Photo-magnetization in two-dimensional sliding ferroelectrics

Abstract Light–matter interaction is one of the key routes to understanding and manipulating geometric and electronic behaviors of materials, especially two-dimensional materials which are optically accessible owing to their high surface to volume ratio. In the current work, we focus on the recently discovered two-dimensional sliding ferroelectric materials, in which the out-of-plane electric polarization can be switched with a small horizontal translation in one layer. Combining symmetry analysis and first-principles calculations, we predict that light illumination could inject non-equilibrium magnetic moments into the sliding ferroelectrics. Such magnetic moment is composed of both spin and orbital degrees of freedom contributions. We use ZrI₂, WTe₂, and MoS₂ bilayer ferroelectrics to illustrate our theory. Under intermediate light illumination, one can yield non-equilibrium magnetic moments on the order of 0.1–1 μ_B in these systems, which also depends on the polarization nature of incident light. Furthermore, we show that such photo-injected magnetism changes its sign when the sliding dipole moment switches. This photo-magnetization can be detected by magneto-optical methods (such as Kerr or Faraday effect), which serves as an indicator of sliding ferroelectricity. Hence, one can use an all-optical pump and probe setup to measure and detect the subtle sliding ferroelectric phase.