journal article·2022-04

Abrading bulk metal into single atoms

Gao-Feng Han, Feng Li, Alexandre I. Rykov, Yoon-Kwang Im, Soo-Young Yu, Jong-Pil Jeon, Seok-Jin Kim, Wenhui Zhou, Rile Ge, Zhimin Ao, Tae Joo Shin, Junhu Wang, Hu Young Jeong, Jong-Beom Baek

Nature Nanotechnology· Volume 17· Issue 4
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Abstract

Single-atom catalysts have recently attracted considerable attention because of their highly efficient metal utilization and unique properties. Finding a green, facile method to synthesize them is key to their widespread commercialization. Here we show that single-atom catalysts (including iron, cobalt, nickel and copper) can be prepared via a top-down abrasion method, in which the bulk metal is directly atomized onto different supports, such as carbon frameworks, oxides and nitrides. The level of metal loading can be easily tuned by changing the abrasion rate. No synthetic chemicals, solvents or even water were used in the process and no by-products or waste were generated. The underlying reaction mechanism involves the mechanochemical force in situ generating defects on the supports, then trapping and stably sequestering atomized metals.
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Research context

OpenAlex topics: Catalytic Processes in Materials Science · Electrocatalysts for Energy Conversion · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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