The preparation of rigid hybrid silicone resins by combining carbon nanomaterial loading nanoparticles

Abstract A series of carbon nanotubes and graphene loading nanoparticles (Mo, Ru, and Pt) were synthesized by the ethylene glycol reduction, in addition, the nanomaterials went through the silanization process by (3‐aminopropyl)triethoxysilane in order to obtain the perfect consistency and dispersibility. The characterization results were then exhibited by X‐ray photoelectron spectroscopy, Raman spectroscopy, scanning electron microscopy, and transmission electron microscopy tests. Furthermore, the nanomaterials modified silicone resins were obtained by combining methyl phenyl silicone resins, nanocarbon material and HOOBt. The differential scanning calorimetry, sol–gel time and thermogravimetric analysis tests showed the preferable improvement of heat‐resistant quality. Then the silicone resin matrix composites were manufactured by molding process and went through a thermal decomposition process. The ILSS, bending strength and modulus results showed that the hybrid modified silicone resin composites had the leading trend (361.4 MPa, 190.3 MPa, 13.5 GPa, etc.) at all temperature stages. This experimental scheme of carbon nanomaterial loading nanoparticles and hybrid modified silicone resins would have a competitive advantage in exotic material field.