journal article·2020-02-28

Switchable Ionic Rectifiers Based on Ferroelectric Nanopores

Yuchun Zhang, Bin Tu, Jiahui Guo, Tao Xiao, Xing Zhao, Liu Yang, Qiaojun Fang, Yong Yan

ACS Applied Nano Materials· Volume 3· Issue 2
Publisher page

Abstract

A switchable ionic rectifier composed of an array of ferroelectric polymer nanopore structures was demonstrated. The ferroelectric polarization established an asymmetric potential and ionic charge distribution, which couples to the movement of ionic charges through nanopores and leads to unidirectional current flow or rectification. This rectifier is stable, with rectification characteristics maintained for at least tens of hours, does not require chemical functionalization of nanopores, and, importantly, can reversibly switch the current-rectifying direction by electrical tuning of the ferroelectric polarization states. Finally, reconfigurable nanofluidic logic circuits, specifically, a few types of basic “AND” and “OR” gates, are assembled.
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Research context

OpenAlex topics: Nanopore and Nanochannel Transport Studies · Fuel Cells and Related Materials · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China

Laboratory of Theoretical and Computational Nanoscience, CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China

University of Chinese Academy of Sciences, Beijing 100049, China

Funding

National Natural Science Foundation of China · Chinese Academy of Sciences

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