Laser-Controlled Charge Transfer in a Two-Dimensional Organic/Inorganic Optical Coherent Nanojunction

Understanding the fundamental mechanisms ruling laser-induced coherent charge transfer in hybrid organic/inorganic interfaces is of paramount importance to exploit these systems in next-generation optoelectronic applications. In a first-principles work based on real-time time-dependent density-functional theory, we investigate the ultrafast charge-carrier dynamics of a prototypical two-dimensional vertical nanojunction formed by a MoSe2 monolayer with adsorbed pyrene molecules. The response of the system to the incident pulse, set in resonance with the frequency of the lowest-energy transition in the physisorbed moieties, is clearly nonlinear. Under weak pulses, charge transfer occurs from the molecules to the monolayer, while for intensities higher than 1000 GW/cm2, the direction of charge transfer is reverted, with electrons being transferred from MoSe2 to pyrene. This finding is explained by Pauli blocking: laser-induced (de)population of (valence) conduction states saturates for intensities beyond 200 GW/cm2. Evidence of multiphoton absorption is also provided by our results. A thorough analysis of electronic current density, excitation energy, and number of excited electrons supports the proposed rationale and suggests the possibility to create an inorganic/organic coherent optical nanojunction for ultrafast electronics.