Nanocellulose chiral synergistic effect enhances circularly polarized luminescence of lanthanide electric dipole transition bands
Source abstract
Abstract
Abstract The circularly polarized luminescence (CPL) of Eu(III) ion has been highly valued due to their high asymmetry factor and characteristic luminescence. However, the most reported CPL of Eu3+ ion is contributed from the magnetic dipole transitions but very less from the electric dipole transitions due to the influence of coordination fields. Until now, the amplification of the asymmetry factor (glum) of CPL is mainly due to magnetic dipole transition glum (glum−mag), while electric dipole transition glum (glum−ele) has almost no amplification. In this study, nanocellulose chiral films were synergistically induced with chiral β-diketones Eu-TFC (D/L) and hybrid photonic crystal films CNC@Eu-TFC (D/L) targeted methods for achieving electric dipole transition CPL and glum−ele of Eu3+ ions. The glum−ele was higher than glum−mag, achieving a reversal of glum−ele and glum−mag sizes. The glum of CNC@Eu-TFC (L) was relatively higher than that of CNC@Eu-TFC (D), the main reason for which was that the macroscopic chirality of the nanocellulose film, with a left-handed spiral structure, had a stronger synergistic induction effect with left-handed Eu-TFC (L). Therefore, utilizing the macroscopic chirality of CNC films could effectively amplify the difficulty to activate glum−ele of Eu3+ ions, providing a new approach for its preparation in high-performance CPL materials.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Liquid Crystal Research Advancements · Lanthanide and Transition Metal Complexes · Synthesis and Properties of Aromatic Compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Ai Y, Fei Y, Shu Z, Zhu Y, Liu J, Li Y (2022) Visible-light-controlled ternary chiroptical switches with high-performance circularly polarized luminescence for advanced optical information storage and anti-counterfeiting materials. Chem Eng J 450:138390. https://doi.org/10.1016/j.cej.2022.13839010.1016/j.cej.2022.138390 ↗
2. Albano G, Pescitelli G, Bari L (2020) Chiroptical properties in thin films of π-conjugated systems. Chem Rev 120:10145. https://doi.org/10.1021/acs.chemrev.0c0019510.1021/acs.chemrev.0c00195 ↗
3. Arrico L, De RC, Di BL, Melchior A, Piccinelli F (2020) Effect of the counterion on circularly polarized luminescence of europium(III) and samarium(III) complexes. Inorg Chem 59:5050–5062. https://doi.org/10.1021/acs.inorgchem.0c0028010.1021/acs.inorgchem.0c00280 ↗
4. Arrico L, Benetti C, Di BL (2021) Combining lanthanides with PyBox ligands: a aimple route to circularly polarized light emitters. ChemPhotoChem 5:815–821. https://doi.org/10.1002/cptc.20210008210.1002/cptc.202100082 ↗
5. Barry DE, Kitchen JA, Mercs L, Peacock RD, Albrecht M, Gunnlaugsson T (2019) Chiral luminescent lanthanide complexes possessing strong (samarium, SmIII) circularly polarised luminescence (CPL), and their self-assembly into Langmuir-Blodgett films. Dalton T 48:11317–11325. https://doi.org/10.1039/C9DT02003A10.1039/C9DT02003A ↗
6. Daicho K, Saito T, Fujisawa S, Isogai A (2018) The crystallinity of nanocellulose: dispersion-induced disordering of the grain boundary in biologically structured cellulose. ACS Appl Nano Mater 1(10):5774–5785. https://doi.org/10.1021/acsanm.8b0143810.1021/acsanm.8b01438 ↗
7. Dalal A, Nehra K, Hooda A, Singh D, Kumar S, Malik RS (2022) Red emissive ternary europium complexes: synthesis, optical, and luminescence characteristics. Luminescence 37:1309–1320. https://doi.org/10.1002/bio.429710.1002/bio.4297 ↗
8. De Vries HL (1951) Rotatory power and other optical properties of certain liquid crystals. Acta Crystallogr 4:219–226. https://doi.org/10.1107/S0365110X5100075110.1107/S0365110X51000751 ↗
9. Doistau B, Jiménez JR, Piguet C (2020) Beyond chiral organic (p-block) chromophores for circularly polarized luminescence: the success of d-block and f-block chiral complexes. Front Chem 8:555. https://doi.org/10.3389/fchem.2020.0055510.3389/fchem.2020.00555 ↗
10. Grey P, Fernandes SN, Gaspar D, Fortunato E, Martins R, Godinho MH, Pereira L (2019) Field-effect fransistors on photonic cellulose nanocrystal solid electrolyte for circular polarized light sensing. Adv Funct Mater 29:1805279. https://doi.org/10.1002/adfm.20180527910.1002/adfm.201805279 ↗
11. Gu Q, Chen Z, Xie W, Qiu W, Peng X, Jiao Y, Su S (2022) Chiral exciplex acceptor enables circularly polarized electroluminescence with high dissymmetry factor close to 10−2. Adv Opt Mater 10:2201793. https://doi.org/10.1002/adom.20220179310.1002/adom.202201793 ↗
12. Han J, Guo S, Lu H, Liu S, Zhao Q, Huang W (2018) Recent progress on circularly polarized luminescent materials for organic optoelectronic devices. Adv Opt Mater 6:180053810.1002/adom.201800538 ↗
13. Han Q, Hao A, Gao W, Qi J, Wang Y, Dong J (2020) Luminescence mechanism of Eu3+ ions doped NaYF4 nanocrystals via in situ time-resolved spectroscopy. Ceram Int 46:11132–11136. https://doi.org/10.1016/j.ceramint.2020.01.13310.1016/j.ceramint.2020.01.133 ↗
14. Hussein BHM, Khairy GM, Kamel RM (2016) Fluorescence sensing of phosdrin pesticide by the luminescent Eu(III)- and Tb(III)-bis(coumarin-3-carboxylic acid) probes. Spectrochim Acta A 158:34–42. https://doi.org/10.1016/j.saa.2016.01.00810.1016/j.saa.2016.01.008 ↗
15. Jiang Q, Xu X, Yin PA, Ma K, Zhen Y, Duan P, Ding B (2019) Circularly polarized luminescence of achiral cyanine molecules assembled on DNA templates. J Am Chem Soc 141:9490–9494. https://doi.org/10.1021/jacs.9b0330510.1021/jacs.9b03305 ↗
16. Jonker JL, Morrison L, Lynch EP, Grunwald I, Byern J, Power AM (2015) The chemistry of stalked barnacle adhesive (Lepas anatifera). Interface Focus 5:20140062. https://doi.org/10.1098/rsfs.2014.006210.1098/rsfs.2014.0062 ↗
17. Kapusta DP, Mulashkin FD, Khrenova MG (2021) Keto-enol tautomerism of the 4,5-dimethyl-2-(2′-hydroxyphenyl)imidazole in water solution: modeling equilibrium between neutral forms and accurate assignment of the absorption bands. Int J Quantum Chem 121:26577. https://doi.org/10.1002/qua.2657710.1002/qua.26577 ↗
18. Liu S, Wang X, Dou Y, Wang Q, Kim J, Slebodnick C, Quan L (2024) Direct observation of circularly polarized nonlinear optical activities in chiral hybrid lead halides. J Am Chem Soc 146:11835–11844. https://doi.org/10.1021/jacs.4c0061910.1021/jacs.4c00619 ↗
19. Maj M, Jeon J, Góra RW, Cho M (2013) Induced optical activity of DNA-templated cyanine dye aggregates: exciton coupling theory and TD-DFT studies. J Phys Chem A 117:5909–5918. https://doi.org/10.1021/jp309807y10.1021/jp309807y ↗
20. Mizzoni S, Ruggieri S, Sickinger A, Riobé F, Guy L, Roux M, Piccinelli F (2023) Circularly polarized activity from two photon excitable europium and samarium chiral bioprobes. J Mater Chem C 11:4188–4202. https://doi.org/10.1039/D2TC05362D10.1039/D2TC05362D ↗
21. Niu F, Li M, Huang Q, Zhang X, Pan W, Yang J, Li J (2017) The characteristic and dispersion stability of nanocellulose produced by mixed acid hydrolysis and ultrasonic assistance. Carbohyd Polym 165:197–204. https://doi.org/10.1016/j.carbpol.2017.02.04810.1016/j.carbpol.2017.02.048 ↗
22. Qu D, Archimi M, Camposeo A, Pisignano D, Zussman E (2021) Circularly polarized laser with chiral nematic cellulose nanocrystal cavity. ACS Nano 15:8753–8760. https://doi.org/10.1021/acsnano.1c0100110.1021/acsnano.1c01001 ↗
23. Ritacco T, Aceti DM, De DG, Giocondo M, Mazzulla A, Cipparrone G, Pagliusi P (2023) Tuning cholesteric selective reflection in situ upon two-photon polymerization enables structural multicolor 4D microfabrication. Adv Opt Mater 11:2302489. https://doi.org/10.1002/adom.20210152610.1002/adom.202101526 ↗
24. Ruggieri S, Mizzoni S, Nardon C, Cavalli E, Sissa C, Anselmi M, Piccinelli F (2023) Circularly polarized luminescence from new heteroleptic Eu(III) and Tb(III) complexes. Inorg Chem 62:8812–8822. https://doi.org/10.1021/acs.inorgchem.3c0019610.1021/acs.inorgchem.3c00196 ↗
25. Segal LG, Creely JJ, Martin AE Jr, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794. https://doi.org/10.1177/00405175590290100310.1177/004051755902901003 ↗
26. Sugiura K (2020) Paracyclophane-based chiral platforms for circularly polarized luminescence fluorophores and their chiroptical properties: past and future. Front Chem 8:700. https://doi.org/10.3389/fchem.2020.0070010.3389/fchem.2020.00700 ↗
27. Tan YB, Yamada M, Katao S, Nishikawa Y, Asanoma F, Yuasa J, Kawai T (2020) Self-assembled tetranuclear EuIII complexes with D 2-and C 2h-symmetrical square scaffold. Inorg Chem 59:12867–12875. https://doi.org/10.1021/acs.inorgchem.0c0193310.1021/acs.inorgchem.0c01933 ↗
28. Tsurui M, Kitagawa Y, Shoji S, Ohmagari H, Hasegawa M, Gon M, Hasegawa Y (2022) Asymmetric lumino-transformer: circularly polarized luminescence of chiral Eu(III) coordination polymer with phase-transition behavior. J Phys Chem B 126:3799–3807. https://doi.org/10.1021/acs.jpcb.2c0163910.1021/acs.jpcb.2c01639 ↗
29. Wang C, Tang C, Wang Y, Shen Y, Qi W, Zhang T, He Z (2022) Chiral photonic materials self-assembled by cellulose nanocrystals. Curr Opin Solid St M 26:101017. https://doi.org/10.1016/j.cossms.2022.10101710.1016/j.cossms.2022.101017 ↗
30. Willis OG, Petri F, De DF, Mandoli A, Pal R, Zinna F, Di BL (2023) Two-photon circularly polarized luminescence of chiral Eu complexes. J Am Chem Soc 145:25170–2517610.1021/jacs.3c05957 ↗
31. Wong HY, Lo WS, Yim KH, Law GL (2019) Chirality and chiroptics of lanthanide molecular and supramolecular assemblies. Chem 5:3058–3095. https://doi.org/10.1016/j.chempr.2019.08.00610.1016/j.chempr.2019.08.006 ↗
32. Xie F, Shen C, Li X, Xiao P, Wang S, Li Y, Liu Q (2024) An electrochemiluminescence sensor based on lanthanide bimetallic MOFs with a “cascade sensitization mechanism” for the sensitive detection of CA242. Talanta 273:125956. https://doi.org/10.1016/j.talanta.2024.12595610.1016/j.talanta.2024.125956 ↗
33. Yu H, Zhang K, Yu Q, Zhang J, Ye Y, Redshaw C, Chen Z, Xu D, Mehl G (2024) Enhanced asymmetric circularly polarized luminescence in self-organized helical superstructures enabled by macro-chiral liquid crystal quantum dots. ACS Nano 18:32056. https://doi.org/10.1021/acsnano.4c1042310.1021/acsnano.4c10423 ↗
34. Zhang J, Dai L, Webster AM, Chan WTK, Mackenzie LE, Pal R, Law GL (2021) Unusual magnetic field responsive circularly polarized luminescence probes with highly emissive chiral europium (III) complexes. Angew Chem Int Ed 60:1004–1010. https://doi.org/10.1002/anie.20201213310.1002/anie.202012133 ↗
35. Zhang Y, Yu S, Han B, Zhou Y, Zhang X, Gao X, Tang Z (2022) Circularly polarized luminescence in chiral materials. Matter 5:837–875. https://doi.org/10.1016/j.matt.2022.01.00110.1016/j.matt.2022.01.001 ↗
36. Zhang M, Guo Q, Li Z, Zhou Y, Zhao S, Tong Z, Yu SH (2023) Processable circularly polarized luminescence material enables flexible stereoscopic 3D imaging. Sci Adv 9:9944. https://doi.org/10.1126/sciadv.adi994410.1126/sciadv.adi9944 ↗
37. Zhao T, Han J, Duan P, Liu M (2020) New perspectives to trigger and modulate circularly polarized luminescence of complex and aggregated systems: energy transfer, photon upconversion, charge transfer, and organic radical. Acc ChemRes 53:1279–1292. https://doi.org/10.1021/acs.accounts.0c0011210.1021/acs.accounts.0c00112 ↗
38. Zhao S, Yu Y, Zhang B, Feng P, Dang C, Li M, Gao L (2021a) Metal-enhanced circularly polarized luminescence of self-assembled Au@SiO2 triangular nanoprisms and fluorophores in chiral cellulose nanocrystal films. Adv Opt Mater 9:2100907. https://doi.org/10.1002/adom.20210090710.1002/adom.202100907 ↗
39. Zhao S, Yu Y, Zhang B, Feng P, Dang C, Li M, Zhao L, Gao L (2021b) Dual-mode circularly polarized light emission and metal-enhanced fluorescence realized by the luminophore–chiral cellulose nanocrystal interfaces. ACS Appl Mater Interfaces 13:59132–59141. https://doi.org/10.1021/acsami.1c1940410.1021/acsami.1c19404 ↗
40. Zhong Y, Wu Z, Zhang Y, Dong B, Bai X (2023) Circularly polarized luminescence of lanthanide complexes: from isolated individuals, discrete oligomers, to hierarchical assemblies. InfoMat 5:12392. https://doi.org/10.1002/inf2.1239210.1002/inf2.12392 ↗
41. Zhou Y, Yao Y, Cheng Z, Gao T, Li H, Yan P (2020) Point chirality controlled diastereoselective self-assembly and circularly polarized luminescence in quadruple-stranded europium(III) helicates. Inorg Chem 59:12850–12857. https://doi.org/10.1021/acs.inorgchem.0c0191110.1021/acs.inorgchem.0c01911 ↗