journal article·2021-11

Development and characterization of bentonite-gum arabic composite as novel highly-efficient adsorbent to remove thorium ions from aqueous media

Tawfik A. Saleh, Ahmet Sarı, Mustafa Tuzen

Cellulose· Volume 28· Issue 16
Publisher page

Abstract

Elimination of radioactive ions from wastewater using powerful adsorbents is of great importance for reducing the environmental pollution. Within this context, Bentonite (BNT)-Gum Arabic (GA) composite was developed as a new adsorbent to excellently eliminate Th(IV) ions from aqueous media. The produced composite adsorbent was examined by FTIR and SEM/EDX techniques. The effects of main empirical parameters on the adsorption efficiency were optimized by factorial design analysis. The maximum elimination capacity of BNT-GA was determined as 885.4 mg g−1 at pH 4.5, in 30 min, and 24 °C. Thermodynamic studies showed that Th(IV) adsorption progressed exothermically and the spontaneity of the process was lessened with the increase in temperature. Kinetic findings exposed that the adsorption mechanism fits perfectly with the pseudo-second-order (PSO) model. A 96% part of the adsorbed Th(IV) ions was recovered from the composite adsorbent using 1.0 M HCl. The produced composite revealed remarkable adsorption/desorption efficiency even after 7 cycles. All results show that the prepared BNT-GA compound can be used for the effective exclusion of Th(IV) ions from wastewater due to its advantageous properties such as great elimination capacity, cost-effectiveness, and facile preparation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Radioactive element chemistry and processing · Adsorption and biosorption for pollutant removal · Chemical Synthesis and Characterization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Agency for Toxic Substances and Disease Registry (ATSDR) (1990) Toxicological Profile for Thorium. Department of Health and Human Services, Public Health Service, Atlanta, GA, U.S
2. Anirudha TS, Rijith S, Tharun AR (2010) Adsorptive removal of thorium(IV) from aqueous solutions using poly(methacrylic acid-grafted chitosan/bentonite composite matrix: Process design and equilibrium studies. Colloids and Surfaces A: Physicochem. Eng Aspects 368:13–2210.1016/j.colsurfa.2010.07.005 ↗
3. Anirudhan TS, Suchithra PS, Senan P, Tharun AR (2012) Kinetic and equilibrium profiles of adsorptive recovery of thorium(IV) from aqueous solutions using poly(methacrylic acid) grafted cellulose/bentonite superabsorbent composite. Ind Eng Chem Res 51:4825–483610.1021/ie202538q ↗
4. Atta AM, Akl ZF (2015) Removal of thorium from water using modified magnetite nanoparticles capped with rosin amidoxime. Mater Chem Phys 163:253–26110.1016/j.matchemphys.2015.07.038 ↗
5. Bhainsa KC, D’Souza SF (2009) Thorium biosorption by Aspergillus fumigatus, a filamentous fungal biomass. J Hazard Mater 165:670–67610.1016/j.jhazmat.2008.10.033 ↗
6. Bhalara PD, Punetha D, Balasubramanian K (2015) Kinetic and isotherm analysis for selective thorium(IV) retrieval from aqueous environment using eco-friendly cellulose composite. Int J Environ Sci Technol 12:3095–310610.1007/s13762-014-0682-0 ↗
7. Bradl HB (2004) Adsorption of heavy metal ions on soils and soils constituents. J Colloid Interface Sci 277:1–1810.1016/j.jcis.2004.04.005 ↗
8. Dang TD, Banerjee AN, Tran QT, Roy S (2016) Fast degradation of dyes in water using manganese-oxide-coated diatomite for environmental remediation. J Water Supply Res T 98:50–5810.1016/j.jpcs.2016.06.006 ↗
9. Das D, Vimala R, Das N (2015) Removal of Ag(I) and Zn(II) ions from single and binary solution using sulfonated form of gum arabic-powdered mushroom composite hollow semispheres: Equilibrium, kinetic, thermodynamic and ex-situ studies. Ecological Eng 75:116–12210.1016/j.ecoleng.2014.11.037 ↗
10. Ding H, Luo X, Zhang X, Yang H (2019) Alginate-immobilized Aspergillus niger: characterization and biosorption removal of thorium ions from radioactive wastewater. Colloids Surf A 56:186–19510.1016/j.colsurfa.2018.11.032 ↗
11. Elbedwehy AM, Abou-Elanwar AM, Ezzat AO, Atta AM (2019) Super effective removal of toxic metals water pollutants using multi functionalized polyacrylonitrile and arabic gum grafts. Polymers 11:193810.3390/polym11121938 ↗
12. Elwakeel KZ, El-Sadik HA, Abdel-Razek AS, Beheary MS (2012) Environmental remediation of thorium(IV) from aqueous medium onto Cellulosimicrobium cellulans isolated from radioactive wastewater. Desalin Water Treat 46:1–910.1080/19443994.2012.677405 ↗
13. Freundlich HMF (1906) Über die adsorption in lösungen. Zeitschrift für Physikalische 57A:385–470
14. Gok C, Aytas S (2013) Recovery of thorium by high capacity biopolymeric sorbent. Separ Sci Technol 48:2115–212410.1080/01496395.2013.791992 ↗
15. Ho YS (2006) Review of second-order models for adsorption systems. J Hazard Mater 136:681–68910.1016/j.jhazmat.2005.12.043 ↗
16. Hongxia Z, Xiaoyun W, Honghong L, Tianshe T, Wangsuo W (2016) Adsorption behavior of Th(IV) onto illite: Effect of contact time, pH value, ionic strength, humic acid and temperature. Appl Clay Sci 127–128:35–4310.1016/j.clay.2016.03.038 ↗
17. Humelnicu D, Dinu MV, Dragan ES (2011) Adsorption characteristics of UO22+ and Th4+ ions from simulated radioactive solutions onto chitosan/clinoptilolite sorbents. J Hazard Mater 185:447–45510.1016/j.jhazmat.2010.09.053 ↗
18. Hussein AEM (2011) Successive uranium and thorium adsorption from Egyptian monazite by solvent impregnated foam. J Radioanal Nucl Chem 289:321–32910.1007/s10967-011-1107-x ↗
19. Islam MA, Ali I, Abdul Karim SM, Hossain Firoz MS, Chowdhury AN, Morton DW, Angove MJ (2019) Removal of dye from polluted water using novel nano manganese oxidebased materials. J Water Proc Eng 32:10091110.1016/j.jwpe.2019.100911 ↗
20. Kaynar UH, Ayvacıklı M, Hiçsonmez U, Çam Kaynar S (2015) Removal of thorium (IV) ions from aqueous solution by a novel nanoporous ZnO: Isotherms, kinetic and thermodynamic studies. J Environ Radioact 150:145–15110.1016/j.jenvrad.2015.08.014 ↗
21. Khalili FI, Salameh NH, Shaybe MM (2013) Sorption of Uranium(VI) and Thorium(IV) by Jordanian Bentonite. J Chem 586136:13
22. Khan TA, Imran Ali MN, Kumar A (2017) Removal of Chromium(VI) from aqueous solution using guar gum–nano zinc oxide biocomposite adsorbent. Arab J Chem 10:2388–239810.1016/j.arabjc.2013.08.019 ↗
23. Lagergren S (1898) Zur theorie der sogenannten adsorption geloster stöffe. Kungliga Sevenska Vetenskapsakademiens, Handlingar 24(1898):1
24. Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinium, J Am. Chem Soc 40:1361–140310.1021/ja02242a004 ↗
25. Liu J, Luo M, Yuan Z, Ping A (2013) Synthesis, characterization, and application of titanate nanotubes for Th(IV) adsorption. J Radioanal Nucl Chem 298:1427–143410.1007/s10967-013-2607-7 ↗
26. Ma J, Qi J, Yao C, Cui B, Zhang T, Li D (2012) A novel bentonite-based adsorbent for anionic pollutant removal from water. Chem Eng J 200–202:97–10310.1016/j.cej.2012.06.014 ↗
27. Mckay G, Ho YS, YS, (1999) Pseudo-Second Order Model for Sorption Process. Process Biochem 34:451–46510.1016/S0032-9592(98)00112-5 ↗
28. Mokhtari M, Keshtkar AR (2016) Removal of Th(IV), Ni(II) and Fe(II) from aqueous solutions by a novel PAN-TiO2 nanofiber adsorbent modified with aminopropyltriethoxysilane. Res Chem Intermed 42:4055–407610.1007/s11164-015-2258-0 ↗
29. Oyewo OA, Onyango MS, Wolkersdorfer C (2016) Application of banana peels nanosorbent for the removal of radioactive minerals from real mine water. J Environ Radioact 164:369–37610.1016/j.jenvrad.2016.08.014 ↗
30. Pan N, Wyman I, Guan D, Jin Y, He T, Wang R, Xia C (2013) Removal of Th4+ ions from aqueous solutions by graphene oxide. J Radioanal Nucl Chem 298:1999–200810.1007/s10967-013-2660-2 ↗
31. Raghav S, Kumar D (2018) Adsorption equilibrium, kinetics, and thermodynamic studies of fluoride adsorbed by tetrametallic oxide adsorbent. J Chem Eng Data 63:1682–169710.1021/acs.jced.8b00024 ↗
32. Rouhi Broujeni B, Nilchi A, Azad F (2021) Adsorption modeling and optimization of thorium (IV) ion from aqueous solution using chitosan/TiO2 nanocomposite: Application of artificial neural network and genetic algorithm. Environ. Nanotech. Monit Manage 15:100400
33. Salah BA, Gaber MS, Kandil AT (2019) The removal of uranium and thorium from their aqueous solutions by 8-hydroxyquinoline immobilized bentonite. Minerals 9(626):1–18
34. Saleh TA (2015) Mercury sorption by silica/carbon nanotubes and silica/activated carbon: a comparison study. J Water Supply Res Technol 64(8):892–90310.2166/aqua.2015.050 ↗
35. Saleh TA (2016) Nanocomposite of carbon nanotubes/silica nanoparticles and their use for adsorption of Pb (II): from surface properties to sorption mechanism. Desalin Water Treat 57(23):10730–1074410.1080/19443994.2015.1036784 ↗
36. Saleh TA (2018) Simultaneous adsorptive desulfurization of diesel fuel over bimetallic nanoparticles loaded on activated carbon. J Cleaner Prod 172:2123–2132. https://doi.org/10.1016/j.jclepro.2017.11.20810.1016/j.jclepro.2017.11.208 ↗
37. Saleh TA (2020) Characterization, determination and elimination technologies for sulfur from petroleum: Toward cleaner fuel and a safe environment. Trends Environ Anal Chem 25:e0008010.1016/j.teac.2020.e00080 ↗
38. Saleh TA (2021) Protocols for synthesis of nanomaterials polymers and green materials as adsorbents for water treatment technologies. Environ Technol Innov 24:101821. https://doi.org/10.1016/j.eti.2021.10182110.1016/j.eti.2021.101821 ↗
39. Sharma G, Kumar A, Naushad M, García-Peñas A, Al-Muhtaseb AH, Ghfard AA, Sharma V, Ahamad T, Stadler FJ (2018) Fabrication and characterization of Gum arabic-cl-poly(acrylamide) nanohydrogel for effective adsorption of crystal violet dye. Carbohydrate Polym 202:444–45310.1016/j.carbpol.2018.09.004 ↗
40. Simonin JP (2016) On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. Chem Eng J 300:254–26310.1016/j.cej.2016.04.079 ↗
41. Tuzen M, Sarı A, Saleh TA (2020) Synthesis, characterization and evaluation of carbon nanofiber modified-polymer for ultra-removal of thorium ions from aquatic media. Chem Eng Res Design 163:76–8410.1016/j.cherd.2020.08.021 ↗
42. Varala S, Kumari A, Dharanija B, Bhargava SK, Parthasarathy R, Satyavathi B (2016) Removal of thorium (IV) from aqueous solutions by deoiled karanja seed cake: Optimization using Taguchi method, equilibrium, kinetic and thermodynamic studies. J Environ Chem Eng 4:405–41710.1016/j.jece.2015.11.035 ↗
43. Wang YQ, Zhang Z, Li Q, Liu YH (2012) Adsorption of thorium from aqueous solution by HDTMA+-pillared bentonite. J Radioanal Nucl Chem 293:519–52810.1007/s10967-012-1793-z ↗
44. Xiao J, Chen Y, Zhao W, Xu J (2013) Sorption behavior of U(VI) onto Chinese bentonite: Effect of pH, ionic strength, temperature and humic acid. J Mol Liq 188:178–18510.1016/j.molliq.2013.10.008 ↗
45. Yin Z, Pan D, Liu P, Wu H, Li Z, Wu W (2018) Sorption behavior of thorium(IV) onto activated bentonite. J Radioanal Nucl Chem 316:301–31210.1007/s10967-018-5716-5 ↗
46. Zhang HX, Niu ZW, Liu Z, Wen ZD, Li WP, Wang XY, Wu WS (2015) Equilibrium, kinetic and thermodynamic studies of adsorption of Th(IV) from aqueous solution onto kaolin. J Radioanal Nucl Chem 303:87–9710.1007/s10967-014-3324-6 ↗
47. Zhou L, Jia Y, Peng J, Liu Z, Al-Zaini E (2014) Competitive adsorption of uranium(VI) and thorium(IV) ions from aqueous solution using triphosphate-crosslinked magnetic chitosan resins. J Radioanal Nucl Chem 302:331–34010.1007/s10967-014-3125-y ↗