journal article·2017-03

Abiotic and biotic degradation of post‐consumer polypropylene/ethylene vinyl acetate: Wood flour composites exposed to natural weathering

André L. Catto, Larissa S. Montagna, Ruth M.C. Santana

Polymer Composites· Volume 38· Issue 3
Publisher page

Abstract

The effects of natural weathering on the visual appearance and chemical changes of wood plastic composite (WPC) formulations based on post‐consumer polypropylene/ethylene vinyl acetate (PP‐EVA) matrix were investigated. The WPC composition used was 70/30 (w/w) (recycled PP‐EVA/wood flour). Besides, the effectiveness of using coupling agent on adhesion of WPC and its influence in degradation were evaluated. Colorimetry, scanning electron microscopy, Fourier transform infrared spectroscopy, mechanical test, and biodegradation in simulated soil after natural weathering were used in this research. The results showed the samples with longer exposure time to natural weathering presented significant color change, increased in carbonyl index, and wood loss on weathered WPC surfaces. Weathered WPC exhibited decreased in mechanical properties, higher mass loss after biodegradation test when compared with no weathering WPC, reaching to 15.0% mass loss against 3.7%, respectively. Climatic conditions directly affect the characteristics of all composites, thus indicating a significant photo‐oxidation of the samples with a longer time of exposure to weathering, and this natural ageing has facilitated the WPC biodegradation . POLYM. COMPOS., 38:571–582, 2017. © 2015 Society of Plastics Engineers
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Research context

OpenAlex topics: Natural Fiber Reinforced Composites · biodegradable polymer synthesis and properties · Microplastics and Plastic Pollution

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Engineering, Laboratory of Polymers—LAPOL Federal University of Rio Grande do Sul UFRGS, School of Engineering Porto Alegre Brazil

Funding

CAPES and CNPq

References (70)

Show source-provided references
1. Yildiz S. · BioResources · 2011 · 6 · 250410.15376/biores.6.3.2504-2521 ↗
2. 10.1016/j.polymdegradstab.2013.05.00410.1016/j.polymdegradstab.2013.05.004 ↗
3. 10.1016/j.compscitech.2012.07.00210.1016/j.compscitech.2012.07.002 ↗
4. 10.1016/j.polymdegradstab.2004.01.01310.1016/j.polymdegradstab.2004.01.013 ↗
5. 10.1016/S0141-3910(98)00191-810.1016/S0141-3910(98)00191-8 ↗
6. 10.1023/A:100929800827610.1023/A:1009298008276 ↗
7. 10.1016/j.compositesa.2010.06.00410.1016/j.compositesa.2010.06.004 ↗
8. 10.1002/pc.2004810.1002/pc.20048 ↗
9. T.Lundin Effect of Accelerated Weathering on the Physical and Mechanical Properties of Natural‐Fiber Thermoplastic Composites M.S. Thesis University of Wisconsin Madison WI (2001).
10. 10.1016/j.polymdegradstab.2012.03.02210.1016/j.polymdegradstab.2012.03.022 ↗
11. Miklecic J. · BioResources · 2011 · 6 · 43410.15376/biores.6.1.434-446 ↗
12. 10.1016/j.compscitech.2008.06.01410.1016/j.compscitech.2008.06.014 ↗
13. 10.1016/j.progpolymsci.2008.12.00210.1016/j.progpolymsci.2008.12.002 ↗
14. Schauwecker C. · For. Prod. J. · 2006 · 56 · 123
15. 10.1016/j.polymdegradstab.2006.08.00310.1016/j.polymdegradstab.2006.08.003 ↗
16. J.S.Fabiyi A.G.McDonald M.P.Wolcott andK.Englund Understanding the chemistry of wood plastic composites weathering inProceedings Progress in Wood and Bio‐Fibre Plastic Composites International Conference May 1–2 Toronto Ontario Canada (2006).
17. 10.1016/S0141-3910(03)00129-010.1016/S0141-3910(03)00129-0 ↗
18. 10.1016/j.biotechadv.2007.12.00510.1016/j.biotechadv.2007.12.005 ↗
19. 10.1016/j.enzmictec.2007.01.01810.1016/j.enzmictec.2007.01.018 ↗
20. 10.1007/s10924-009-0143-x10.1007/s10924-009-0143-x ↗
21. American Society for Testing Materials ASTM D1435‐13 Standard Practice for Outdoor Weathering of Plastics.
22. American Society for Testing Materials ASTM G7/G7M–13 Standard Practice for Atmospheric Environmental Exposure Testing of Nonmetallic Materials.
23. American Society for Testing Materials ASTM D638–10 Standard Test Method for Tensile Properties of Plastics.
24. American Society for Testing Materials ASTM D256–10 Standard Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics.
25. American Society for Testing Materials ASTM E1252–13 Standard Practice for General Techniques for Obtaining Infrared Spectra for Qualitative Analysis.
26. 10.1016/j.polymdegradstab.2010.02.01810.1016/j.polymdegradstab.2010.02.018 ↗
27. R.L.Silva M.A.DePaoli M.A.S.Spinacé Composites Environmental Aging of Polypropylene with Curauá Fibers 12° Brazilian Polymer Congress (12° CBPOL) Florianópolis Brasil (2013).
28. American Society for Testing Materials ASTM D 2244‐01 Standard Practice for Calculation of Color Tolerances and Color Differences from Instrumentally Measured Color Coordinates.
29. American Society for Testing Materials ASTM D 1003‐13 Standard Test Method for Haze and Luminous Transmittance of Transparent Plastics.
30. CIE · 1986
31. 10.1016/S0141-3910(03)00105-810.1016/S0141-3910(03)00105-8 ↗
32. 10.1063/1.487379310.1063/1.4873793 ↗
33. American Society for Testing Materials ASTM D5338‐11 Standard Test Method for Determining Aerobic Biodegradation of Plastic Materials Under Controlled Composting Conditions Incorporating Thermophilic Temperatures.
34. American Society for Testing Materials ASTM D5988‐12 Standard Test Method for Determining Aerobic Biodegradation of Plastic Materials in Soil.
35. 10.1016/j.polymdegradstab.2010.12.00410.1016/j.polymdegradstab.2010.12.004 ↗
36. International Organization for Standardization ISO 17556:2003: Plastics Determination of the Ultimate Aerobic Biodegradability in Soil by Measuring the Oxygen Demand in a Respirometric or the Amount of Carbon Dioxide Evolved.
37. Montagna L.S. · J. Mater. Sci. Eng. A · 2013 · 3 · 123
38. 10.1080/1532179760807611310.1080/15321797608076113 ↗
39. 10.1007/978-94-011-1274-110.1007/978-94-011-1274-1 ↗
40. Allen N.S. · Eng. Plast. · 1995 · 8 · 247
41. 10.1016/0032-3950(80)90364-010.1016/0032-3950(80)90364-0 ↗
42. 10.1016/0141-3910(93)90190-T10.1016/0141-3910(93)90190-T ↗
43. 10.1016/0141-3910(93)90122-Y10.1016/0141-3910(93)90122-Y ↗
44. 10.1016/j.polymdegradstab.2008.06.01210.1016/j.polymdegradstab.2008.06.012 ↗
45. 10.1016/j.polymdegradstab.2003.10.02210.1016/j.polymdegradstab.2003.10.022 ↗
46. 10.1016/j.compositesa.2009.03.01110.1016/j.compositesa.2009.03.011 ↗
47. 10.1002/app.1144610.1002/app.11446 ↗
48. 10.1016/j.polymdegradstab.2007.06.01710.1016/j.polymdegradstab.2007.06.017 ↗
49. 10.1016/j.polymdegradstab.2008.05.02410.1016/j.polymdegradstab.2008.05.024 ↗
50. 10.1016/j.polymdegradstab.2011.12.01410.1016/j.polymdegradstab.2011.12.014 ↗
51. 10.1016/j.polymdegradstab.2010.02.02010.1016/j.polymdegradstab.2010.02.020 ↗
52. 10.1002/app.2303510.1002/app.23035 ↗
53. 10.1016/j.polymdegradstab.2004.04.01710.1016/j.polymdegradstab.2004.04.017 ↗
54. 10.1007/s10086-006-0838-810.1007/s10086-006-0838-8 ↗
55. 10.1016/j.polymdegradstab.2004.04.01710.1016/j.polymdegradstab.2004.04.017 ↗
56. 10.1002/pol.1984.17022092310.1002/pol.1984.170220923 ↗
57. 10.1016/j.compositesa.2011.10.00110.1016/j.compositesa.2011.10.001 ↗
58. B.T.Luppi R.Gadioli andM.A.DePaoli Lignin Eucalyptus as an antioxidant for Polypropylene: Environmental and accelerated aging 12° Brazilian Polymer Congress (12°CBPOL) Florianópolis SC (2013).
59. 10.1177/073168440504171710.1177/0731684405041717 ↗
60. 10.1016/j.polymdegradstab.2008.04.00610.1016/j.polymdegradstab.2008.04.006 ↗
61. 10.1016/j.polymdegradstab.2005.06.02410.1016/j.polymdegradstab.2005.06.024 ↗
62. 10.1016/j.biortech.2011.11.12210.1016/j.biortech.2011.11.122 ↗
63. Morrell J.J. · Wood Des. Focus · 2006 · 16 · 7
64. 10.1016/S0032-3861(97)00213-910.1016/S0032-3861(97)00213-9 ↗
65. 10.1080/03602559.2011.55782310.1080/03602559.2011.557823 ↗
66. 10.1007/BF0024443710.1007/BF00244437 ↗
67. R.S.Williams Weathering of Wood Handbook of Wood. Chemistry and Wood Composites CRC Press LLC 139(2005).
68. Hon D.N.S. · 2000 · 512
69. 10.1016/j.polymdegradstab.2007.10.01110.1016/j.polymdegradstab.2007.10.011 ↗
70. 10.1016/j.ibiod.2009.08.00210.1016/j.ibiod.2009.08.002 ↗