journal article·2012-09

Abnormal increase of glass transition temperature of poly(propylene carbonate) modified with rubber particles

Xiang Wang, Zhuoxin Li, Xingzhong Cao, Baoyi Wang, Guicun Qi, Xiaohong Zhang, Jianming Gao, Binghai Li, Zhihai Song, Jinliang Qiao

Polymer Composites· Volume 33· Issue 9
Publisher page

Abstract

Abstract Poly(propylene carbonate) (PPC) modified with CBS‐UFPR rubber particle was used as an example to explore the abnormal increase of glass transition temperature ( T g ) of thermoplastics modified with rubber particle. TEM and AFM results showed that CBS‐UFPR was dispersed well in PPC with diameter of about 100 nm. The concentration and size of free‐volume in blends were measured by PALS, which indicated the existence of interfacial interaction between PPC and CBS‐UFRP. A schematic two‐layer model was proposed and the thickness of the interfacial layer was calculated. POLYM. COMPOS. 2012. © 2012 Society of Plastics Engineers
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Polymer crystallization and properties · Polymer Nanocomposites and Properties · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (15)

Show source-provided references
1. 10.1021/ma00105a05910.1021/ma00105a059 ↗
2. 10.1021/ma021270010.1021/ma0212700 ↗
3. 10.1103/PhysRevE.52.R332910.1103/PhysRevE.52.R3329 ↗
4. 10.1103/PhysRevE.61.R5310.1103/PhysRevE.61.R53 ↗
5. 10.1103/PhysRevE.63.02150110.1103/PhysRevE.63.021501 ↗
6. 10.1002/pat.57010.1002/pat.570 ↗
7. 10.1088/0953-8984/17/15/R0110.1088/0953-8984/17/15/R01 ↗
8. 10.1002/047175712810.1002/0471757128 ↗
9. 10.1039/c0py00413h10.1039/c0py00413h ↗
10. Liu Y.Q. · Chin. J. Polym. Sci. · 2002 · 20 · 93
11. (a)J.L.Qiao G.S.Wei X.H.Zhang S.J.Zhang J.M.Gao W.Zhang Y.Q.Liu F.R.Zhang R.L.Zhai J.B.Shao K.K.Yan andH.Yin US 6 423 760 B1 (2002). (b)J.L.Qiao G.S.Wei X.H.Zhang S.J.J.M.Gao W.Zhang Y.Q.Liu F.R.Zhang R.L.Zhai J.B.Shao K.K.Yan andH.Yin CN1152082C (2004).
12. 10.1002/1521-3927(20020901)23:13<786::AID-MARC786>3.0.CO;2-T10.1002/1521-3927(20020901)23:13<786::AID-MARC786>3.0.CO;2-T ↗
13. 10.1021/ma901267s10.1021/ma901267s ↗
14. 10.1002/pssa.221141020210.1002/pssa.2211410202 ↗
15. 10.1016/j.eurpolymj.2007.05.01110.1016/j.eurpolymj.2007.05.011 ↗