Self-assembled molecules with hydrogen-bond networks enable efficient all-perovskite tandem solar cells
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Perovskite Materials and Applications · Organic Electronics and Photovoltaics · Organic Light-Emitting Diodes Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (84)
Show source-provided references
1. Leijtens, T., Bush, K. A., Prasanna, R. & McGehee, M. D. Opportunities and challenges for tandem solar cells using metal halide perovskite semiconductors. Nat. Energy 3, 828–838 (2018).10.1038/s41560-018-0190-4 ↗
2. Eperon, G. E., Hörantner, M. T. & Snaith, H. J. Metal halide perovskite tandem and multiple-junction photovoltaics. Nat. Rev. Chem. 1, 0095 (2017).10.1038/s41570-017-0095 ↗
3. McMeekin, D. P. et al. A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells. Science 351, 151–155 (2016).10.1126/science.aad5845 ↗
4. Lin, R. et al. All-perovskite tandem solar cells with dipolar passivation. Nature 648, 600–606 (2025).10.1038/s41586-025-09773-7 ↗
5. Zhu, P. et al. Aqueous synthesis of perovskite precursors for highly efficient perovskite solar cells. Science 383, 524–531 (2024).10.1126/science.adj7081 ↗
6. Liu, Z. et al. All-perovskite tandem solar cells achieving >29% efficiency with improved (100) orientation in wide-bandgap perovskites. Nat. Mater. 24, 252–259 (2025).10.1038/s41563-024-02073-x ↗
7. Wu, S. et al. Redox mediator-stabilized wide-bandgap perovskites for monolithic perovskite-organic tandem solar cells. Nat. Energy 9, 411–421 (2024).10.1038/s41560-024-01451-8 ↗
8. Liu, C. et al. Bimolecularly passivated interface enables efficient and stable inverted perovskite solar cells. Science 382, 810–815 (2023).10.1126/science.adk1633 ↗
9. Wang, D. et al. Rigid molecules anchoring on NiOx enable >26% efficiency perovskite solar cells. Joule 9, 101815 (2025).10.1016/j.joule.2024.101815 ↗
10. Zhang, X. et al. A spiro-type self-assembled hole transporting monolayer for highly efficient and stable inverted perovskite solar cells and modules. Energy Environ. Sci. 18, 468–477 (2025).10.1039/D4EE01960A ↗
11. Chen, J. et al. Determining the bonding–degradation trade-off at heterointerfaces for increased efficiency and stability of perovskite solar cells. Nat. Energy 10, 181–190 (2024).
12. Li, M., Liu, M., Qi, F., Lin, F. R. & Jen, A. K. Self-assembled monolayers for interfacial engineering in solution-processed thin-film electronic devices: design, fabrication, and applications. Chem. Rev. 124, 2138–2204 (2024).10.1021/acs.chemrev.3c00396 ↗
13. Al-Ashouri, A. et al. Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells. Energy Environ. Sci. 12, 3356–3369 (2019).10.1039/C9EE02268F ↗
14. Zhang, S. et al. Minimizing buried interfacial defects for efficient inverted perovskite solar cells. Science 380, 404–409 (2023).10.1126/science.adg3755 ↗
15. Jiang, W. et al. Spin-coated and vacuum-processed hole-extracting self-assembled multilayers with H-aggregation for high-performance inverted perovskite solar cells. Angew. Chem. Int. Ed. 63, e202411730 (2024).10.1002/anie.202411730 ↗
16. Wang, X. et al. Regulating phase homogeneity by self-assembled molecules for enhanced efficiency and stability of inverted perovskite solar cells. Nat. Photonics 18, 1269–1275 (2024).10.1038/s41566-024-01531-x ↗
17. Jiang, W., Hu, Y., Li, F., Lin, F. R. & Jen, A. K. Y. Hole-selective contact with molecularly tailorable reactivity for passivating high-performing inverted perovskite solar cells. CCS Chem. 6, 1654–1661 (2024).10.31635/ccschem.024.202303710 ↗
18. Tan, Q. et al. Inverted perovskite solar cells using dimethylacridine-based dopants. Nature 620, 545–551 (2023).10.1038/s41586-023-06207-0 ↗
19. Zhao, K. et al. peri-Fused polyaromatic molecular contacts for perovskite solar cells. Nature 632, 301–306 (2024).10.1038/s41586-024-07712-6 ↗
20. Qu, G. et al. Conjugated linker-boosted self-assembled monolayer molecule for inverted perovskite solar cells. Joule 8, 2123–2134 (2024).10.1016/j.joule.2024.05.005 ↗
21. Li, Z. et al. Stabilized hole-selective layer for high-performance inverted p–i–n perovskite solar cells. Science 382, 284–289 (2023).10.1126/science.ade9637 ↗
22. Jiang, W. et al. pi-expanded carbazoles as hole-selective self-assembled monolayers for high-performance perovskite solar cells. Angew. Chem. Int. Ed. 61, e202213560 (2022).10.1002/anie.202213560 ↗
23. Zhou, J. et al. Molecular contacts with an orthogonal π-skeleton induce amorphization to enhance perovskite solar cell performance. Nat. Chem. 17, 564–570 (2025).10.1038/s41557-025-01732-z ↗
24. Truong, M. A. et al. Tripodal triazatruxene derivative as a face-on oriented hole-collecting monolayer for efficient and stable inverted perovskite solar cells. J. Am. Chem. Soc. 145, 7528–7539 (2023).10.1021/jacs.3c00805 ↗
25. Park, S. M. et al. Low-loss contacts on textured substrates for inverted perovskite solar cells. Nature 624, 289–294 (2023).10.1038/s41586-023-06745-7 ↗
26. Liu, S. et al. Buried interface molecular hybrid for inverted perovskite solar cells. Nature 632, 536–542 (2024).10.1038/s41586-024-07723-3 ↗
27. Qu, G. et al. Self-assembled materials with an ordered hydrophilic bilayer for high performance inverted Perovskite solar cells. Nat. Commun. 16, 86 (2025).10.1038/s41467-024-55523-0 ↗
28. He, R. et al. Improving interface quality for 1-cm2 all-perovskite tandem solar cells. Nature 618, 80–86 (2023).10.1038/s41586-023-05992-y ↗
29. Liu, M. et al. Compact hole-selective self-assembled monolayers enabled by disassembling micelles in solution for efficient perovskite solar cells. Adv. Mater. 35, e2304415 (2023).10.1002/adma.202304415 ↗
30. Ren, J. et al. Manipulating aggregation kinetics toward efficient all-printed organic solar cells. Adv. Mater. 37, 2418353 (2025).10.1002/adma.202418353 ↗
31. Paramonov, P. B. et al. Theoretical characterization of the indium tin oxide surface and of its binding sites for adsorption of phosphonic acid monolayers. Chem. Mater. 20, 5131–5133 (2008).10.1021/cm8014622 ↗
32. Zhang, R. et al. Equally high efficiencies of organic solar cells processed from different solvents reveal key factors for morphology control. Nat. Energy 10, 124–134 (2024).10.1038/s41560-024-01678-5 ↗
33. Li, L. et al. Flexible all-perovskite tandem solar cells approaching 25% efficiency with molecule-bridged hole-selective contact. Nat. Energy 7, 708–717 (2022).10.1038/s41560-022-01045-2 ↗
34. Luo, C. et al. Engineering bonding sites enables uniform and robust self-assembled monolayer for stable perovskite solar cells. Nat. Mater. 24, 1265–1272 (2025).10.1038/s41563-025-02275-x ↗
35. Wu, H. et al. Tailored lattice-matched carbazole self-assembled molecule for efficient and stable perovskite solar cells. J. Am. Chem. Soc. 147, 8004–8011 (2025).10.1021/jacs.5c00629 ↗
36. Wu, J. et al. Bisphosphonate-anchored self-assembled molecules with larger dipole moments for efficient inverted perovskite solar cells with excellent stability. Adv. Mater. 36, e2401537 (2024).10.1002/adma.202401537 ↗
37. Peng, W. et al. A versatile energy-level-tunable hole-transport layer for multi-composition inverted perovskite solar cells. Energy Environ. Sci. 18, 874–883 (2025).10.1039/D4EE03208J ↗
38. McGettrick, J. D. et al. Sources of Pb0 artefacts during XPS analysis of lead halide perovskites. Mater. Lett. 251, 98–101 (2019).10.1016/j.matlet.2019.04.081 ↗
39. Zhan, C. et al. Indium tin oxide induced internal positive feedback and indium ion transport in perovskite solar cells. Angew. Chem. Int. Ed. 63, e202403824 (2024).10.1002/anie.202403824 ↗
40. Chen, W. et al. Monolithic perovskite/organic tandem solar cells with 23.6% efficiency enabled by reduced voltage losses and optimized interconnecting layer. Nat. Energy 7, 229–237 (2022).10.1038/s41560-021-00966-8 ↗
41. Qin, S. et al. Constructing monolithic perovskite/organic tandem solar cell with efficiency of 22.0% via reduced open-circuit voltage loss and broadened absorption spectra. Adv. Mater. 34, 2108829 (2022).10.1002/adma.202108829 ↗
42. Wen, J. et al. Steric engineering enables efficient and photostable wide-bandgap perovskites for all-perovskite tandem solar cells. Adv. Mater. 34, 2110356 (2022).10.1002/adma.202110356 ↗
43. Jiang, X. et al. Surface heterojunction based on n-type low-dimensional perovskite film for highly efficient perovskite tandem solar cells. Natl Sci. Rev. 11, nwae055 (2024).10.1093/nsr/nwae055 ↗
44. Sun, Q. et al. Surface charge transfer doping of narrow-bandgap Sn–Pb perovskites for high-performance tandem solar cells. Energy Environ. Sci. 17, 2512–2520 (2024).10.1039/D3EE03898J ↗
45. Chen, P. et al. Multifunctional ytterbium oxide buffer for perovskite solar cells. Nature 625, 516–522 (2024).10.1038/s41586-023-06892-x ↗
46. Pu, D. et al. Enhancing efficiency and intrinsic stability of large-area blade-coated wide-bandgap perovskite solar cells through strain release. Adv. Funct. Mater. 34, 2314349 (2024).10.1002/adfm.202314349 ↗
47. Yong, J. et al. Enhancement of interfacial properties by indoloquinoxaline-based small molecules for highly efficient wide-bandgap perovskite solar cells. Adv. Funct. Mater. 34, 2312505 (2024).10.1002/adfm.202312505 ↗
48. Yang, F. et al. Minimizing interfacial recombination in 1.8 eV triple-halide perovskites for 27.5% efficient all-perovskite tandems. Adv. Mater. 36, 2307743 (2024).10.1002/adma.202307743 ↗
49. Yi, Z. et al. Achieving a high open-circuit voltage of 1.339 V in 1.77 eV wide-bandgap perovskite solar cells via self-assembled monolayers. Energy Environ. Sci. 17, 202–209 (2024).10.1039/D3EE02839A ↗
50. Wen, J. et al. Heterojunction formed via 3D-to-2D perovskite conversion for photostable wide-bandgap perovskite solar cells. Nat. Commun. 14, 7118 (2023).10.1038/s41467-023-43016-5 ↗
51. Cui, H. et al. Lead halide coordination competition at buried interfaces for low VOC-deficits in wide-bandgap perovskite solar cells. Energy Environ. Sci. 16, 5992–6002 (2023).10.1039/D3EE02818F ↗
52. Gao, M. et al. Enhancing efficiency of large-area wide-bandgap perovskite solar modules with spontaneously formed self-assembled monolayer interfaces. J. Phys. Chem. Lett. 15, 4015–4023 (2024).10.1021/acs.jpclett.4c00814 ↗
53. Zhou, J. et al. Phase-stable wide-bandgap perovskites with 2D/3D structure for all-perovskite tandem solar cells. ACS Energy Lett. 9, 1984–1992 (2024).10.1021/acsenergylett.4c00285 ↗
54. Dong, Y. et al. Interface reactive sputtering of transparent electrode for high-performance monolithic and stacked perovskite tandem solar cells. Adv. Mater. 36, 2312704 (2024).10.1002/adma.202312704 ↗
55. Lin, Y.-H. et al. Bandgap-universal passivation enables stable perovskite solar cells with low photovoltage loss. Science 384, 767–775 (2024).10.1126/science.ado2302 ↗
56. Li, Y. et al. Highly durable inverted inorganic perovskite/organic tandem solar cells enabled by multifunctional additives. Angew. Chem. Int. Ed. 63, e202412515 (2024).10.1002/anie.202412515 ↗
57. Wang, Y. et al. Homogenized contact in all-perovskite tandems using tailored 2D perovskite. Nature 635, 867–873 (2024).10.1038/s41586-024-08158-6 ↗
58. Wei, Z. et al. Surpassing 90% Shockley–Queisser VOC limit in 1.79 eV wide-bandgap perovskite solar cells using bromine-substituted self-assembled monolayers. Energy Environ. Sci. 18, 1847–1855 (2025).10.1039/D4EE04029E ↗
59. Wu, Z. et al. Enhancing photovoltaically preferred orientation in wide-bandgap perovskite for efficient all-perovskite tandem solar cells. Adv. Mater. 37, 2412943 (2025).10.1002/adma.202412943 ↗
60. Peng, W. et al. Reducing nonradiative recombination in perovskite solar cells with a porous insulator contact. Science 379, 683–690 (2023).10.1126/science.ade3126 ↗
61. Hu, S. et al. Steering perovskite precursor solutions for multijunction photovoltaics. Nature 639, 93–101 (2025).10.1038/s41586-024-08546-y ↗
62. Bai, Y. et al. Decoupling light- and oxygen-induced degradation mechanisms of Sn–Pb perovskites in all perovskite tandem solar cells. Energy Environ. Sci. 17, 8557–8569 (2024).10.1039/D4EE02427C ↗
63. Zhang, Z. et al. Suppression of phase segregation in wide-bandgap perovskites with thiocyanate ions for perovskite/organic tandems with 25.06% efficiency. Nat. Energy 9, 592–601 (2024).10.1038/s41560-024-01491-0 ↗
64. Wang, D. et al. All-in-one additive enabled efficient and stable narrow-bandgap perovskites for monolithic all-perovskite tandem solar cells. Adv. Mater. 36, e2411677 (2024).10.1002/adma.202411677 ↗
65. An, Y. et al. Optimizing crystallization in wide-bandgap mixed halide perovskites for high-efficiency solar cells. Adv. Mater. 36, 2306568 (2024).10.1002/adma.202306568 ↗
66. Li, F. et al. Regulating surface termination for efficient inverted perovskite solar cells with greater than 23% efficiency. J. Am. Chem. Soc. 142, 20134–20142 (2020).10.1021/jacs.0c09845 ↗
67. Hu, S. et al. Optimized carrier extraction at interfaces for 23.6% efficient tin–lead perovskite solar cells. Energy Environ. Sci. 15, 2096–2107 (2022).10.1039/D2EE00288D ↗
68. Hu, S. et al. A universal surface treatment for p–i–n perovskite solar cells. ACS Appl. Mater. Interfaces 14, 56290–56297 (2022).10.1021/acsami.2c15989 ↗
69. Zeng, J. et al. Small-molecule hole transport materials for >26% efficient inverted perovskite solar cells. J. Am. Chem. Soc. 147, 725–733 (2025).10.1021/jacs.4c13356 ↗
70. Kresse, G. & Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169–11186 (1996).10.1103/PhysRevB.54.11169 ↗
71. Lu, T. & Chen, F. Multiwfn: a multifunctional wavefunction analyzer. J. Comput. Chem. 33, 580–592 (2012).10.1002/jcc.22885 ↗
72. Thompson, A. P. et al. LAMMPS—a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales. Comput. Phys. Commun. 271, 108171 (2022).10.1016/j.cpc.2021.108171 ↗
73. Martínez, L., Andrade, R., Birgin, E. G. & Martínez, J. M. PACKMOL: a package for building initial configurations for molecular dynamics simulations. J. Comput. Chem. 30, 2157–2164 (2009).10.1002/jcc.21224 ↗
74. Walsh, A., Catlow, C. R. A., Sokol, A. A. & Woodley, S. M. Physical properties, intrinsic defects, and phase stability of indium sesquioxide. Chem. Mater. 21, 4962–4969 (2009).10.1021/cm902280z ↗
75. Neese, F. Software update: the ORCA program system—version 5.0. WIREs Comput. Mol. Sci. 12, e1606 (2022).10.1002/wcms.1606 ↗
76. Lin, R. et al. Monolithic all-perovskite tandem solar cells with 24.8% efficiency exploiting comproportionation to suppress Sn(II) oxidation in precursor ink. Nat. Energy 4, 864–873 (2019).10.1038/s41560-019-0466-3 ↗
77. Xiao, K. et al. All-perovskite tandem solar cells with 24.2% certified efficiency and area over 1 cm2 using surface-anchoring zwitterionic antioxidant. Nat. Energy 5, 870–880 (2020).10.1038/s41560-020-00705-5 ↗
78. Dai, X. et al. Efficient monolithic all-perovskite tandem solar modules with small cell-to-module derate. Nat. Energy 7, 923–931 (2022).10.1038/s41560-022-01102-w ↗
79. Lin, R. et al. All-perovskite tandem solar cells with improved grain surface passivation. Nature 603, 73–78 (2022).10.1038/s41586-021-04372-8 ↗
80. Jiang, Q. et al. Compositional texture engineering for highly stable wide-bandgap perovskite solar cells. Science 378, 1295–1300 (2022).10.1126/science.adf0194 ↗
81. Lin, R. et al. All-perovskite tandem solar cells with 3D/3D bilayer perovskite heterojunction. Nature 620, 994–1000 (2023).10.1038/s41586-023-06278-z ↗
82. Zhou, S. et al. Aspartate all-in-one doping strategy enables efficient all-perovskite tandems. Nature 624, 69–73 (2023).10.1038/s41586-023-06707-z ↗
83. Pan, Y. et al. Surface chemical polishing and passivation minimize non-radiative recombination for all-perovskite tandem solar cells. Nat. Commun. 15, 7335 (2024).10.1038/s41467-024-51703-0 ↗
84. Green, M. A. et al. Solar cell efficiency tables (version 65). Prog. Photovolt Res. Appl. 33, 3–15 (2024).10.1002/pip.3867 ↗