Cubic lead perovskite PbMoO3 with anomalous metallic behavior

A previously unreported Pb-based perovskite ${\mathrm{PbMoO}}₃$ is obtained by high-pressure and high-temperature synthesis. This material crystallizes in the $Pm\overline{3}m$ cubic structure at room temperature, making it distinct from typical Pb-based perovskite oxides with a structural distortion. ${\mathrm{PbMoO}}₃$ exhibits a metallic behavior down to 0.1 K with an unusual $T$-sublinear dependence of the electrical resistivity. Moreover, a large specific heat is observed at low temperatures accompanied by a peak in ${C}_P/{T}³$ around 10 K, in marked contrast to the isostructural metallic system ${\mathrm{SrMoO}}₃$. These transport and thermal properties for ${\mathrm{PbMoO}}₃$, taking into account anomalously large Pb atomic displacements detected through diffraction experiments, are attributed to a low-energy vibrational mode, associated with incoherent off-centering of lone-pair ${\mathrm{Pb}}²⁺$ cations. We discuss the unusual behavior of the electrical resistivity in terms of a polaronlike conduction, mediated by the strong coupling between conduction electrons and optical phonons of the local low-energy vibrational mode.