Precise Control over the Number of Pyrrolidine Catalytic Centers in Chiral COFs for Boosted Asymmetric Catalysis
Source abstract
Abstract
-nitrobenzaldehyde, achieving a 91% yield and 88% ee within only one day. This performance far surpassed that of the counterparts with only 3 or 4.5 pyrrolidine catalytic centers per pore channel, as well as most other reported chiral COFs. This study provides key insights into the precise regulation of catalytic site density in chiral COFs, offering a new perspective for designing COF catalysts with high-efficiency asymmetric catalytic performance.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Covalent Organic Framework Applications · Asymmetric Synthesis and Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization, and Guangzhou Key Laboratory of Analytical Chemistry for Biomedicine, School of Chemistry
South China Normal University
School of Chemistry and Chemical Engineering
Lingnan Normal University
Funding
Basic and Applied Basic Research Foundation of Guangdong Province · Guangzhou Municipal Science and Technology Project · National Natural Science Foundation of China
References (53)
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