journal article·2021-06-04

Screening and band bending effects in the Stark control of electrons at interfaces (SCELI)

Antonio J. Garzón-Ramírez, Francisco Fernández Villoria, Ignacio Franco

Physical Review B· Volume 103· Issue 23
Publisher page

Abstract

Recently, we developed a general laser control scheme, i.e., the Stark control of electrons at interfaces (SCELI), based on Stark shifts, that is able to manipulate the electron dynamics at material interfaces [A. J. Garz\'on-Ram\'{\i}rez and I. Franco, Phys. Rev. B 98, 121305 (2018)]. Here, we investigate how SCELI is influenced by the band bending effects introduced by interfacial dipoles and by the laser screening due to the polarization response of the material. For this, we follow the quantum dynamics of a model one-dimensional tight-binding semiconductor-semiconductor heterojunction driven by nonresonant few-cycle laser pulses of intermediate intensity. Band bending effects are introduced through an interfacial electrostatic potential term dictated by the depletion approximation of a neutral $p\text{\ensuremath{-}}n$ junction. In turn, screening effects are captured through the general boundary conditions of the field vectors at interfaces dictated by Maxwell's equations. For field amplitudes where SCELI dominates (${E}0\ensuremath{\le}0.55$ V/\AA{} in the model), laser screening leads to a 46% reduction of the effect that can be partially compensated by increasing the intensity of the incident field. Surprisingly, band bending mildly affects SCELI. When both band bending and screening are considered simultaneously, the charge transfer is reduced, on average, 40% for ${E}0\ensuremath{\le}0.46$ V/\AA{}. Overall, we observe that screening and band bending change the magnitude of SCELI but leave the underlying mechanism for electron transfer intact.
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Research context

OpenAlex topics: Laser-Matter Interactions and Applications · Spectroscopy and Quantum Chemical Studies · Advanced Chemical Physics Studies

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Affiliations

Department of Chemistry, University of Rochester, Rochester, New York 14627, USA

Departamento de Química, Módulo 13, Universidad Autónoma de Madrid, 28049 Madrid, Spain

Department of Physics, University of Rochester, Rochester, New York 14627, USA

Funding

National Science Foundation

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