journal article·2021-04-28

Electrocatalytic Oxygen Evolution by Hierarchically Structured Cobalt–Iron Composites

Dandan Gao, Rongji Liu, Si Liu, Simon Greiner, Montaha Anjass, Johannes Biskupek, Ute Kaiser, Hanna Braun, Timo Jacob, Carsten Streb

ACS Applied Materials & Interfaces· Volume 13· Issue 16
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Abstract

The development of scalable routes to highly active and efficient oxygen evolution reaction (OER) electrocatalysts based on earth-abundant materials is crucial for post-fossil fuel energy schemes. Here, we demonstrate how commercial copper foam electrodes can be functionalized for water oxidation using a facile electrodeposition process. The resulting composite electrode features hierarchically structured cobalt–iron-based catalyst particles, which offer channel-like structures for the transport of electrolyte and release of oxygen gas bubbles. We report high electrocatalytic OER performance as demonstrated by high current densities at low overpotentials (293 mV at j = 50 mA cm–2) and long-term stability under technologically relevant alkaline conditions (>24 h in 1.0 M aqueous KOH).
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Electrochemical Analysis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081 Ulm, Germany

Helmholtz Institute Ulm, Electrochemical Energy Storage (HIU), Helmholtzstr. 11, 89081 Ulm, Germany

Karlsruhe Institute of Technology, P.O. Box 3640, 76021 Karlsruhe, Germany

Electron Microscopy of Materials Science, Central Facility for Electron Microscopy, Ulm University, Albert-Einstein-Allee 11, 89081 Ulm, Germany

Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081 Ulm, Germany

Funding

Helmholtz-Gemeinschaft · Deutsche Forschungsgemeinschaft · China Scholarship Council · Alexander von Humboldt-Stiftung · Universit?t Ulm

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