journal article·2015-04

TiO2 nanopores with high sensitivity to ultraviolet light

D.F. Rodríguez, P.M. Perillo

Optical Materials· Volume 42
Publisher page

Abstract

Abstract We investigated the UV photoconductivity and transient response of TiO2 nanopores on silicon substrate. Ti thin films were first deposited by radio-frequency (RF) magnetron sputtering and then anodized in glycerol electrolytes containing ammonium fluoride (NH4F). For the UV irradiation, the rise and decay curves of photocurrent are well fitted to a bi-exponential function. In both cases, the photocurrent was dominated by an initial fast response about 2 s. The ohmic I–V characteristic of the TiO2 nanopores under illumination could be ascribed to the decrease of the Schottky barrier height, to the accumulation of conduction electrons, resulted from the neutralization between photogenerated holes and negatively charged oxygen ions. These nanopores arrays could be useful in serving as photodetectors, chemical and biological sensors, and switching devices for nanoscale optoelectronics.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Analytical Chemistry and Sensors · Ion-surface interactions and analysis · Advanced biosensing and bioanalysis techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (23)

Show source-provided references
1. UV light activation of TiO2-doped SnO2 thick film for sensing ethanol at room temperature10.2320/matertrans.MC200904 ↗
2. A review on highly ordered, vertically oriented TiO2 nanotube arrays: fabrication, material properties, and solar energy applications10.1016/j.solmat.2006.04.007 ↗
3. Fabrication of TiO2 nanotubes by anodization of Ti thin film for VOC sensing10.1016/j.tsf.2011.04.183 ↗
4. Grimes · 2009
5. J.M. Macák, Growth of anodic self-organized titanium dioxide nanotube layers, Als Dissertation genehmigt von der Technischen Fakultät der Universität Erlangen-Nürnberg, Erlangen, Germany, 2008, p. 163.
6. Structural characterization and optical property of TiO2 powders prepared by the sol–gel method10.1016/j.ceramint.2014.01.083 ↗
7. A review on TiO2-based nanotubes synthesized via hydrothermal method: formation mechanism, structure modification, and photocatalytic applications10.1016/j.cattod.2013.10.090 ↗
8. Electrospinning of nanofiber: reinventing the wheel10.1002/adma.200400719 ↗
9. Nanostructured materials for photon detection10.1038/nnano.2010.78 ↗
10. Engineering light absorption in semiconductor nanowire devices10.1038/nmat2477 ↗
11. Young · J. Cryst. Growth · 2006 · 293 · 4310.1016/j.jcrysgro.2006.03.059 ↗
12. Sandvik · J. Cryst. Growth · 2001 · 231 · 36610.1016/S0022-0248(01)01467-1 ↗
13. Varenne · Thin Solid Films · 2008 · 516 · 223710.1016/j.tsf.2007.08.008 ↗
14. Fabrication of nanostructured TiO2 by anodization: a comparison between electrolytes and substrates10.1016/j.snb.2007.07.076 ↗
15. On wafer TiO2 nanotube-layer formation by anodization of Ti-films on Si10.1016/j.cplett.2006.07.062 ↗
16. Titanium oxide nanotube arrays prepared by anodic oxidation10.1557/JMR.2001.0457 ↗
17. Fabrication and characterization of highly-ordered titania nanotubes via electrochemical anodization10.1016/j.matlet.2008.01.015 ↗
18. Anodic growth of self-organized anodic TiO2 nanotubes in viscous electrolytes10.1016/j.electacta.2006.07.021 ↗
19. Smooth anodic TiO2 nanotubes: annealing and structure10.1002/pssa.200622214 ↗
20. Effect of heat treatment on the properties and structure of TiO2 nanotubes: phase composition and chemical composition10.1002/sia.3183 ↗
21. Nano-sized blue spectral shift in sol–gel derived mesoporous titania films10.1007/s10971-011-2634-1 ↗
22. Photoinduced effect in TiO2 nanocrystaline films with different morphology10.1016/j.jallcom.2010.08.135 ↗
23. Toward a systematic understanding of photodetectors based on individual metal oxide nanowires10.1021/jp804614q ↗