journal article·2015-02

Influence of Barium Titanate on poly(vinyl pyrrolidone)‐based composite polymer blend electrolytes for lithium battery applications

K. Kesavan, S. Rajendran, Chithra M. Mathew

Polymer Composites· Volume 36· Issue 2
Publisher page

Abstract

Nanocomposite polymer blend electrolytes based on poly (ethylene oxide), poly (vinyl pyrrolidone) that contained lithium perchlorate as a dopant, propylene carbonate (PC) as a plasticizer and Barium Titanate (BaTiO3) as a filler were prepared for various concentrations of BaTiO3 using solvent casting technique. The structural and complex formations of the composite electrolyte membranes were confirmed by X‐ray diffraction and FTIR analysis. The addition of BaTiO3 nanofillers improved the ionic conductivity of the polymer electrolytes to some extent when the content of the BaTiO3 is 10 wt%. The addition of BaTiO3 also enhanced the thermal stability of the electrolyte. The surface morphology of the sample having a maximum ionic conductivity was studied by AFM. Molecular motion in the polymeric media was supported by fluorescence studies. The charge transfer arises between the polymer blend and Li‐ions were confirmed by UV‐Vis analysis. POLYM. COMPOS., 36:302–311, 2015. © 2014 Society of Plastics Engineers
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Physics, Alagappa University Karaikudi Tamilnadu 630003 India

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