journal article·2024-02Open access

Correlated insulator and Chern insulators in pentalayer rhombohedral-stacked graphene

Tonghang Han, Zhengguang Lu, Giovanni Scuri, Jiho Sung, Jue Wang, Tianyi Han, Kenji Watanabe, Takashi Taniguchi, Hongkun Park, Long Ju

Nature Nanotechnology· Volume 19· Issue 2

Abstract

Rhombohedral-stacked multilayer graphene hosts a pair of flat bands touching at zero energy, which should give rise to correlated electron phenomena that can be tuned further by an electric field. Moreover, when electron correlation breaks the isospin symmetry, the valley-dependent Berry phase at zero energy may give rise to topologically non-trivial states. Here we measure electron transport through hexagonal boron nitride-encapsulated pentalayer graphene down to 100 mK. We observed a correlated insulating state with resistance at the megaohm level or greater at charge density n = 0 and displacement field D = 0. Tight-binding calculations predict a metallic ground state under these conditions. By increasing D, we observed a Chern insulator state with C = -5 and two other states with C = -3 at a magnetic field of around 1 T. At high D and n, we observed isospin-polarized quarter- and half-metals. Hence, rhombohedral pentalayer graphene exhibits two different types of Fermi-surface instability, one driven by a pair of flat bands touching at zero energy, and one induced by the Stoner mechanism in a single flat band. Our results establish rhombohedral multilayer graphene as a suitable system for exploring intertwined electron correlation and topology phenomena in natural graphitic materials without the need for moiré superlattice engineering.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Topological Materials and Phenomena · Quantum and electron transport phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Cao, Y. et al. Correlated insulator behaviour at half-filling in magic-angle graphene superlattices. Nature 556, 80–84 (2018).10.1038/nature26154 ↗
2. Cao, Y. et al. Unconventional superconductivity in magic-angle graphene superlattices. Nature 556, 43–50 (2018).10.1038/nature26160 ↗
3. Sharpe, A. L. et al. Emergent ferromagnetism near three-quarters filling in twisted bilayer graphene. Science 365, 605–608 (2019).10.1126/science.aaw3780 ↗
4. Serlin, M. et al. Intrinsic quantized anomalous Hall effect in a moiré heterostructure. Science 367, 900–903 (2020).10.1126/science.aay5533 ↗
5. Chen, G. et al. Evidence of a gate-tunable Mott insulator in a trilayer graphene moiré superlattice. Nat. Phys. 15, 237–241 (2019).10.1038/s41567-018-0387-2 ↗
6. Chen, G. et al. Signatures of tunable superconductivity in a trilayer graphene moiré superlattice. Nature 572, 215–219 (2019).10.1038/s41586-019-1393-y ↗
7. Chen, G. et al. Tunable correlated Chern insulator and ferromagnetism in a moiré superlattice. Nature 579, 56–61 (2020).10.1038/s41586-020-2049-7 ↗
8. Regan, E. C. et al. Mott and generalized Wigner crystal states in WSe2/WS2 moiré superlattices. Nature 579, 359–363 (2020).10.1038/s41586-020-2092-4 ↗
9. Tang, Y. et al. Simulation of Hubbard model physics in WSe2/WS2 moiré superlattices. Nature 579, 353–358 (2020).10.1038/s41586-020-2085-3 ↗
10. Wang, L. et al. Correlated electronic phases in twisted bilayer transition metal dichalcogenides. Nat. Mater. 19, 861–866 (2020).10.1038/s41563-020-0708-6 ↗
11. Yankowitz, M. et al. Tuning superconductivity in twisted bilayer graphene. Science 363, 1059–1064 (2019).10.1126/science.aav1910 ↗
12. Cao, Y. et al. Tunable correlated states and spin-polarized phases in twisted bilayer–bilayer graphene. Nature 583, 215–220 (2020).10.1038/s41586-020-2260-6 ↗
13. Shen, C. et al. Correlated states in twisted double bilayer graphene. Nat. Phys. 16, 520–525 (2020).10.1038/s41567-020-0825-9 ↗
14. Liu, X. et al. Tunable spin-polarized correlated states in twisted double bilayer graphene. Nature 583, 221–225 (2020).10.1038/s41586-020-2458-7 ↗
15. Polshyn, H. et al. Electrical switching of magnetic order in an orbital Chern insulator. Nature 588, 66–70 (2020).10.1038/s41586-020-2963-8 ↗
16. Chen, G. et al. Tunable orbital ferromagnetism at noninteger filling of a moiré superlattice. Nano Lett. 22, 238–245 (2022).10.1021/acs.nanolett.1c03699 ↗
17. Min, H. & MacDonald, A. H. Electronic structure of multilayer graphene. Prog. Theor. Phys. Suppl. 176, 227–252 (2008).10.1143/PTPS.176.227 ↗
18. Zhang, F., Sahu, B., Min, H. & MacDonald, A. H. Band structure of ABC-stacked graphene trilayers. Phys. Rev. B 82, 035409 (2010).10.1103/PhysRevB.82.035409 ↗
19. Zhang, F., Jung, J., Fiete, G. A., Niu, Q. & MacDonald, A. H. Spontaneous quantum Hall states in chirally stacked few-layer graphene systems. Phys. Rev. Lett. 106, 156801 (2011).10.1103/PhysRevLett.106.156801 ↗
20. Koshino, M. & McCann, E. Trigonal warping and Berry’s phase Nπ in ABC-stacked multilayer graphene. Phys. Rev. B 80, 165409 (2009).10.1103/PhysRevB.80.165409 ↗
21. Yang, N., Li, C., Tang, Y. & Yelgel, C. Electronic structure of ABC-stacked multilayer graphene and trigonal warping: a first principles calculation. J. Phys. Conf. Ser. 707, 012022 (2016).10.1088/1742-6596/707/1/012022 ↗
22. Shi, Y. et al. Electronic phase separation in multilayer rhombohedral graphite. Nature 584, 210–214 (2020).10.1038/s41586-020-2568-2 ↗
23. Zhou, H. et al. Half- and quarter-metals in rhombohedral trilayer graphene. Nature 598, 429–433 (2021).10.1038/s41586-021-03938-w ↗
24. Zhou, H., Xie, T., Taniguchi, T., Watanabe, K. & Young, A. F. Superconductivity in rhombohedral trilayer graphene. Nature 598, 434–438 (2021).10.1038/s41586-021-03926-0 ↗
25. Pierucci, D. et al. Evidence for flat bands near the Fermi level in epitaxial rhombohedral multilayer graphene. ACS Nano 9, 5432–5439 (2015).10.1021/acsnano.5b01239 ↗
26. Kerelsky, A. et al. Moiréless correlations in ABCA graphene. Proc. Natl Acad. Sci. USA 118, e2017366118 (2021).10.1073/pnas.2017366118 ↗
27. Weitz, R. T., Allen, M. T., Feldman, B. E., Martin, J. & Yacoby, A. Broken-symmetry states in doubly gated suspended bilayer graphene. Science 330, 812–816 (2010).10.1126/science.1194988 ↗
28. Freitag, F., Trbovic, J., Weiss, M. & Schönenberger, C. Spontaneously gapped ground state in suspended bilayer graphene. Phys. Rev. Lett. 108, 76602 (2012).10.1103/PhysRevLett.108.076602 ↗
29. Bao, W. et al. Stacking-dependent band gap and quantum transport in trilayer graphene. Nat. Phys. 7, 948–952 (2011).10.1038/nphys2103 ↗
30. Velasco, J. et al. Transport spectroscopy of symmetry-broken insulating states in bilayer graphene. Nat. Nanotechnol. 7, 156–160 (2012).10.1038/nnano.2011.251 ↗
31. Myhro, K. et al. Large tunable intrinsic gap in rhombohedral-stacked tetralayer graphene at half filling. 2D Mater. 5, 045013 (2018).10.1088/2053-1583/aad2f2 ↗
32. Pamuk, B., Baima, J., Mauri, F. & Calandra, M. Magnetic gap opening in rhombohedral-stacked multilayer graphene from first principles. Phys. Rev. B 95, 075422 (2017).10.1103/PhysRevB.95.075422 ↗
33. Jia, J., Gorbar, E. V. & Gusynin, V. P. Gap generation in ABC-stacked multilayer graphene: screening versus band flattening. Phys. Rev. B 88, 205428 (2013).10.1103/PhysRevB.88.205428 ↗
34. Zhou, H. et al. Isospin magnetism and spin-polarized superconductivity in Bernal bilayer graphene. Science 375, 774–778 (2022).10.1126/science.abm8386 ↗
35. de la Barrera, S. C. et al. Cascade of isospin phase transitions in Bernal-stacked bilayer graphene at zero magnetic field. Nat. Phys. 18, 771–775 (2022).10.1038/s41567-022-01616-w ↗
36. Seiler, A. M. et al. Quantum cascade of correlated phases in trigonally warped bilayer graphene. Nature 608, 298–302 (2022).10.1038/s41586-022-04937-1 ↗
37. Zhang, F., Min, H., Polini, M. & MacDonald, A. H. Spontaneous inversion symmetry breaking in graphene bilayers. Phys. Rev. B 81, 041402 (2010).10.1103/PhysRevB.81.041402 ↗
38. Jung, J., Zhang, F. & MacDonald, A. H. Lattice theory of pseudospin ferromagnetism in bilayer graphene: competing interaction-induced quantum Hall states. Phys. Rev. B 83, 115408 (2011).10.1103/PhysRevB.83.115408 ↗
39. Nandkishore, R. & Levitov, L. Quantum anomalous Hall state in bilayer graphene. Phys. Rev. B 82, 115124 (2010).10.1103/PhysRevB.82.115124 ↗
40. Vafek, O. & Yang, K. Many-body instability of Coulomb interacting bilayer graphene: renormalization group approach. Phys. Rev. B 81, 041401 (2010).10.1103/PhysRevB.81.041401 ↗
41. Lemonik, Y., Aleiner, I. & Fal’Ko, V. I. Competing nematic, antiferromagnetic, and spin-flux orders in the ground state of bilayer graphene. Phys. Rev. B 85, 245451 (2012).10.1103/PhysRevB.85.245451 ↗
42. Kharitonov, M. Antiferromagnetic state in bilayer graphene. Phys. Rev. B 86, 195435 (2012).10.1103/PhysRevB.86.195435 ↗
43. Xu, D. H. et al. Stacking order, interaction, and weak surface magnetism in layered graphene sheets. Phys. Rev. B 86, 201404 (2012).10.1103/PhysRevB.86.201404 ↗
44. Sun, K., Yao, H., Fradkin, E. & Kivelson, S. A. Topological insulators and nematic phases from spontaneous symmetry breaking in 2D Fermi systems with a quadratic band crossing. Phys. Rev. Lett. 103, 046811 (2009).10.1103/PhysRevLett.103.046811 ↗
45. Streda, P. Theory of quantised Hall conductivity in two dimensions. J. Phys. C 15, L717 (1982).10.1088/0022-3719/15/22/005 ↗
46. Li, J., Tupikov, Y., Watanabe, K., Taniguchi, T. & Zhu, J. Effective Landau level diagram of bilayer graphene. Phys. Rev. Lett. 120, 47701 (2018).10.1103/PhysRevLett.120.047701 ↗
47. McCann, E. & Fal’ko, V. I. Landau-level degeneracy and quantum Hall effect in a graphite bilayer. Phys. Rev. Lett. 96, 86805 (2006).10.1103/PhysRevLett.96.086805 ↗
48. Slizovskiy, S., McCann, E., Koshino, M. & Fal’ko, V. I. Films of rhombohedral graphite as two-dimensional topological semimetals. Commun. Phys. 2, 164 (2019).10.1038/s42005-019-0268-8 ↗
49. Kopnin, N. B., Ijäs, M., Harju, A. & Heikkilä, T. T. High-temperature surface superconductivity in rhombohedral graphite. Phys. Rev. B 87, 140503 (2013).10.1103/PhysRevB.87.140503 ↗
50. Ghazaryan, A., Holder, T., Berg, E. & Serbyn, M. Multilayer graphenes as a platform for interaction-driven physics and topological superconductivity. Phys. Rev. B 107, 104502 (2023).10.1103/PhysRevB.107.104502 ↗
51. Calvera, V., Kivelson, S. A. & Berg, E. Pseudo-spin order of Wigner crystals in multi-valley electron gases. Low Temp. Phys. 49, 679–700 (2023).10.1063/10.0019425 ↗
52. Ju, L. et al. Topological valley transport at bilayer graphene domain walls. Nature 520, 650–655 (2015).10.1038/nature14364 ↗
53. Li, H. et al. Electrode-free anodic oxidation nanolithography of low-dimensional materials. Nano Lett. 18, 8011–8015 (2018).10.1021/acs.nanolett.8b04166 ↗
54. Geisenhof, F. R. et al. Quantum anomalous Hall octet driven by orbital magnetism in bilayer graphene. Nature 598, 53–58 (2021).10.1038/s41586-021-03849-w ↗
55. Varlet, A. et al. Anomalous sequence of quantum Hall liquids revealing a tunable Lifshitz transition in bilayer graphene. Phys. Rev. Lett. 113, 116602 (2014).10.1103/PhysRevLett.113.116602 ↗