journal article·2022-10-28

Amorphization of LaCoO3 Perovskite Nanostructures for Efficient Oxygen Evolution

Zhiwang Li, Yusheng Xie, Zixun Huang, Yanyan Su, Chuanlong Sun, Jianghong Fu, Hehe Wei, Fengchi Wu, Gang Ou

ACS Applied Nano Materials· Volume 5· Issue 10
Publisher page

Abstract

It has become a challenge to further enhance the electrocatalytic performance of perovskite oxides due to their limited active surface area. Herein, we propose a top-down strategy for the amorphization of crystalline LaCoO3 nanopowders with significantly enhanced specific surface area and electrocatalytic oxygen evolution reaction (OER) activity and durability, in which the overpotential at the current density of 10 mA cm–2 reduced from 405 to 293 mV, and the Tafel slope decreased from 96.6 to 63.4 mV dec–1. This work provides an effective method for the property optimization of nanometer perovskite oxides and the design of high-performance electrocatalysts.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Electrochemical Analysis and Applications

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Affiliations

College of Chemistry and Materials Science, Jinan University, Guangzhou 511443, P. R. China

Key Laboratory for Advanced Materials, Center for Computational Chemistry and Research Institute of Industrial Catalysis, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, P. R. China

School of Innovation and Entrepreneurship, Guangdong Polytechnic Normal University, Guangzhou 510665, P. R. China

Funding

Central University Basic Research Fund of China · Department of Education of Guangdong Province · Jinan University · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China · Guangdong Basic and Applied Basic Research Foundation · Guangzhou Basic and Applied Basic Research Foundation · National College Students Innovation and Entrepreneurship Training Program · Innovation Team Project in Guangdong Colleges and Universities

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