Study on BMI modified allyl‐functional novolac resin/silica cloth composites: Effect of allylation degree on thermal and mechanical properties

Abstract A series of allyl‐functional novolac resin with various allylation degree, from 32.4 to 114.6%, were synthesized and then blended reactively with 4,4′‐bismaleimide biphenyl methane (BMI) at a weight ratio of 2.50:1 to get BMI‐modified allyl‐functional novolac (BMAN) resins. BMAN resins were used as matrix resin to fabricate BMAN/Silica cloth composites by compression molding process. Heat‐resistant properties of the composites were evaluated by means of dynamic mechanical analysis. The results indicated that thermal resistance of the composites increased as allylation degree of BMAN resins increased. Mechanical properties of the composites, including interlaminar shear strength (ILSS) and flexural strength at room temperature and 300°C, were determined, and the results showed that with increase in allylation degree of matrices the ILSS and flexural strength values of composites at room temperature decreased, but the values of ILSS and flexural strength at 300°C increased. Scanning electron microscope morphology analysis of fracture surface for composites revealed that tough interphase was responsible for the better mechanical properties of the composites based on lower allylation degree resins. POLYM. COMPOS., 28:180–185, 2007. © 2007 Society of Plastics Engineers