journal article·2015-05Open access

Hybrid optical–electrical detection of donor electron spins with bound excitons in silicon

C. C. Lo, M. Urdampilleta, P. Ross, M. F. Gonzalez-Zalba, J. Mansir, S. A. Lyon, M. L. W. Thewalt, J. J. L. Morton

Nature Materials· Volume 14· Issue 5

Abstract

Electrical detection of spins is an essential tool for understanding the dynamics of spins, with applications ranging from optoelectronics and spintronics, to quantum information processing. For electron spins bound to donors in silicon, bulk electrically detected magnetic resonance has relied on coupling to spin readout partners such as paramagnetic defects or conduction electrons, which fundamentally limits spin coherence times. Here we demonstrate electrical detection of donor electron spin resonance in an ensemble by transport through a silicon device, using optically driven donor-bound exciton transitions. We measure electron spin Rabi oscillations, and obtain long electron spin coherence times, limited only by the donor concentration. We also experimentally address critical issues such as non-resonant excitation, strain, and electric fields, laying the foundations for realizing a single-spin readout method with relaxed magnetic field and temperature requirements compared with spin-dependent tunnelling, enabling donor-based technologies such as quantum sensing.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Quantum and electron transport phenomena · Semiconductor materials and devices · Diamond and Carbon-based Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Malissa, H. et al. Room-temperature coupling between electrical current and nuclear spins in OLEDs. Science 345, 1487–1490 (2014).10.1126/science.1255624 ↗
2. Algasinger, M. et al. Improved black silicon for photovoltaic applications. Adv. Energy Mater. 3, 1068–1074 (2013).10.1002/aenm.201201038 ↗
3. Appelbaum, I., Huang, B. & Monsma, D. J. Electronic measurements and control of spin transport in silicon. Nature 447, 295–298 (2007).10.1038/nature05803 ↗
4. Stegner, A. R. et al. Electrical detection of coherent 31P spin quantum states. Nature Phys. 2, 835–838 (2006).10.1038/nphys465 ↗
5. Paik, S. Y., Lee, S. Y., Baker, W. J., McCamey, D. R. & Boehme, C. T1 and T2 spin relaxation time limitations of phosphorus donor electron near crystalline silicon to silicon dioxide interface defects. Phys. Rev. B 81, 075214 (2010).10.1103/PhysRevB.81.075214 ↗
6. McCamey, D. R., van Tol, J., Morley, G. W. & Boehme, C. Electronic spin storage in an electrically readable nuclear spin memory with a lifetime >100 seconds. Science 330, 1652–1656 (2010).10.1126/science.1197931 ↗
7. Lo, C. C. et al. Electrically detected magnetic resonance of neutral donors interacting with a two-dimensional electron gas. Phys. Rev. Lett. 106, 207601 (2011).10.1103/PhysRevLett.106.207601 ↗
8. Lo, C. C., Weis, C. D., van Tol, J., Bokor, J. & Schenkel, T. All-electrical nuclear spin polarization of donors in silicon. Phys. Rev. Lett. 110, 057601 (2013).10.1103/PhysRevLett.110.057601 ↗
9. Steger, M. et al. Quantum information storage for over 180s using donor spins in a 28Si “semiconductor vacuum”. Science 336, 1280–1283 (2012).10.1126/science.1217635 ↗
10. Saeedi, K. et al. Room-temperature qubit storage exceeding 39 minutes using ionized donors in 28Si. Science 342, 830–833 (2013).10.1126/science.1239584 ↗
11. Tyryshkin, A. M. et al. Electron spin coherence exceeding seconds in high-purity silicon. Nature Mater. 11, 143–147 (2012).10.1038/nmat3182 ↗
12. Morello, A. et al. Single-shot readout of an electron spin in silicon. Nature 467, 687–691 (2010).10.1038/nature09392 ↗
13. Pla, J. J. et al. A single-atom electron spin qubit in silicon. Nature 489, 541–545 (2012).10.1038/nature11449 ↗
14. Kane, B. A silicon-based nuclear spin quantum computer. Nature 393, 133–137 (1998).10.1038/30156 ↗
15. Morton, J. J. L. et al. Solid-state quantum memory using the 31P nuclear spin. Nature 455, 1085–1088 (2008).10.1038/nature07295 ↗
16. Taylor, J. et al. High-sensitivity diamond magnetometer with nanoscale resolution. Nature Phys. 4, 810–816 (2008).10.1038/nphys1075 ↗
17. Schmid, W. Auger lifetimes for excitons bound to neutral donors and acceptors in Si. Phys. Status Solidi B 84, 529–540 (1977).10.1002/pssb.2220840216 ↗
18. Yang, A. et al. Simultaneous sub second hyper polarization of the nuclear and electron spins of phosphorus in silicon by optical pumping of exciton transitions. Phys. Rev. Lett. 102, 257401 (2009).10.1103/PhysRevLett.102.257401 ↗
19. Haynes, J. R. Experimental proof of the existence of a new electronic complex in silicon. Phys. Rev. Lett. 4, 361 (1960).10.1103/PhysRevLett.4.361 ↗
20. Yang, A. et al. High-resolution photoluminescence measurement of the isotopic-mass dependence of the lattice parameter of silicon. Phys. Rev. B 77, 113203 (2008).10.1103/PhysRevB.77.113203 ↗
21. Wilson, D. K. & Feher, G. Electron spin resonance experiments on donors in silicon. III. Investigation of excited states by the application of uniaxial stress and their importance in relaxation processes. Phys. Rev. 124, 1068–1083 (1961).10.1103/PhysRev.124.1068 ↗
22. Feher, G. Electron spin resonance experiments on donors in silicon. I. Electronic structure of donors by electron nuclear double resonance technique. Phys. Rev. 114, 1219–1244 (1959).10.1103/PhysRev.114.1219 ↗
23. Kopf, A. & Lassmann, K. Linear Stark and nonlinear Zeeman coupling to the ground state of effective mass acceptors in silicon. Phys. Rev. Lett. 69, 1580–1583 (1992).10.1103/PhysRevLett.69.1580 ↗
24. Hoehne, F., Dreher, L., Huebl, H., Stutzmann, M. & Brandt, M. S. Electrical detection of coherent nuclear spin oscillations in phosphorus-doped silicon using pulsed endor. Phys. Rev. Lett. 106, 187601 (2011).10.1103/PhysRevLett.106.187601 ↗
25. Jiang, L. et al. Repetitive readout of a single electronic spin via quantum logic with nuclear spin ancillae. Science 326, 267–272 (2009).10.1126/science.1176496 ↗
26. Thorbeck, T. & Zimmerman, N. M. Formation of strain-induced quantum dots in gated semiconductor nanostructures. Preprint at http://arxiv.org/abs/1409.3549 (2014)10.1063/1.4928320 ↗
27. Yin, C. et al. Optical addressing of an individual erbium ion in silicon. Nature 497, 91–95 (2013).10.1038/nature12081 ↗
28. Sleiter, D. et al. Quantum hall charge sensor for single-donor nuclear spin detection in silicon. New J. Phys. 12, 093028 (2010).10.1088/1367-2630/12/9/093028 ↗
29. Fuhrer, A., Füchsle, M., Reusch, T. C. G., Weber, B. & Simmons, M. Y. Atomic-scale, all epitaxial in-plane gated donor quantum dot in silicon. Nano Lett. 9, 707–710 (2009).10.1021/nl803196f ↗
30. Thewalt, M. L. W. & Rostworowski, J. A. Effects of uniaxial stress on the luminescence lines due to multiexciton complexes bound to phosphorus in silicon. Phys. Rev. Lett. 41, 808–812 (1978).10.1103/PhysRevLett.41.808 ↗