Optical and photocatalytic properties of conjugated-organic-templates derived semiconducting iodocuprates hybrids
Source abstract
Abstract
Abstract Two iodocuprates hybrids, [Me3TPB][Cu5I8] (1, Me3(TPB) = N,N′,N″-trimethyl-1,3,5-tris(4-pyridyl)benzene) and [Me3TIB]2[Cu15I21] (2, Me3(TIB) = N,N′,N″-trimethyl-1,3,5-tris(1-imidazolyl)benzene), directed by in-situ N-alkylation conjugated-organic-templates were solvothermally achieved. 1 features a one-dimensional (1-D) anionic chain built by {Cu5} clusters. 2 exhibits a 2-D layered network based on a rare {Cu15} cluster. 1 is expressed as the first case of halometallate based on TPB. Compared with raw material CuI, both of them possess narrower band gaps and show potential semiconductor properties, which lead to the efficient and stable photocatalytic behavior of 1 under visible-light irradiation. This work further demonstrates that the introduction of conjugated organic templates is beneficial to generating of semiconducting halometallates with narrow band gaps.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanocluster Synthesis and Applications · Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
Show source-provided references
1. Structural overview and structure–property relationships of iodoplumbate and iodobismuthate10.1016/j.ccr.2009.08.003 ↗
2. Hybrid organic-inorganic perovskites (HOIPs): opportunities and challenges10.1002/adma.201502294 ↗
3. The renaissance of halide perovskites and their evolution as emerging semiconductors10.1021/acs.accounts.5b00229 ↗
4. A photoferroelectric perovskite-type organometallic halide with exceptional anisotropy of bulk photovoltaic effects10.1002/anie.201601933 ↗
5. Semiconductive nanotube Array constructed from giant [Pb(II)18I54(I2)9] wheel clusters10.1002/anie.201507083 ↗
6. Photochromism of a methyl viologen bismuth(III) chloride: structural variation before and after UV irradiation10.1002/anie.200700122 ↗
7. Wavelength-dependent photochromic inorganic-organic hybrid based on a 3D iodoplumbate open-framework material10.1002/anie.200800603 ↗
8. Novel 3D semiconducting open-frameworks based on cuprous bromides with visible light driven photocatalytic properties10.1002/chem.201702736 ↗
9. Semiconductive 3-D haloplumbate framework hybrids with high color rendering index white-light emission10.1039/C5SC02501J ↗
10. Luminescent MTN-type cluster-organic framework with 2.6 nm cages10.1021/ja308801n ↗
11. A 3D haloplumbate framework constructed from unprecedented lindqvist-like highly coordinated [Pb6Br25]13- nanoclusters with temperature-dependent emission10.1002/asia.201801292 ↗
12. Control of perovskite crystal growth by methylammonium lead chloride templating10.1002/asia.201501379 ↗
13. [C6H14N]PbBr3: AnABX3-T ype semiconducting perovskite hybrid with above-room-T emperature phase transition10.1002/asia.201701588 ↗
14. Chemically diverse and multifunctional hybrid organic–inorganic perovskites10.1038/natrevmats.2016.99 ↗
15. A series of iodoargentates directed by solvated metal cations featuring uptake and photocatalytic degradation of organic dye pollutants10.1002/asia.201801920 ↗
16. Five monocyclic pyridinium derivative based halo-argentate/cuprate hybrids or iodide salts: influence of composition on photochromic behaviors10.1039/C8DT02574F ↗
17. Do alkyl groups on aromatic or aliphatic structure directing agents affect water stabilities and properties of hybrid iodoargentates?10.1039/C7DT02152F ↗
18. A new class of cuprous bromide cluster-based hybrid materials: direct observation of the stepwise replacement of hydrogen bonds by coordination bonds10.1021/ic5024168 ↗
19. Variable temperature and high-pressure crystal chemistry of perovskite formamidinium lead iodide: a single crystal X-ray diffraction and computational study10.1039/C7CC00995J ↗
20. Copper(I) halides: a versatile family in coordination chemistry and crystal engineering10.1016/j.ccr.2009.10.003 ↗
21. Novel three-dimensional semiconducting materials based on hybrid d(10) transition metal halogenides as visible light-driven photocatalysts10.1021/acs.inorgchem.7b01171 ↗
22. Cu3I7 trimer and Cu4I8 tetramer based cuprous iodide polymorphs for efficient photocatalysis and luminescent sensing: unveiling possible hierarchical assembly mechanism10.1021/ic500822w ↗
23. Low-bandgap Cs4CuSb2Cl12 layered double perovskite: synthesis, reversible thermal changes, and magnetic interaction10.1002/asia.201800635 ↗
24. [Co(phen3)]2[Cu11I15]: a mixed-metal iodocuprate containing the novel [Cu10I15]5- and [Cu12I15]3- clusters10.1039/b716031c ↗
25. Tripyridine-Derivative-derived semiconducting iodo-argentate/cuprate hybrids with excellent visible-light-induced photocatalytic performance10.1002/asia.201801555 ↗
26. In situ ligand modification strategy for the construction of one-, two-, and three-dimensional heterometallic iodides10.1021/acs.inorgchem.7b01807 ↗
27. Ultrasensitive photochromic iodocuprate(I) hybrid10.1021/acs.inorgchem.6b01599 ↗
28. Recent advances in zeolite-like cluster organic frameworks10.1002/chem.201803204 ↗
29. Host-guest engineering of coordination polymers for highly tunable luminophores based on charge transfer emissions10.1021/acsami.6b14554 ↗
30. J. Schmedt auf der Gunne, S. Dehnen, Formation of a strandlike polycatenane of icosahedral cages for reversible one-dimensional encapsulation of guests10.1021/ja2030273 ↗
31. Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties10.1039/C8DT02761G ↗
32. 3D inorganic cuprous iodide open-framework templated by in situ N-methylated 2,4,6-Tri(4-pyridyl)-1,3,5-triazine10.1021/acs.cgd.7b00296 ↗
33. Syntheses, structures and efficient visible light-driven photocatalytic properties of layered cuprous halides based on two types of building units10.1039/C7DT04733A ↗
34. Sheldrick · 1997
35. Sheldrick · 1997
36. New discrete iodometallates with in situ generated triimidazole derivatives as counteractions (Mn+= Ag+, Pb2+, Bi3+)10.1039/C6RA27510A ↗
37. Reactivity of CuI and CuBr toward dialkyl sulfides RSR: from discrete molecular Cu4I4S4 and Cu8I8S6 clusters to luminescent copper(I) coordination polymers10.1021/acs.inorgchem.5b00327 ↗
38. TOPOS 3.2—a new version of the program package for multipurpose crystal-chemical analysis10.1107/S0021889800007202 ↗
39. Wendlandt · 1966
40. Observation of microwave conductivity in copper iodide films and relay effect in the dye molecules attached to CuI photocathode10.1016/j.jssc.2005.07.015 ↗
41. Triiodide-induced band-edge reconstruction of a lead-free perovskite-derivative hybrid for strong light absorption10.1021/acs.chemmater.8b01200 ↗
42. Exploring a lead-free semiconducting hybrid ferroelectric with a zero-dimensional perovskite-like structure10.1002/anie.201606079 ↗
43. Structural and functional modulation of five 4-cyanopyridinium iodoargentates built up from cubane-like Ag4I4 nodes10.1021/cg5010769 ↗
44. Accelerated photocatalytic degradation of organic pollutant over metal-organic framework MIL-53(Fe) under visible LED light mediated by persulfate10.1016/j.apcatb.2016.09.005 ↗
45. Magnetic CoFe2O4 nanoparticles supported on titanate nanotubes (CoFe2O4/TNTs) as a novel heterogeneous catalyst for peroxymonosulfate activation and degradation of organic pollutants10.1016/j.jhazmat.2016.01.035 ↗
46. Symmetrically related construction and optical properties of two noncentrosymmetric 3D iodides of d(10) cation (Cu+, Ag+) based on the N-benzylpyridinium and its supramolecular interactions10.1021/acs.inorgchem.5b01331 ↗