journal article·2025-12

Hermetic stretchable seals enabled by a viscoplastic surface effect

Rui Xia, Chun Li, Yan Shao, Dong He, Jianfeng Yan, Mao Yu, Kangjie Chu, Huanhuan Yang, Daohang Cai, Guoli Chen, Yaqi Du, Guangfu Luo, Weishu Liu, Fuzeng Ren, Zhubing He, Yanhao Yu

Nature Materials· Volume 24· Issue 12
Publisher page

Abstract

Elastic seals safeguard stretchable electronics from reactive species in the surrounding environment. However, elastic contact with device modules and the intrinsic small-molecule permeability of elastomers limit the hermeticity of devices. Here we present a viscoplastic surface effect in polymeric elastomers for deriving sealing platforms with high hermeticity and large stretchability, made possible by controlling phase separations of partially miscible polar plastics within the near-surface region of block copolymer elastomers. The resulting viscoplastic surface allows the elastomer to form defect-free interfaces regardless of their size, materials chemistry and geometry. This capability facilitates the airtight integration of device modules to mitigate side leakage and enable the seamless assembly of high-potential gas barriers to prevent bulk penetration. A multilayer seal that incorporates scavenging components demonstrates properties that are as hermetic as aluminium foil while being stretchable like a rubber band. This breakthrough extends the operational lifetime of perovskite optoelectronics, hydrogel thermoelectrics and implantable bioelectronics without sacrificing their stretchability or efficiency.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Tribology and Lubrication Engineering · Adhesion, Friction, and Surface Interactions · Lubricants and Their Additives

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. Zhong, D. et al. High-speed and large-scale intrinsically stretchable integrated circuits. Nature 627, 313–320 (2024).10.1038/s41586-024-07096-7 ↗
2. Madhvapathy, S. R. et al. Implantable bioelectronic systems for early detection of kidney transplant rejection. Science 381, 1105–1112 (2023).10.1126/science.adh7726 ↗
3. Mackanic, D. G., Chang, T.-H., Huang, Z., Cui, Y. & Bao, Z. Stretchable electrochemical energy storage devices. Chem. Soc. Rev. 49, 4466–4495 (2020).10.1039/D0CS00035C ↗
4. Fukuda, K. et al. A bending test protocol for characterizing the mechanical performance of flexible photovoltaics. Nat. Energy 9, 1335–1343 (2024).10.1038/s41560-024-01651-2 ↗
5. Zhang, Z. et al. High-brightness all-polymer stretchable LED with charge-trapping dilution. Nature 603, 624–630 (2022).10.1038/s41586-022-04400-1 ↗
6. Nguyen, T. N., Iranpour, B., Cheng, E. & Madden, J. D. W. Washable and stretchable Zn–MnO2 rechargeable cell. Adv. Energy Mater. 12, 2103148 (2022).10.1002/aenm.202103148 ↗
7. Zheng, Y. et al. Environmentally stable and stretchable polymer electronics enabled by surface-tethered nanostructured molecular-level protection. Nat. Nanotechnol. 18, 1175–1184 (2023).10.1038/s41565-023-01418-y ↗
8. Xu, J. et al. Highly stretchable polymer semiconductor films through the nanoconfinement effect. Science 355, 59–64 (2017).10.1126/science.aah4496 ↗
9. Sang, M., Kim, K., Shin, J. & Yu, K. J. Ultra-thin flexible encapsulating materials for soft bio-integrated electronics. Adv. Sci. 9, 2202980 (2022).10.1002/advs.202202980 ↗
10. Mariello, M., Kim, K., Wu, K., Lacour, S. P. & Leterrier, Y. Recent advances in encapsulation of flexible bioelectronic implants: materials, technologies, and characterization methods. Adv. Mater. 34, 2201129 (2022).10.1002/adma.202201129 ↗
11. Faiz, S., Kim, H. W., Oh, J., Veerapandian, S. & Jeong, U. High-precision stretchable ionic temperature sensor passivated with a liquid metal/block copolymer multilayer film. ACS Appl. Mater. Interfaces 15, 28825–28832 (2023).10.1021/acsami.3c03811 ↗
12. Shen, Q. et al. Liquid metal-based soft, hermetic, and wireless-communicable seals for stretchable systems. Science 379, 488–493 (2023).10.1126/science.ade7341 ↗
13. Song, E., Li, J., Won, S. M., Bai, W. & Rogers, J. A. Materials for flexible bioelectronic systems as chronic neural interfaces. Nat. Mater. 19, 590–603 (2020).10.1038/s41563-020-0679-7 ↗
14. Li, K. et al. A generic soft encapsulation strategy for stretchable electronics. Adv. Funct. Mater. 29, 1806630 (2019).10.1002/adfm.201806630 ↗
15. Shao, Y. et al. A universal packaging substrate for mechanically stable assembly of stretchable electronics. Nat. Commun. 15, 6106 (2024).10.1038/s41467-024-50494-8 ↗
16. Li, N. et al. Bioadhesive polymer semiconductors and transistors for intimate biointerfaces. Science 381, 686–693 (2023).10.1126/science.adg8758 ↗
17. Ji, S. & Chen, X. Enhancing the interfacial binding strength between modular stretchable electronic components. Natl Sci. Rev. 10, nwac172 (2023).10.1093/nsr/nwac172 ↗
18. Veerapandian, S. et al. Hydrogen-doped viscoplastic liquid metal microparticles for stretchable printed metal lines. Nat. Mater. 20, 533–540 (2021).10.1038/s41563-020-00863-7 ↗
19. Liu, Y. et al. Morphing electronics enable neuromodulation in growing tissue. Nat. Biotechnol. 38, 1031–1036 (2020).10.1038/s41587-020-0495-2 ↗
20. Lee, S. et al. A shape-morphing cortex-adhesive sensor for closed-loop transcranial ultrasound neurostimulation. Nat. Electron. 7, 800–814 (2024).10.1038/s41928-024-01240-x ↗
21. Takalloo, S. E. et al. Impermeable and compliant: SIBS as a promising encapsulant for ionically electroactive devices. Robotics 8, 60 (2019).10.3390/robotics8030060 ↗
22. Szabó, P., Epacher, E., Földes, E. & Pukánszky, B. Miscibility, structure and properties of PP/PIB blends. Mater. Sci. Eng. A 383, 307–315 (2004).10.1016/j.msea.2004.04.035 ↗
23. Yang, S., Zhang, Y.-W. & Zeng, K. Analysis of nanoindentation creep for polymeric materials. J. Appl. Phys. 95, 3655–3666 (2004).10.1063/1.1651341 ↗
24. Tang, B. & Ngan, A. H. W. Accurate measurement of tip–sample contact size during nanoindentation of viscoelastic materials. J. Mater. Res. 18, 1141–1148 (2003).10.1557/JMR.2003.0156 ↗
25. Wiersma, J. & Sain, T. A coupled viscoplastic-damage constitutive model for semicrystalline polymers. Mech. Mater. 176, 104527 (2023).10.1016/j.mechmat.2022.104527 ↗
26. Venkatesh, R. B. & Lee, D. Conflicting effects of extreme nanoconfinement on the translational and segmental motion of entangled polymers. Macromolecules 55, 4492–4501 (2022).10.1021/acs.macromol.2c00145 ↗
27. Liang, C. et al. Stiff and self-healing hydrogels by polymer entanglements in co-planar nanoconfinement. Nat. Mater. 24, 599–606 (2025).10.1038/s41563-025-02146-5 ↗
28. Wang, Z. Y., et al. Ion transport in 2D nanostructured π-conjugated thieno[3,2-b]thiophene-based liquid crystal. ACS Nano 16, 20714–20729 (2022).10.1021/acsnano.2c07789 ↗
29. Wang, Y., Hasegawa, T., Matsumoto, H. & Michinobu, T. Significant improvement of unipolar n-type transistor performances by manipulating the coplanar backbone conformation of electron-deficient polymers via hydrogen bonding. J. Am. Chem. Soc. 141, 3566–3575 (2019).10.1021/jacs.8b12499 ↗
30. López-Barrón, C. R., Zhou, H., Younker, J. M. & Mann, J. A. Molecular structure, chain dimensions, and linear rheology of poly(4-vinylbiphenyl). Macromolecules 50, 9048–9057 (2017).10.1021/acs.macromol.7b01564 ↗
31. Mitchell, G. R. & Windle, A. H. Structure of polystyrene glasses. Polymer 25, 906–920 (1984).10.1016/0032-3861(84)90073-9 ↗
32. Lim, D.-H. et al. Structural insight into aggregation and orientation of TPD-based conjugated polymers for efficient charge-transporting properties. Chem. Mater. 31, 4629–4638 (2019).10.1021/acs.chemmater.8b04605 ↗
33. Tang, L., Watts, B., Thomsen, L. & McNeill, C. R. Morphology and charge transport properties of P(NDI2OD-T2)/polystyrene blends. Macromolecules 54, 11134–11146 (2021).10.1021/acs.macromol.1c01661 ↗
34. Zhou, J. & Komvopoulos, K. Surface and interface viscoelastic behaviors of thin polymer films investigated by nanoindentation. J. Appl. Phys. 100, 114329 (2006).10.1063/1.2398797 ↗
35. Qiu, H. N. et al. Stress relaxation and creep response of glassy hydrogels with dense physical associations. ACS Appl. Mater. Interfaces 17, 9981–9991 (2025).10.1021/acsami.4c22398 ↗
36. Hao, Z. et al. Mobility gradients yield rubbery surfaces on top of polymer glasses. Nature 596, 372–376 (2021).10.1038/s41586-021-03733-7 ↗
37. Kim, S. Y., Park, M. J., Balsara, N. P. & Jackson, A. Confinement effects on watery domains in hydrated block copolymer electrolyte membranes. Macromolecules 43, 8128–8135 (2010).10.1021/ma101620k ↗
38. Shi, B. et al. Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity. Nat. Commun. 13, 6666 (2022).10.1038/s41467-022-33868-8 ↗
39. Paetzold, R., Winnacker, A., Henseler, D., Cesari, V. & Heuser, K. Permeation rate measurements by electrical analysis of calcium corrosion. Rev. Sci. Instrum. 74, 5147–5150 (2003).10.1063/1.1626015 ↗
40. Keller, P. E. & Kouzes, R. T. Water Vapor Permeation in Plastics Technical Report PNNL-26070 (US Department of Energy, 2017); https://doi.org/10.2172/1411940.10.2172/1411940 ↗
41. Carcia, P. F., McLean, R. S., Groner, M. D., Dameron, A. A. & George, S. M. Gas diffusion ultrabarriers on polymer substrates using Al2O3 atomic layer deposition and SiN plasma-enhanced chemical vapor deposition. J. Appl. Phys. 106, 023533 (2009).10.1063/1.3159639 ↗
42. Ochirkhuyag, N. et al. Stretchable gas barrier films using liquid metal toward a highly deformable battery. ACS Appl. Mater. Interfaces 14, 48123–48132 (2022).10.1021/acsami.2c13023 ↗
43. Kempe, M. D., Dameron, A. A. & Reese, M. O. Evaluation of moisture ingress from the perimeter of photovoltaic modules. Prog. Photovolt. 22, 1159–1171 (2014).10.1002/pip.2374 ↗
44. Apeagyei, A. K., Grenfell, J. R. A. & Airey, G. D. Application of Fickian and non-Fickian diffusion models to study moisture diffusion in asphalt mastics. Mater. Struct. 48, 1461–1474 (2015).10.1617/s11527-014-0246-2 ↗
45. Carter, H. G. & Kibler, K. G. Langmuir-type model for anomalous moisture diffusion in composite resins. J. Compos. Mater. 12, 118–131 (1978).10.1177/002199837801200201 ↗
46. Zhou, H. et al. Water passivation of perovskite nanocrystals enables air-stable intrinsically stretchable color-conversion layers for stretchable displays. Adv. Mater. 32, 2001989 (2020).10.1002/adma.202001989 ↗
47. Pinchuk, L. The development of a SIBS shunt to treat glaucoma. J. Ocul. Pharmacol. Ther. 39, 530–540 (2023).10.1089/jop.2023.0005 ↗
48. Gan, T. et al. Conformally adhesive, large-area, solid-like, yet transient liquid metal thin films and patterns via gelatin-regulated droplet deposition and sintering. ACS Appl. Mater. Interfaces 14, 42744–42756 (2022).10.1021/acsami.2c12880 ↗
49. Iqbal, H. F. et al. Suppressing bias stress degradation in high performance solution processed organic transistors operating in air. Nat. Commun. 12, 2352 (2021).10.1038/s41467-021-22683-2 ↗