journal article·2023-06-23

Hollow ZnWO4/In2O3 Nanotubes for Ultrasensitive and Rapid Trace Detection of Triethylamine

Duo Sun, QiLin Wang, Wei Wang, Yu Chen, Shengping Ruan

ACS Applied Nano Materials· Volume 6· Issue 12
Publisher page

Abstract

The directional modulation of metal oxide semiconductors (MOSs) can be effective in developing high-performance gas-sensing materials. Herein, we propose an efficient strategy by modifying ZnWO 4 on In 2 O 3 to achieve controllable modulation of oxygen vacancies and energy band structures in ZnWO 4 /In 2 O 3 heterostructures. The sensor based on optimized ZnWO 4 /In 2 O 3 exhibits significantly enhanced performance to detect triethylamine, including a lower operating temperature (100 °C), a higher responsivity (R a /R g = 221.2 for 100 ppm), and a lower detection limit (500 ppb). In addition, the fabricated sensor exhibits faster response and good selectivity. The improved gas-sensing performance could be attributed to the acid–base interaction between triethylamine gas and ZnWO 4, the formation of heterojunctions, and the increase of oxygen vacancies to achieve a synergistic modulation of the chemical and energy band structures. It is anticipated that our current investigation could offer insights and a useful strategy for triethylamine detection.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Advanced Chemical Sensor Technologies · Analytical Chemistry and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory on Integrated Optoelectronics, College of Electronic Science & Engineering, Jilin University, Changchun 130012, P. R. China

Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, P. R. China

Funding

Jilin Scientific and Technological Development Program · National Natural Science Foundation of China

References (49)

Show source-provided references
1. 10.1016/j.snb.2021.13001510.1016/j.snb.2021.130015 ↗
2. 10.1016/j.snb.2021.13048610.1016/j.snb.2021.130486 ↗
3. 10.1016/j.snb.2021.13069810.1016/j.snb.2021.130698 ↗
4. 10.1039/d1ta00694k10.1039/d1ta00694k ↗
5. 10.1016/j.snb.2021.13011510.1016/j.snb.2021.130115 ↗
6. 10.1016/j.snb.2022.13170710.1016/j.snb.2022.131707 ↗
7. 10.1016/j.apsusc.2022.15375210.1016/j.apsusc.2022.153752 ↗
8. 10.1016/j.chemosphere.2021.13271510.1016/j.chemosphere.2021.132715 ↗
9. 10.1016/j.jallcom.2021.16001510.1016/j.jallcom.2021.160015 ↗
10. 10.1021/acsanm.0c0173110.1021/acsanm.0c01731 ↗
11. 10.1016/j.snb.2021.13031610.1016/j.snb.2021.130316 ↗
12. 10.1016/j.snr.2021.10006410.1016/j.snr.2021.100064 ↗
13. 10.1109/tnano.2017.278922510.1109/tnano.2017.2789225 ↗
14. 10.1016/j.ceramint.2019.01.26810.1016/j.ceramint.2019.01.268 ↗
15. 10.1002/slct.20170175210.1002/slct.201701752 ↗
16. 10.1109/tim.2021.309785810.1109/tim.2021.3097858 ↗
17. 10.1016/j.snb.2017.10.13910.1016/j.snb.2017.10.139 ↗
18. 10.1016/j.snb.2022.13198710.1016/j.snb.2022.131987 ↗
19. 10.1016/j.cattod.2021.09.01210.1016/j.cattod.2021.09.012 ↗
20. 10.1016/j.heliyon.2022.e0996410.1016/j.heliyon.2022.e09964 ↗
21. 10.1039/d1ta02618f10.1039/d1ta02618f ↗
22. 10.1002/anie.20080383710.1002/anie.200803837 ↗
23. 10.1016/j.snb.2019.12703710.1016/j.snb.2019.127037 ↗
24. 10.1016/j.snb.2021.13012610.1016/j.snb.2021.130126 ↗
25. 10.1039/d1tc00983d10.1039/d1tc00983d ↗
26. 10.1021/acsami.9b1659910.1021/acsami.9b16599 ↗
27. 10.1016/j.snb.2022.13312510.1016/j.snb.2022.133125 ↗
28. 10.1016/j.snb.2021.12999010.1016/j.snb.2021.129990 ↗
29. 10.1016/j.jpcs.2022.11106110.1016/j.jpcs.2022.111061 ↗
30. 10.1038/s41467-019-10302-010.1038/s41467-019-10302-0 ↗
31. 10.1021/jacs.5b1218910.1021/jacs.5b12189 ↗
32. 10.1016/j.snb.2020.12881410.1016/j.snb.2020.128814 ↗
33. 10.1016/j.ceramint.2019.07.14110.1016/j.ceramint.2019.07.141 ↗
34. 10.1016/j.snb.2021.13086710.1016/j.snb.2021.130867 ↗
35. 10.1016/j.snb.2022.13272210.1016/j.snb.2022.132722 ↗
36. 10.1016/j.snb.2022.13225610.1016/j.snb.2022.132256 ↗
37. 10.1016/j.jallcom.2020.15754510.1016/j.jallcom.2020.157545 ↗
38. 10.1016/j.jallcom.2020.15471310.1016/j.jallcom.2020.154713 ↗
39. 10.1016/j.snb.2022.13141410.1016/j.snb.2022.131414 ↗
40. 10.1016/j.jallcom.2016.11.38010.1016/j.jallcom.2016.11.380 ↗
41. 10.1016/j.snb.2009.06.04910.1016/j.snb.2009.06.049 ↗
42. 10.1016/j.snb.2020.12927110.1016/j.snb.2020.129271 ↗
43. 10.1016/j.surfin.2017.12.00510.1016/j.surfin.2017.12.005 ↗
44. 10.1016/j.snb.2020.12921810.1016/j.snb.2020.129218 ↗
45. 10.1039/c5ta08873a10.1039/c5ta08873a ↗
46. 10.1021/acsanm.9b0207210.1021/acsanm.9b02072 ↗
47. 10.1016/j.jhazmat.2022.12883610.1016/j.jhazmat.2022.128836 ↗
48. 10.1016/j.snb.2020.12819110.1016/j.snb.2020.128191 ↗
49. 10.1002/adma.20180716110.1002/adma.201807161 ↗