On the unique temperature-dependent interplay of a B-exciton and its trion in monolayer MoSe ₂

B-exciton family: (i) the trion binding energy has an observable temperature dependence with a decreasing trend towards low temperatures and (ii) the exciton-trion emission ratio varies non-monotonically with temperature with a steep increase in the trion emission at lower temperatures. Using detailed models, we identify the particle size required for selective excitation and describe the underlying physical processes. This opens newer avenues for selectively promoting excitonic species and tuning the effective particle lifetimes in monolayer semiconductors. These results demonstrate the excellent plasmonic properties of Ga nanoparticles, which along with facile processing techniques makes it an attractive alternative to the prevalent noble metal plasmonics having applications in flexible/stretchable materials and textiles.