journal article·2008-07Open access

Tailoring the atomic structure of graphene nanoribbons by scanning tunnelling microscope lithography

Levente Tapasztó, Gergely Dobrik, Philippe Lambin, László P. Biró

Nature Nanotechnology· Volume 3· Issue 7

Abstract

The practical realization of nanoscale electronics faces two major challenges: the precise engineering of the building blocks and their assembly into functional circuits. In spite of the exceptional electronic properties of carbon nanotubes, only basic demonstration devices have been realized that require time-consuming processes. This is mainly due to a lack of selective growth and reliable assembly processes for nanotubes. However, graphene offers an attractive alternative. Here we report the patterning of graphene nanoribbons and bent junctions with nanometre-precision, well-defined widths and predetermined crystallographic orientations, allowing us to fully engineer their electronic structure using scanning tunnelling microscope lithography. The atomic structure and electronic properties of the ribbons have been investigated by scanning tunnelling microscopy and tunnelling spectroscopy measurements. Opening of confinement gaps up to 0.5 eV, enabling room-temperature operation of graphene nanoribbon-based devices, is reported. This method avoids the difficulties of assembling nanoscale components and may prove useful in the realization of complete integrated circuits, operating as room-temperature ballistic electronic devices.
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Research context

OpenAlex topics: Graphene research and applications · Carbon Nanotubes in Composites · Molecular Junctions and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Avouris, P., Chen, Z. & Perebeinos, V. Carbon-based electronics. Nature Nanotech. 2, 605–615 (2007).10.1038/nnano.2007.300 ↗
2. Avouris, P. Molecular electronics with carbon nanotubes. Acc. Chem. Res. 35, 1026–1034 (2002).10.1021/ar010152e ↗
3. Tans, S. J., Verschueren, A. R. M. & Dekker, C. Room-temperature transistor based on a single carbon nanotube. Nature 393, 49–52 (1998).10.1038/29954 ↗
4. Yao, Z., Postma, H. W. C., Balents, L. & Dekker, C. Carbon nanotube intramolecular junctions. Nature 402, 273–276 (1999).10.1038/46241 ↗
5. Keren, K., Berman, R. S., Buchstab, E., Sivan, U. & Braun, E. DNA-templated carbon nanotube field-effect transistor. Science 302, 1380–1382 (2003).10.1126/science.1091022 ↗
6. Areshkin, D. A. & White, C. T. Building blocks for integrated graphene circuits. Nano Lett. 7, 3253–3259 (2007).10.1021/nl070708c ↗
7. Yan, Q. et al. Intrinsic current–voltage characteristics of graphene nanoribbon transistors and effect of edge doping. Nano Lett. 7, 1469–1473 (2007).10.1021/nl070133j ↗
8. Geim, A. K. & Novoselov, K. S. The rise of graphene. Nature Mater. 6, 183–191 (2007).10.1038/nmat1849 ↗
9. Novoselov, K. S. et al. Two-dimensional gas of massless Dirac fermions in graphene. Nature 438, 197–200 (2005).10.1038/nature04233 ↗
10. Barone, V., Hod, O. & Scuseria, G. E. Electronic structure and stability of semiconducting graphene nanoribbons. Nano Lett. 6, 2748–2754 (2006).10.1021/nl0617033 ↗
11. Son, Y. W., Cohen, M. L. & Louie, S. G. Energy gaps in graphene nanoribbons. Phys. Rev. Lett. 97, 216803 (2006).10.1103/PhysRevLett.97.216803 ↗
12. Han, M. Y., Ozylmaz, B., Zhang, Y. & Kim, P. Energy band-gap engineering of graphene nanoribbons. Phys. Rev. Lett. 98, 206805 (2007).10.1103/PhysRevLett.98.206805 ↗
13. Chen, Z., Lin, Y. M., Rooks, M. J. & Avouris, P. Graphene nano-ribbon electronics. Physica E 40, 228–232 (2007).10.1016/j.physe.2007.06.020 ↗
14. Tseng, A. A., Notargiacomo, A. & Chen, T. P. Nanofabrication by scanning probe microscope lithography: A review. J. Vac. Sci. Technol. B 23, 877–894 (2005).10.1116/1.1926293 ↗
15. Albrecht, T. R. et al. Nanometer-scale hole formation on graphite using a scanning tunneling microscope. Appl. Phys. Lett. 55, 1727–1729 (1989).10.1063/1.102201 ↗
16. McCarley, R. L., Hendricks, S. A. & Bard, A. J. Controlled nanofabrication of highly oriented pyrolytic graphite with the scanning tunneling microscope. J. Phys. Chem. 96, 10089–10092 (1992).10.1021/j100204a002 ↗
17. Mizes, H. A. & Foster, J. S. Long-range electronic perturbations caused by defects using scanning tunneling microscopy. Science 244, 559–562 (1989).10.1126/science.244.4904.559 ↗
18. Tapasztó, L. et al. Electron scattering in a multiwall carbon nanotube bend junction studied by scanning tunneling microscopy. Phys. Rev. B 74, 235422 (2006).10.1103/PhysRevB.74.235422 ↗
19. Ishigami, M., Chen, J. H., Cullen, W. G., Fuhrer, M. S. & Williams, E. D. Atomic structure of graphene on SiO2 . Nano Lett. 7, 1643–1648 (2007).10.1021/nl070613a ↗
20. Rutter, G. M. et al. Scattering and interference in epitaxial graphene. Science 317, 219–222 (2007).10.1126/science.1142882 ↗
21. Gomez-Navarro, C. et al. Electronic transport properties of individual chemically reduced graphene oxide sheets, Nano Lett. 7, 3499–3503 (2007).10.1021/nl072090c ↗
22. Meunier, V. & Lamnin, P. Tight-binding computation of the STM image of carbon nanotubes. Phys. Rev. Lett. 81, 5588–5591 (1998).10.1103/PhysRevLett.81.5588 ↗
23. Tersoff, J. & Hamann, D. R. Theory of the scanning tunneling microscope. Phys. Rev. B 31, 805–813 (1985).10.1103/PhysRevB.31.805 ↗
24. Wildöer, J. W. G., Venema, L. C., Rinzler, A. G., Smalley, R. E. & Dekker, C. Electronic structure of atomically resolved carbon nanotubes. Nature 391, 59–62 (1998).10.1038/34139 ↗
25. Berger, C. et al. Electronic confinement and coherence in patterned epitaxial graphene. Science 312, 1191–1196 (2006).10.1126/science.1125925 ↗
26. Miao, F. et al. Phase-coherent transport in graphene quantum billiards. Science 317, 1530–1533 (2007).10.1126/science.1144359 ↗
27. Yoon, Y. & Guo, J. Effect of edge roughness in graphene nanoribbon transistors. Appl. Phys. Lett. 91, 73103 (2007).10.1063/1.2769764 ↗
28. Knoll, A. et al. Integrating nanotechnology into a working storage device. Microelectron. Eng. 83, 1692–1697 (2006).10.1016/j.mee.2006.01.206 ↗
29. Kim, D. H., Koo, J. Y. & Kim, J. J. Cutting of multiwalled carbon nanotubes by a negative voltage tip of an atomic force microscope: A possible mechanism. Phys. Rev. B 68, 113406 (2003).10.1103/PhysRevB.68.113406 ↗