Dynamic rheological properties of binary PP/PA and ternary PP/PA/GF blends

Abstract The dynamic rheological behavior was investigated for binary polypropylene (PP) ‐ polyamide‐6 (PA‐6) and ternary PP‐PA‐6‐glass fiber (GF) blends. The observed trends are related to the blend morphology and the partitioning of the GF within the three component blends. The dynamic and shear viscosity results show a good overlap for the PP homopolymer, within the shear rates studied. The addition of PA‐6 and/or glass fibers to the PP causes significant deviations between the two rheological behaviors. This reflects the fibrillation of PA‐6 and the orientation of glass fibers during shear rheometry, which reduce the blends' shear viscosity. The effect of PA‐6 content on dynamic viscosity is less significant than for shear viscosity, owing to the absence of morphological structuring. The addition of PA‐6 to PP increased the principal relaxation time of the binary blends. The addition of GF to these binary blends gave a further increase in the principal relaxation time.