journal article·2019-07-19Open access

Near unity charge separation efficiency leads to pure ultraviolet emission in few layer graphene nanosheets

Xiaoxiao He, Litao Zhao, Zihao Zhou, Sanjun Zhang, Haifeng Pan, Jinquan Chen, Jianhua Xu

Nanotechnology· Volume 30· Issue 29

Abstract

Abstract Two-dimensional materials with van der Waals structure attract intense interest due to their high performance in ultrathin optoelectronic devices. In particular, the high efficiency charge separation between the two-dimensional materials can significantly improve the photo-response of a given device. Here we report the discovery of pure ultraviolet (UV) emission from few layer graphene nanosheets (GNS). Near unity charge separation efficiency is key to pure UV emission. The dynamics of an excited electron were analyzed using femtosecond transient absorption techniques. Electron transfer is observed from surface defect states induced by oxygen-containing functional groups to intrinsic sp 2 domain states in few layer GNS. Moreover, a solar blind response device based on few layer GNS with a high on-off ratio was successfully fabricated.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. Two-dimensional gas of massless Dirac fermions in graphene10.1038/nature04233 ↗
2. Graphene-like two-dimensional materials10.1021/cr300263a ↗
3. Electric field effect in atomically thin carbon films10.1126/science.1102896 ↗
4. Two-dimensional GaSe/MoSe2 misfit bilayer heterojunctions by van der Waals epitaxy10.1126/sciadv.1501882 ↗
5. Hybrid 2D-0D MoS2 -PbS quantum dot photodetectors10.1002/adma.201402471 ↗
6. Hybrid graphene-quantum dot phototransistors with ultrahigh gain10.1038/nnano.2012.60 ↗
7. Single defect light-emitting diode in a van der Waals heterostructure10.1021/acs.nanolett.6b01580 ↗
8. Light-emitting diodes by band-structure engineering in van der Waals heterostructures10.1038/nmat4205 ↗
9. Valley polarization by spin injection in a light-emitting van der Waals heterojunction10.1021/acs.nanolett.6b02527 ↗
10. Ultrafast formation of interlayer hot excitons in atomically thin MoS2/WS2 heterostructures10.1038/ncomms12512 ↗
11. Charge transfer at carbon nanotube-graphene van der Waals heterojunctions10.1039/C6NR03965K ↗
12. Ultrafast charge transfer and enhanced absorption in MoS2-organic van der Waals heterojunctions using plasmonic metasurfaces10.1021/acsnano.6b03414 ↗
13. Sandwiched assembly of ZnO nanowires between graphene layers for a self-powered and fast responsive ultraviolet photodetector10.1088/0957-4484/27/9/095205 ↗
14. Broadband photodetectors based on graphene–Bi2Te3 heterostructure10.1021/nn506920z ↗
15. Enhanced performance of a monolayer MoS2/WSe2 heterojunction as a photoelectrochemical cathode10.1007/s40820-018-0212-6 ↗
16. Tunable moire bands and strong correlations in small-twist-angle bilayer graphene10.1073/pnas.1620140114 ↗
17. Bilayer graphene: a little twist with big consequences10.1038/nmat3764 ↗
18. Deep ultraviolet photoluminescence of water-soluble self-passivated graphene quantum dots10.1021/nn300760g ↗
19. Deep ultraviolet to near-infrared emission and photoresponse in layered N-doped graphene quantum dots10.1021/nn501796r ↗
20. The self-association of graphane is driven by London dispersion and enhanced by orbital interactions10.1021/acs.jctc.5b00075 ↗
21. Van der Waals heterogeneous layer-layer carbon nanostructures involving π⋯H–C–C–H⋯π⋯H–C–C–H stacking based on graphene and graphane sheets10.1002/jcc.24743 ↗
22. Removal by ultra-violet lamp of ethylene and other hydrocarbons produced by bananas10.1002/jsfa.2740220916 ↗
23. Recent advances in application of UV light-emitting diodes for degrading organic pollutants in water through advanced oxidation processes: a review10.1016/j.watres.2017.12.079 ↗
24. Application of long wavelength ultraviolet radiation for modification and patterning of protein-repelling monolayers10.1021/jp4000285 ↗
25. Single ZnO nanowire/p‐type GaN heterojunctions for photovoltaic devices and UV light‐emitting diodes10.1002/adma.201000985 ↗
26. Interface anchored effect on improving working stability of deep ultraviolet light-emitting diode using graphene oxide-based fluoropolymer encapsulant10.1021/acsami.7b17668 ↗
27. UV electroluminescence emission from ZnO light-emitting diodes grown by high-temperature radiofrequency sputtering10.1002/adma.200502633 ↗
28. A p‐type amorphous oxide semiconductor and room temperature fabrication of amorphous oxide p–n heterojunction diodes10.1002/adma.200304947 ↗
29. Fabrication and photoresponse of a pn -heterojunction diode composed of transparent oxide semiconductors, p- NiO and n- ZnO10.1063/1.1598624 ↗
30. Recovery of gallium and vanadium from gasification fly ash10.1016/j.jhazmat.2006.02.041 ↗
31. Ultraviolet light-emitting diodes based on group three nitrides10.1038/nphoton.2007.293 ↗
32. Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots10.1002/adma.200902825 ↗
33. Red, yellow, and blue luminescence by graphene quantum dots: syntheses, mechanism, and cellular imaging10.1021/acsami.7b05569 ↗
34. Tunable photoluminescence from graphene oxide10.1002/anie.201200474 ↗
35. UV light exposure of aqueous graphene oxide suspensions to promote their direct reduction, formation of graphene–metal nanoparticle hybrids and dye degradation10.1016/j.carbon.2011.10.005 ↗
36. Peptide-decorated tunable-fluorescence graphene quantum dots10.1021/acsami.6b16364 ↗
37. Direct observation of quantum-confined graphene-like states and novel hybrid states in graphene oxide by transient spectroscopy10.1002/adma.201302927 ↗
38. Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts10.1039/c3nr04402e ↗
39. Trigonal warping and Berry’s phase N π in ABC-stacked multilayer graphene10.1103/PhysRevB.80.165409 ↗
40. Dual n-type doped reduced graphene oxide field effect transistors controlled by semiconductor nanocrystals10.1039/c2cc17543f ↗
41. ChemInform abstract: band bending in semiconductors: chemical and physical consequences at surfaces and interfaces10.1021/cr3000626 ↗
42. Unusual emission transformation of graphene quantum dots induced by self-assembled aggregation10.1039/c2cc32984k ↗
43. Supramolecular π−π stacking pyrene-functioned fluorenes: toward efficient solution-processable small molecule blue and white organic light emitting diodes10.1021/jp8090073 ↗
44. Ultrafast relaxation dynamics in graphene oxide: evidence of electron trapping10.1021/jp206923q ↗
45. The realistic domain structure of as-synthesized graphene oxide from ultrafast spectroscopy10.1021/ja407110r ↗
46. Unraveling bright molecule-like state and dark intrinsic state in green-fluorescence graphene quantum dots via ultrafast spectroscopy10.1002/adom.201200020 ↗
47. Broadband light-induced absorbance change in multilayer graphene10.1021/nl104303c ↗
48. UV excitation of single DNA and RNA strands produces high yields of exciplex states between two stacked bases10.1073/pnas.0802079105 ↗
49. Asymmetric electric field screening in van der Waals heterostructures10.1038/s41467-018-03592-3 ↗