Preparation and properties of short oil alkyd resin/TiO 2 nanocomposites based on surface modified TiO 2 nanoparticles
Source abstract
Abstract
Alkyd resin/TiO 2 nanocomposites (NC) were prepared from short oil alkyd resin and TiO 2 nanoparticles (NPs) surface modified with in situ formed imine ligand, based on 3,4‐dihydroxybenzaldehyde and oleylamine, or with three gallic acid esters. The short oil alkyd resin was synthesized from sunflower oil, phthalic anhydride, and trimethylolpropane. Unmodified and surface modified TiO 2 NPs were examined by transmission electron microscopy. Rheological investigation revealed that prepared dispersions have higher dynamic viscosity than pure alkyd resin. Using different characterization methods it was obtained that NCs have similar thermooxidative stability as alkyd resin, lower glass transition temperature, better barrier properties, enhanced hardness, better chemical resistance, and lower adhesion to the metal, except in the case of NC prepared using TiO 2 NPs surface modified with imine, which exhibited better adhesion to the metal than pure alkyd resin. POLYM. COMPOS., 39:1488–1499, 2018. © 2016 Society of Plastics Engineers
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Epoxy Resin Curing Processes · Polymer composites and self-healing · Silicone and Siloxane Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Innovation Center Faculty of Technology and Metallurgy University of Belgrade Karnegijeva 4, Belgrade 11120 Serbia
Institute of Chemistry, Technology and Metallurgy (ICTM) Center of Chemistry, University of Belgrade Studentski Trg 12–16, Belgrade 11000 Serbia
Vinča Institute of Nuclear Sciences University of Belgrade P.O. Box 522, Belgrade 11001 Serbia
Faculty of Technology and Metallurgy University of Belgrade Karnegijeva 4, Belgrade 11120 Serbia
Funding
Ministry of Education, Science and Technological Development of the Republic of Serbia
References (45)
Show source-provided references
1. Deligny P. · 2000
2. 10.1016/j.porgcoat.2011.01.01410.1016/j.porgcoat.2011.01.014 ↗
3. 10.1002/pola.2735210.1002/pola.27352 ↗
4. 10.1007/s11746-997-0169-y10.1007/s11746-997-0169-y ↗
5. 10.1007/s11746-997-0049-510.1007/s11746-997-0049-5 ↗
6. 10.1007/s11746-010-1668-910.1007/s11746-010-1668-9 ↗
7. 10.1016/j.electacta.2010.03.08810.1016/j.electacta.2010.03.088 ↗
8. 10.1016/j.porgcoat.2013.08.00510.1016/j.porgcoat.2013.08.005 ↗
9. 10.1016/j.porgcoat.2011.07.01310.1016/j.porgcoat.2011.07.013 ↗
10. 10.1007/BF0270681310.1007/BF02706813 ↗
11. 10.1108/0369942121126486610.1108/03699421211264866 ↗
12. 10.1016/S0300-9440(98)00033-210.1016/S0300-9440(98)00033-2 ↗
13. 10.1016/B978-0-08-045316-3.00003-X10.1016/B978-0-08-045316-3.00003-X ↗
14. 10.1016/j.arabjc.2013.12.02310.1016/j.arabjc.2013.12.023 ↗
15. 10.1016/j.porgcoat.2009.02.00410.1016/j.porgcoat.2009.02.004 ↗
16. 10.1021/jp020928910.1021/jp0209289 ↗
17. 10.1007/s11164-013-1165-510.1007/s11164-013-1165-5 ↗
18. 10.1016/j.carbon.2014.02.01310.1016/j.carbon.2014.02.013 ↗
19. 10.1002/app.2405610.1002/app.24056 ↗
20. 10.1016/j.porgcoat.2004.03.00210.1016/j.porgcoat.2004.03.002 ↗
21. 10.1016/j.porgcoat.2008.07.00710.1016/j.porgcoat.2008.07.007 ↗
22. 10.1002/app.3027610.1002/app.30276 ↗
23. 10.1088/0957-4484/25/31/31510110.1088/0957-4484/25/31/315101 ↗
24. 10.1016/j.corsci.2008.09.02810.1016/j.corsci.2008.09.028 ↗
25. 10.1016/j.matchemphys.2009.07.01010.1016/j.matchemphys.2009.07.010 ↗
26. 10.1039/C3RA48068B10.1039/C3RA48068B ↗
27. 10.1007/s11998-008-9127-310.1007/s11998-008-9127-3 ↗
28. 10.1016/j.porgcoat.2011.11.02010.1016/j.porgcoat.2011.11.020 ↗
29. Shi H. · J. Mater. Sci. Technol. · 2007 · 23 · 551
30. 10.1016/j.matchemphys.2014.03.04510.1016/j.matchemphys.2014.03.045 ↗
31. 10.1166/mex.2014.118510.1166/mex.2014.1185 ↗
32. 10.1016/j.eurpolymj.2012.05.01710.1016/j.eurpolymj.2012.05.017 ↗
33. 10.1002/pc.2242310.1002/pc.22423 ↗
34. 10.1016/j.matdes.2014.05.01510.1016/j.matdes.2014.05.015 ↗
35. 10.3144/expresspolymlett.2015.8310.3144/expresspolymlett.2015.83 ↗
36. 10.2298/HEMIND131106081R10.2298/HEMIND131106081R ↗
37. B.Sas B.Coppens andJ.VanHemel WIPO Patent Publication Number WO 01/30299 A2 (2001).
38. 10.1021/j100387a01710.1021/j100387a017 ↗
39. 10.1016/j.polymdegradstab.2009.07.01810.1016/j.polymdegradstab.2009.07.018 ↗
40. 10.1002/pc.2019910.1002/pc.20199 ↗
41. 10.1007/s11998-011-9376-410.1007/s11998-011-9376-4 ↗
42. 10.1021/la301781n10.1021/la301781n ↗
43. 10.1016/j.porgcoat.2014.01.01710.1016/j.porgcoat.2014.01.017 ↗
44. 10.1108/0369942121121075710.1108/03699421211210757 ↗
45. 10.1002/app.3502910.1002/app.35029 ↗