribological Properties of Continuous Carbon Fiber/Poly (Ether Ether Ketone) Composites10.1016/j.matchemphys.2021.125344 ↗
81. A Facile Strategy to Prepare Boron Nitride Grafted Carbon Nanotubes Coating for CF/PEEK Composites Interfacial Enhancement10.1016/j.coco.2023.101770 ↗
82. Construction of Solvent‐Resistant Interphase of CF/PEEK Composites via Introducing Water‐Based Crosslinkable Polyaryl Ether Sizing Agent10.1016/j.compscitech.2022.109530 ↗
83. Effect of Emulsifier on Properties of Thermoplastic Water Dispersible Emulsion Sizing Agent
84. Effect of Sizing Agent Storage Time on Properties of Domestic Carbon Fiber and Its Composite
85. Strong Interface Construction of Carbon Fiber‐Reinforced PEEK Composites: An Efficient Method for Modifying Carbon Fiber With Crystalline PEEK10.1002/marc.202000001 ↗
86. Preparation of Semi‐Aliphatic Polyimide for Organic‐Solvent‐Free Sizing Agent in CF/PEEK Composites10.1016/j.compscitech.2020.108490 ↗
87. Aqueous Sizing Agent Prepared via Ethyl Acetate‐Induced Polyamide Acid Conformation Twist for CFRTPs Enhancement10.1016/j.compscitech.2025.111312 ↗
88. Highly Enhancing the Interfacial Strength of CF/PEEK Composites by Introducing PAIK Onto Diazonium Functionalized Carbon Fibers10.1016/j.apsusc.2020.145400 ↗
89. Synergistic Effect of Hydrogen Bonding and π‐π Stacking in Interface of CF/PEEK Composites10.1016/j.compositesb.2019.04.015 ↗
90. Enhancing CF/PEEK Composites by CF Decoration With Polyimide and Loosely‐Packed CNT Arrays10.1016/j.compositesa.2019.105613 ↗
91. A Chemically Modified MWCNT/PEEK Multiscale Thermoplastic Composites: Forming, Mechanical Performance, and Application10.1002/pc.27679 ↗