journal article·2019-04-11Open access

Plasmon-enhanced light–matter interactions and applications

Huakang Yu, Yusi Peng, Yong Yang, Zhi-Yuan Li

npj Computational Materials· Volume 5· Issue 1

Abstract

Abstract Surface plasmons are coherent and collective electron oscillations confined at the dielectric–metal interface. Benefitting from the inherent subwavelength nature of spatial profile, surface plasmons can greatly accumulate the optical field and energy on the nanoscale and dramatically enhance various light–matter interactions. The properties of surface plasmons are strongly related to materials and structures, so that metals, semiconductors and two-dimensional materials with various morphologies and structures can have alternating plasmonic wavelengths ranging from ultraviolet, visible, near infrared to far infrared. Because the electric field can be enhanced by orders of magnitude within plasmonic structures, various light–matter interaction processes including fluorescence, Raman scattering, heat generation, photoacoustic effects, photocatalysis, nonlinear optical conversion, and solar energy conversion, can be significantly enhanced and these have been confirmed by both theoretical, computational and experimental studies. In this review, we present a concise introduction and discussion of various plasmon-enhanced light–matter interaction processes. We discuss the physical and chemical principles, influencing factors, computational and theoretical methods, and practical applications of these plasmon-enhanced processes and phenomena, with a hope to deliver guidelines for constructing future high-performance plasmonic devices and technologies.
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Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Plasmonic and Surface Plasmon Research · Nanoplatforms for cancer theranostics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. El-sayed, M. A. & Stephan, L. Shape and size dependence of radiative, non-radiative and photothermal properties of gold nanocrystals. Int. Rev. Phys. Chem. 19, 409–453 (2000).10.1080/01442350050034180 ↗
2. Tian, Z. Q., Ren, B. & Wu, D. Y. Surface-enhanced Raman scattering: from noble to transition metals and from rough surfaces to ordered nanostructures. J. Phys. Chem. B 106, 37 (2002).
3. Maier, S. A. & Atwater, H. A. Plasmonics: localization and guiding of electromagnetic energy in metal dielectric structures. J. Appl. Phys. 98, 011101 (2005).10.1063/1.1951057 ↗
4. Willets, K. A. & Van Duyne, R. P. Localized surface plasmon resonance spectroscopy and sensing. Annu. Rev. Phys. Chem. 58, 267–297 (2007).10.1146/annurev.physchem.58.032806.104607 ↗
5. Jain, P. K., Huang, X. & El-sayed, I. H. Noble metals on the nanoscale: optical and photothermal properties and some applications in imaging, sensing, biology, and medicine. Acc. Chem. Res. 41, 1578–1586 (2008).10.1021/ar7002804 ↗
6. Skrabalak, S. E. et al. Gold nanocages: synthesis, properties, and applications. Acc. Chem. Res. 41, 1587–1595 (2008).10.1021/ar800018v ↗
7. Stiles, P. L., Dieringer, J. A., Shah, N. C. & Van Duyne, R. P. Surface-enhanced Raman spectroscopy. Annu. Rev. Anal. Chem. 1, 601–626 (2008).10.1146/annurev.anchem.1.031207.112814 ↗
8. Xia, Y., Xiong, Y., Lim, B. & Skrabalak, S. E. Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? Angew. Chem. Int. Ed. Engl. 48, 60–103 (2009).10.1002/anie.200802248 ↗
9. Li, Z. Y. Mesoscopic and microscopic strategies for engineering plasmon-enhanced Raman scattering. Adv. Opt. Mater. 6, 1701097 (2018).10.1002/adom.201701097 ↗
10. West, P. R. et al. Searching for better plasmonic materials. Laser Photon. Rev. 4, 795–808 (2010).10.1002/lpor.200900055 ↗
11. Luther, J. M., Jain, P. K., Ewers, T. & Alivisatos, A. P. Localized surface plasmon resonances arising from free carriers in doped quantum dots. Nat. Mater. 10, 361–366 (2011).10.1038/nmat3004 ↗
12. El-Sayed, M. A. & Lee, K. S. Gold and silver nanoparticles in sensing and imaging sensitivity of plasmon response to size, shape, and metal composition. J. Phys. Chem. B 110, 19220–19225 (2006).10.1021/jp062536y ↗
13. El-Sayed, M. A., Link, S. & Wang, Z. L. Alloy formation of gold−silver nanoparticles and the dependence of the plasmon absorption on their composition. J. Phys. Chem. B 103, 3529–3533 (1999).10.1021/jp990387w ↗
14. Verbruggen, S. W., Keulemans, M., Martens, J. A. & Lenaerts, S. Predicting the surface plasmon resonance wavelength of gold–silver alloy nanoparticles. J. Phys. Chem. C 117, 19142–19145 (2013).10.1021/jp4070856 ↗
15. Wiley, B. J. et al. Maneuvering the surface plasmon resonance of silver nanostructures through shape-controlled synthesis. J. Phys. Chem. B 110, 15666–15675 (2006).10.1021/jp0608628 ↗
16. Nie, S. M. & Emory, S. R. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science 275, 1102 (1997).10.1126/science.275.5303.1102 ↗
17. Kneipp, K., Wang, Y. & Kneipp, H. Single molecule detection using surface-enhanced Raman scattering (SERS). Phys. Rev. Lett. 78, 1667 (1997).10.1103/PhysRevLett.78.1667 ↗
18. Yang, Y. et al. Controlled fabrication of silver nanoneedles array for SERS and their application in rapid detection of narcotics. Nanoscale 4, 2663–2669 (2012).10.1039/c2nr12110g ↗
19. Wang, X. J. & Feng, J. Anisotropically shaped magnetic plasmonic nanocomposites for information encryption and magnetic-field-direction sensing. Research 2018, 7527825 (2018).
20. Faucheaux, J. A., Stanton, A. L. & Jain, P. K. Plasmon resonances of semiconductor nanocrystals: physical principles and new opportunities. J. Phys. Chem. Lett. 5, 976–985 (2014).10.1021/jz500037k ↗
21. Yang, L. L., Peng, Y. S. & Yang, Y. Green and sensitive flexible semiconductor SERS substrates hydrogenated black TiO2 nanowires. ACS Appl. Nano Mater. 1, 4516–4527 (2018).10.1021/acsanm.8b00796 ↗
22. Guo, Q. et al. Infrared nanophotonics based on graphene plasmonics. ACS Photon. 4, 2989–2999 (2017).10.1021/acsphotonics.7b00547 ↗
23. Bao, Q., Zhang, H. & Wang, Y. Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers. Adv. Funct. Mater. 19, 3077–3083 (2009).10.1002/adfm.200901007 ↗
24. Yan, H. et al. Damping pathways of mid-infrared plasmons in graphene nanostructures. Nat. Photon. 7, 394–399 (2013).10.1038/nphoton.2013.57 ↗
25. Lopez, J. J. et al. Large photothermal effect in sub-40 nm h-BN nanostructures patterned via high-resolution ion beam. Small 14, 1800072 (2018).10.1002/smll.201800072 ↗
26. Jiang, J., Lin, X. & Zhang, B. Broadband negative refraction of highly squeezed hyperbolic polaritons in 2D materials. Research 2018, 1–7 (2018).10.1155/2018/2532819 ↗
27. Lin, X. et al. All-angle negative refraction of highly squeezed plasmon and phonon polaritons in graphene-boron nitride heterostructures. Proc. Natl Acad. Sci. 114, 6717–6721 (2017).10.1073/pnas.1701830114 ↗
28. Shi, X. et al. Superlight inverse Doppler effect. Nat. Phys. 14, 1001–1005 (2018).10.1038/s41567-018-0209-6 ↗
29. Qian, C. et al. Multifrequency superscattering from subwavelength hyperbolic structures. ACS Photon. 5, 1506–1511 (2018).10.1021/acsphotonics.7b01534 ↗
30. Jiang, Y., Lin, X., Low, T., Zhang, B. & Chen, H. Group-velocity-controlled and gate-tunable directional excitation of polaritons in graphene-boron nitride heterostructures. Laser Photon. Rev. 12, 1800049 (2018).10.1002/lpor.201800049 ↗
31. Soto Lamata, I., Alonso-González, P., Hillenbrand, R. & Nikitin, A. Y. Plasmons in cylindrical 2D materials as a platform for nanophotonic circuits. ACS Photonics 2, 280–286 (2015).10.1021/ph500377u ↗
32. Wang, Y. et al. Plasmon resonances of highly doped two-dimensional MoS2. Nano Lett. 15, 883–890 (2015).10.1021/nl503563g ↗
33. Miao, J. et al. Surface plasmon-enhanced photodetection in few layer MoS2 phototransistors with Au nanostructure arrays. Small 11, 2392–2398 (2015).10.1002/smll.201403422 ↗
34. Liu, Z. & Aydin, K. Localized surface plasmons in nanostructured monolayer black phosphorus. Nano Lett. 16, 3457–3462 (2016).10.1021/acs.nanolett.5b05166 ↗
35. Fang, J. et al. Gold mesostructures with tailored surface topography and their self-assembly arrays for surface-enhanced Raman spectroscopy. Nano Lett. 10, 5006–5013 (2010).10.1021/nl103161q ↗
36. Liu, Z. et al. Highly sensitive, uniform, and reproducible surface-enhanced Raman spectroscopy from hollow Au-Ag alloy nanourchins. Adv. Mater. 26, 2431–2439 (2014).10.1002/adma.201305106 ↗
37. Li, J. F., Li, C. Y. & Aroca, R. F. Plasmon-enhanced fluorescence spectroscopy. Chem. Soc. Rev. 46, 3962–3979 (2017).10.1039/C7CS00169J ↗
38. Chen, H. J., Ming, T., Zhao, L. & Wang, F. Plasmon–molecule interactions. Nano Today. 5, 494–505 (2010).10.1016/j.nantod.2010.08.009 ↗
39. Chen, Y., Munechika, K. & Ginger, D. S. Dependence of fluorescence intensity on the spectral overlap between fluorophores and plasmon resonant single silver nanoparticles. Nano Lett. 7, 690–699 (2007).10.1021/nl062795z ↗
40. Liu, S. Y., Huang, L. & Li, J. F. Simultaneous excitation and emission enhancement of fluorescence assisted by double plasmon modes of gold nanorods. J. Phys. Chem. C 117, 10636–10642 (2013).10.1021/jp4001626 ↗
41. Zhang, H. et al. Surface-plasmon-enhanced GaN-LED based on a multilayered M-shaped nano-grating. Opt. Express 21, 13492–13501 (2013).10.1364/OE.21.013492 ↗
42. Shen, Y. R. The Principles of Nonlinear Optics. (Wiley-Interscience, New York, 1984).
43. Boyd, R. W. Nonlinear Optics. (Elsevier, Cambridge, 2003).
44. Moskovits, M. Surface-enhanced spectroscopy. Rev. Mod. Phys. 57, 783 (1985).10.1103/RevModPhys.57.783 ↗
45. Otto, A., Mrozek, I., Grabhorn, H. & Akemann, W. Surface-enhanced Raman scattering. J. Phys. Condens. Mater. 4, 1143 (1992).10.1088/0953-8984/4/5/001 ↗
46. Campion, A. & Kambhampati, P. Surface-enhanced Raman scattering. Chem. Soc. Rev. 27, 241–250 (1998).10.1039/a827241z ↗
47. Pettinger, B., Schambach, P., Villagómez, C. J. & Scott, N. Tip-enhanced Raman spectroscopy: near-fields acting on a few molecules. Annu. Rev. Phys. Chem. 63, 379–399 (2012).10.1146/annurev-physchem-032511-143807 ↗
48. Schmid, T., Opilik, L., Blum, C. & Zenobi, R. Nanoscale chemical imaging using tip-enhanced Raman spectroscopy: a critical review. Angew. Chem. Int. Ed. 52, 5940–5954 (2013).10.1002/anie.201203849 ↗
49. Zhang, Z., Sheng, S., Wang, R. & Sun, M. Tip-enhanced Raman spectroscopy. Anal. Chem. 88, 9328–9346 (2016).10.1021/acs.analchem.6b02093 ↗
50. Zrimsek, A. B. et al. Single-molecule chemistry with surface-and tip-enhanced Raman spectroscopy. Chem. Rev. 117, 7583–7613 (2016).10.1021/acs.chemrev.6b00552 ↗
51. Shi, X., Coca-López, N. S., Janik, J. & Hartschuh, A. Advances in tip-enhanced near-field Raman microscopy using nanoantennas. Chem. Rev. 117, 4945–4960 (2017).10.1021/acs.chemrev.6b00640 ↗
52. Verma, P. Tip-enhanced Raman spectroscopy: technique and recent advances. Chem. Rev. 117, 6447–6466 (2017).10.1021/acs.chemrev.6b00821 ↗
53. Richard-Lacroix, M., Zhang, Y., Dong, Z. & Deckert, V. Mastering high resolution tip-enhanced Raman spectroscopy: towards a shift of perception. Chem. Soc. Rev. 46, 3922–3944 (2017).10.1039/C7CS00203C ↗
54. Wang, X. et al. Tip-enhanced Raman spectroscopy for surfaces and interfaces. Chem. Soc. Rev. 46, 4020–4041 (2017).10.1039/C7CS00206H ↗
55. McLellan, J. M., Li, Z. Y., Siekkinen, A. R. & Xia, Y. N. The SERS activity of a supported Ag nanocube strongly depends on its orientation relative to laser polarization. Nano Lett. 7, 1013–1017 (2007).10.1021/nl070157q ↗
56. Wiley, B. J. et al. Synthesis and optical properties of silver nanobars and nanorice. Nano Lett. 7, 1032–1036 (2007).10.1021/nl070214f ↗
57. Rycenga, M. et al. Generation of hot spots with silver nanocubes for single-molecule detection by surface-enhanced Raman scattering. Angew. Chem. Int. Ed. 50, 5473–5477 (2011).10.1002/anie.201101632 ↗
58. Ma, Y. et al. Au@ Ag core–shell nanocubes with finely tuned and well-controlled sizes, shell thicknesses, and optical properties. ACS Nano 4, 6725–6734 (2010).10.1021/nn102237c ↗
59. Xiong, Y. et al. Kinetically controlled synthesis of triangular and hexagonal nanoplates of palladium and their SPR/SERS properties. J. Am. Chem. Soc. 127, 17118–17127 (2005).10.1021/ja056498s ↗
60. Zettsu, N. et al. Synthesis, stability, and surface plasmonic properties of rhodium multipods, and their use as substrates for surface-enhanced Raman scattering. Angew. Chem. 118, 1310–1314 (2006).10.1002/ange.200503174 ↗
61. Rang, M. et al. Optical near-field mapping of plasmonic nanoprisms. Nano Lett. 8, 3357–3363 (2008).10.1021/nl801808b ↗
62. Cobley, C. M., Rycenga, M., Zhou, F., Li, Z. Y. & Xia, Y. N. Etching and growth: an intertwined pathway to silver nanocrystals with exotic shapes. Angew. Chem. 121, 4918–4921 (2009).10.1002/ange.200901447 ↗
63. Zhou, F., Li, Z. Y., Liu, Y. & Xia, Y. N. Quantitative analysis of dipole and quadrupole excitation in the surface plasmon resonance of metal nanoparticles. J. Phys. Chem. C 112, 20233–20240 (2008).10.1021/jp807075f ↗
64. Fei, Z., Ye, L. & Zhi-Yuan, L. Simultaneous low extinction and high local field enhancement in Ag nanocubes. Chin. Phys. B 20, 037303 (2011).10.1088/1674-1056/20/3/037303 ↗
65. Li, Q. et al. High Surface-enhanced raman scattering performance of individual gold nanoflowers and their application in live cell imaging. Small 9, 927–932 (2013).10.1002/smll.201201065 ↗
66. Shan, Y. F., Zhen, Z. H. & Liu, J. J. Niobium pentoxide: a promising surface-enhanced Raman scattering active semiconductor substrate. npj Comput. Mater. 3, 11 (2017).10.1038/s41524-017-0008-0 ↗
67. Li, Z. Y. & Xia, Y. N. Metal nanoparticles with gain toward single-molecule detection by surface-enhanced Raman scattering. Nano Lett. 10, 243–249 (2009).10.1021/nl903409x ↗
68. Liu, S. Y., Li, J., Zhou, F., Gan, L. & Li, Z.-Y. Efficient surface plasmon amplification from gain-assisted gold nanorods. Optics Lett. 36, 1296–1298 (2011).10.1364/OL.36.001296 ↗
69. Zhang, R. et al. Chemical mapping of a single molecule by plasmon-enhanced Raman scattering. Nature 498, 82 (2013).10.1038/nature12151 ↗
70. Duan, S. et al. Theoretical modeling of plasmon-enhanced Raman images of a single molecule with subnanometer resolution. J. Am. Chem. Soc. 137, 9515–9518 (2015).10.1021/jacs.5b03741 ↗
71. Zhang, C., Chen, B. Q. & Li, Z. Y. Optical origin of subnanometer resolution in tip-enhanced Raman mapping. J. Phys. Chem. C 119, 11858–11871 (2015).10.1021/acs.jpcc.5b02653 ↗
72. Zhang, C., Chen, B. Q. & Li, Z. Y. Influence of tip geometry on the spatial resolution of tip enhanced Raman mapping. Chin. Phys. B 25, 095203 (2016).10.1088/1674-1056/25/9/095203 ↗
73. Chen, B. Q., Zhang, C., Li, J., Li, Z. Y. & Xia, Y. N. On the critical role of Rayleigh scattering in single-molecule surface-enhanced Raman scattering via a plasmonic nanogap. Nanoscale 8, 15730–15736 (2016).10.1039/C6NR04574J ↗
74. Govorov, A. O. & Richardson, H. H. Generating heat with metal nanoparticles. Nano Today 2, 30–38 (2007).10.1016/S1748-0132(07)70017-8 ↗
75. Baffou, G. & Quidant, R. Thermo-plasmonics: using metallic nanostructures as nano-sources of heat. Laser Photon. Rev. 7, 171–187 (2013).10.1002/lpor.201200003 ↗
76. Brongersma, M. L., Halas, N. J. & Nordlander, P. Plasmon-induced hot carrier science and technology. Nat. Nanotech. 10, 25 (2015).10.1038/nnano.2014.311 ↗
77. Link, S., Burda, C., Mohamed, M., Nikoobakht, B. & El-Sayed, M. A. Laser photothermal melting and fragmentation of gold nanorods: energy and laser pulse-width dependence. J. Phys. Chem. A 103, 1165–1170 (1999).10.1021/jp983141k ↗
78. Link, S., Burda, C., Nikoobakht, B. & El-Sayed, M. A. Laser-induced shape changes of colloidal gold nanorods using femtosecond and nanosecond laser pulses. J. Phys. Chem. B 104, 6152–6163 (2000).10.1021/jp000679t ↗
79. Richardson, H. H., Thomas, A. C., Carlson, M. T., Kordesch, M. E. & Govorov, A. O. Thermo-optical responses of nanoparticles: Melting of ice and nanocalorimetry approach. J. Eelectron. Mater. 36, 1587–1593 (2007).10.1007/s11664-007-0279-1 ↗
80. Wang, J. et al. Photothermal reshaping of gold nanoparticles in a plasmonic absorber. Opt. Express 19, 14726–14734 (2011).10.1364/OE.19.014726 ↗
81. Chen, X., Chen, Y., Yan, M. & Qiu, M. Nanosecond photothermal effects in plasmonic nanostructures. ACS Nano 6, 2550–2557 (2012).10.1021/nn2050032 ↗
82. González-Rubio, G. et al. Femtosecond laser-controlled tip-to-tip assembly and welding of gold nanorods. Nano Lett. 15, 8282–8288 (2015).10.1021/acs.nanolett.5b03844 ↗
83. González-Rubio, G. et al. Femtosecond laser reshaping yields gold nanorods with ultranarrow surface plasmon resonances. Science 358, 640–644 (2017).10.1126/science.aan8478 ↗
84. Liu, G. L., Kim, J., Lu, Y. & Lee, L. P. Optofluidic control using photothermal nanoparticles. Nat. Mater. 5, 27 (2006).10.1038/nmat1528 ↗
85. Boyd, D. A., Adleman, J. R., Goodwin, D. G. & Psaltis, D. Chemical separations by bubble-assisted interphase mass-transfer. Anal. Chem. 80, 2452–2456 (2008).10.1021/ac702174t ↗
86. Volkov, A. N., Sevilla, C. & Zhigilei, L. V. Numerical modeling of short pulse laser interaction with Au nanoparticle surrounded by water. Appl. Surf. Sci. 253, 6394–6399 (2007).10.1016/j.apsusc.2007.01.112 ↗
87. Doane, T. L. & Burda, C. The unique role of nanoparticles in nanomedicine: imaging, drug delivery and therapy. Chem. Soc. Rev. 41, 2885–2911 (2012).10.1039/c2cs15260f ↗
88. Kim, C., Favazza, C. P. & Wang, L. V. In vivo photoacoustic tomography of chemicals: high-resolution functional and molecular optical imaging at new depths. Chem. Rev. 110, 2756–2782 (2010).10.1021/cr900266s ↗
89. Boyer, D., Tamarat, P., Maali, A., Lounis, B. & Orrit, M. Photothermal imaging of nanometer-sized metal particles among scatterers. Science 297, 1160–1163 (2002).10.1126/science.1073765 ↗
90. Zharov, V. P. & Lapotko, D. O. Photothermal imaging of nanoparticles and cells. IEEE J. Sel. Top. Quant. 11, 733–751 (2005).10.1109/JSTQE.2005.857382 ↗
91. Hu, M. et al. Gold nanostructures: engineering their plasmonic properties for biomedical applications. Chem. Soc. Rev. 35, 1084–1094 (2006).10.1039/b517615h ↗
92. Hirsch, L. R. et al. Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance. Proc. Natl Acad. Sci. 100, 13549–13554 (2003).10.1073/pnas.2232479100 ↗
93. Huang, X., El-Sayed, I. H., Qian, W. & El-Sayed, M. A. Cancer cell imaging and photothermal therapy in the near-infrared region by using gold nanorods. J. Am. Chem. Soc. 128, 2115–2120 (2006).10.1021/ja057254a ↗
94. Pissuwan, D., Valenzuela, S. M. & Cortie, M. B. Therapeutic possibilities of plasmonically heated gold nanoparticles. Trends Biotechnol. 24, 62–67 (2006).10.1016/j.tibtech.2005.12.004 ↗
95. Chen, J. et al. Immuno gold nanocages with tailored optical properties for targeted photothermal destruction of cancer cells. Nano Lett. 7, 1318–1322 (2007).10.1021/nl070345g ↗
96. Gobin, A. M. et al. Near-infrared resonant nanoshells for combined optical imaging and photothermal cancer therapy. Nano Lett. 7, 1929–1934 (2007).10.1021/nl070610y ↗
97. Au, L. et al. A quantitative study on the photothermal effect of immuno gold nanocages targeted to breast cancer cells. ACS Nano 2, 1645–1652 (2008).10.1021/nn800370j ↗
98. Wang, Y. et al. Comparison study of gold nanohexapods, nanorods, and nanocages for photothermal cancer treatment. ACS Nano 7, 2068–2077 (2013).10.1021/nn304332s ↗
99. Sershen, S., Westcott, S., Halas, N. & West, J. Temperature-sensitive polymer-nanoshell composites for photothermally modulated drug delivery. J. Biomed. Mater. Res. A 51, 293–298 (2000).10.1002/1097-4636(20000905)51:3<293::AID-JBM1>3.0.CO;2-T ↗
100. Skirtach, A. G. et al. The role of metal nanoparticles in remote release of encapsulated materials. Nano Lett. 5, 1371–1377 (2005).10.1021/nl050693n ↗