Interaction of silica and carbon black fillers with natural rubber/poly(ethylene‐co‐vinyl acetate) matrix by swelling studies

Abstract The interaction of a black filler and a white filler, which are extensively used in the rubber industry, with natural rubber/poly (ethylene‐co‐vinyl acetate) (NR/EVA) blends vulcanized by DCP has been examined by equilibrium swelling technique. Blends loaded with intermediate super abrasion furnace black (ISAF) and those with silica (SiO₂), of same loading, have been used. The silica incorporated blends sorbed a higher amount of aromatic solvents, compared with the ISAF filled blends, when NR was the continuous phase. However, the silica filled systems showed lower sorption characteristics when EVA became the continuous phase. This has been explained in terms of the differences in the interaction between the filler particles and the blend components. The swelling coefficient, diffusion coefficient, and molar mass between crosslinks have been computed to complement the experimental observations. POLYM. COMPOS., 28:705–712, 2007. © 2007 Society of Plastics Engineers