journal article·2024-08-10Open access

Chemo‐rheological and quantitative dispersion analysis of mass‐produced graphene‐unsaturated polyester based nanocomposites

Farnaz Mazaheri Karvandian, David‐Michael Phillips, Emi Myzeqari, Pascal Hubert

Polymer Composites· Volume 45· Issue 11

Abstract

Abstract Recent advancements in mass production of graphene powders utilize less energy‐intensive methods and milder chemicals compared to traditional lab‐scale techniques. This can influence the properties of the resulting graphene particles. This study investigates the effect of mass‐produced graphene powder on the curing and rheological properties of a resin transfer molding (RTM) grade unsaturated polyester resin. An objective dispersion quantification method was established to track the dispersion state of the nanocomposite throughout the curing process. The findings reveal that the graphene powder accelerated the curing evidenced by a shift in the peak temperature and gel point towards lower values. The sample containing 1 wt.% graphene exhibited remarkable dispersion stability with only 7.1% decrease by gelation. The resin matrix's low viscosity enhanced graphene particles mobility, while its fast‐curing nature allowed less time for agglomeration. Highlights Characterization of unsaturated polyester nanocomposites modified with an industrial‐grade graphene powder Real‐time in‐situ monitoring of graphene's dispersion state Quantification dispersion analysis for an objective dispersion assessment
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Epoxy Resin Curing Processes · Polymer Nanocomposites and Properties · Polymer crystallization and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mechanical Engineering McGill University Montreal Quebec Canada

Research Center for High Performance Polymer and Composite Systems Montreal Quebec Canada

Funding

Natural Sciences and Engineering Research Council of Canada

References (48)

Show source-provided references
1. 10.3390/polym1315256710.3390/polym13152567 ↗
2. 10.3390/polym1005047710.3390/polym10050477 ↗
3. 10.1016/j.compositesa.2019.02.02710.1016/j.compositesa.2019.02.027 ↗
4. 10.1021/cr900070d10.1021/cr900070d ↗
5. 10.1016/j.flatc.2018.03.00410.1016/j.flatc.2018.03.004 ↗
6. 10.1002/anie.20200225610.1002/anie.202002256 ↗
7. 10.4028/www.scientific.net/SSP.291.8310.4028/www.scientific.net/SSP.291.83 ↗
8. 10.1016/j.flatc.2021.10022410.1016/j.flatc.2021.100224 ↗
9. JovićM GonçalvesB NascimentoS RenjiniGR.Graphene Manufacturing in 2022.2022.
10. Graphene Supermarket.(accessed September 27 2022). n.d.).https://www.graphene-supermarket.com/
11. 10.1002/pen.2498110.1002/pen.24981 ↗
12. 10.1002/app.5166410.1002/app.51664 ↗
13. 10.1007/s10853‐020‐05336‐510.1007/s10853‐020‐05336‐5 ↗
14. 10.1016/j.eurpolymj.2012.03.01210.1016/j.eurpolymj.2012.03.012 ↗
15. 10.3390/polym1314237510.3390/polym13142375 ↗
16. 10.1002/polb.2451510.1002/polb.24515 ↗
17. 10.1016/j.carbon.2013.03.05010.1016/j.carbon.2013.03.050 ↗
18. 10.1016/j.compositesa.2018.03.02210.1016/j.compositesa.2018.03.022 ↗
19. 10.1016/j.compscitech.2013.04.00910.1016/j.compscitech.2013.04.009 ↗
20. 10.1016/j.compositesb.2019.01.02010.1016/j.compositesb.2019.01.020 ↗
21. 10.1016/j.apsusc.2019.14416410.1016/j.apsusc.2019.144164 ↗
22. 10.1016/j.nanoms.2019.02.00610.1016/j.nanoms.2019.02.006 ↗
23. 10.1007/s42823‐020‐00161‐x10.1007/s42823‐020‐00161‐x ↗
24. 10.1088/0957‐4484/23/31/31570110.1088/0957‐4484/23/31/315701 ↗
25. 10.1021/am301459q10.1021/am301459q ↗
26. 10.1016/j.compositesa.2018.10.00310.1016/j.compositesa.2018.10.003 ↗
27. 10.1177/073168441561370410.1177/0731684415613704 ↗
28. 10.1111/jmi.1253610.1111/jmi.12536 ↗
29. 10.1007/s42452‐019‐1031‐110.1007/s42452‐019‐1031‐1 ↗
30. 10.1016/j.compscitech.2018.12.01210.1016/j.compscitech.2018.12.012 ↗
31. YourdkhaniM.Aspects of nanoparticles dispersion and interaction in polymer nanocomposites.2013129.
32. 10.1002/adma.20180099610.1002/adma.201800996 ↗
33. 10.1016/j.jtice.2018.10.02810.1016/j.jtice.2018.10.028 ↗
34. 10.1007/s12274‐020‐2897‐310.1007/s12274‐020‐2897‐3 ↗
35. 10.3390/polym1313203610.3390/polym13132036 ↗
36. 10.1016/j.matlet.2015.12.13010.1016/j.matlet.2015.12.130 ↗
37. 10.1016/j.tca.2014.12.02410.1016/j.tca.2014.12.024 ↗
38. 10.1002/pen.2066710.1002/pen.20667 ↗
39. 10.1021/ma301784410.1021/ma3017844 ↗
40. 10.1016/j.ijbiomac.2014.05.05510.1016/j.ijbiomac.2014.05.055 ↗
41. 10.3390/ma1704080610.3390/ma17040806 ↗
42. CarreauPJ VergnesB.Rheological characterization of fiber suspensions and nanocomposites. In:Rheology of Non‐Spherical Particle Suspensions. Elsevier;2015:19‐58. doi:10.1016/B978‐1‐78548‐036‐2.50002‐210.1016/B978-1-78548-036-2.50002-2 ↗
43. 10.1007/s00397‐009‐0375‐710.1007/s00397‐009‐0375‐7 ↗
44. 10.1186/s11671‐015‐1004‐210.1186/s11671‐015‐1004‐2 ↗
45. 10.1039/d0ra07639b10.1039/d0ra07639b ↗
46. 10.1166/jnn.2013.746110.1166/jnn.2013.7461 ↗
47. 10.1039/c2cc16031e10.1039/c2cc16031e ↗
48. 10.1016/j.carbon.2014.09.05610.1016/j.carbon.2014.09.056 ↗