journal article·2021

A donor–acceptor ligand boosting the performance of FA 0.8 Cs 0.2 PbBr 3 nanocrystal light-emitting diodes

Wei Shen, Yao Lu, Pengfei Xia, Wenzhu Zhang, Yanfeng Chen, Wei Wang, Yanan Wu, Lihui Liu, Shufen Chen

Nanoscale· Volume 13· Issue 3
Publisher page

Abstract

A donor-acceptor ligand, 3-amino-2-bromo-6-methoxypyridine (ABMeoPy), was introduced to passivate FA0.8Cs0.2PbBr3 nanocrystals (NCs) by a post-processing method. The donor-acceptor interaction can greatly enhance the coordination bond of pyridine-Pb2+, and improve FA0.8Cs0.2PbBr3 NC performance with 95.99% photoluminescence quantum yield (PLQY), 6-month stability in solution, and 26% trap density decrease. In the light of ABMeoPy passivation of FA0.8Cs0.2PbBr3 NCs, the maximum luminance, the maximum current efficiency, and EQE of light-emitting diodes (LEDs) increased 69%, 110%, and 111%, respectively. The strategy of using D-A molecules to passivate perovskite NCs is quite simple and effective, which can be widely promoted in perovskite-based LEDs or solar cells.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Perovskite Materials and Applications · Organic Light-Emitting Diodes Research · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors

Institute of Advanced Materials (IAM)

Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM)

Nanjing University of Posts & Telecommunications (NUPT)

Nanjing 210023

Funding

National Key Research and Development Program of China · Natural Science Foundation of Jiangsu Province · Priority Academic Program Development of Jiangsu Higher Education Institutions · National Natural Science Foundation of China · Jilin University · Nanjing University of Posts and Telecommunications

References (44)

Show source-provided references
1. Nedelcu · Nano Lett. · 2015 · 15 · 563510.1021/acs.nanolett.5b02404 ↗
2. Koscher · J. Am. Chem. Soc. · 2017 · 139 · 656610.1021/jacs.7b02817 ↗
3. Zhao · Chem. Soc. Rev. · 2016 · 45 · 65510.1039/C4CS00458B ↗
4. Liu · ACS Nano · 2017 · 11 · 1037310.1021/acsnano.7b05442 ↗
5. Wu · ACS Energy Lett. · 2018 · 3 · 203010.1021/acsenergylett.8b01025 ↗
6. Yong · J. Am. Chem. Soc. · 2018 · 140 · 994210.1021/jacs.8b04763 ↗
7. Mondal · ACS Energy Lett. · 2019 · 4 · 3210.1021/acsenergylett.8b01909 ↗
8. Cao · Nature · 2018 · 562 · 24910.1038/s41586-018-0576-2 ↗
9. Lin · Nature · 2018 · 562 · 24510.1038/s41586-018-0575-3 ↗
10. Xu · Nat. Photonics · 2019 · 13 · 41810.1038/s41566-019-0390-x ↗
11. De Roo · ACS Nano · 2016 · 10 · 207110.1021/acsnano.5b06295 ↗
12. Wei · Inorg. Chem. · 2017 · 56 · 259610.1021/acs.inorgchem.6b02763 ↗
13. Cai · Nanoscale · 2018 · 10 · 2144110.1039/C8NR06607H ↗
14. Park · ACS Appl. Mater. Interfaces · 2019 · 11 · 842810.1021/acsami.8b20808 ↗
15. Wu · Nanoscale · 2018 · 10 · 417310.1039/C7NR09126E ↗
16. Wang · J. Phys. Chem. Lett. · 2019 · 10 · 9010.1021/acs.jpclett.8b03750 ↗
17. Song · Adv. Mater. · 2018 · 30 · 180540910.1002/adma.201805409 ↗
18. Liu · Chem. Mater. · 2017 · 29 · 516810.1021/acs.chemmater.7b00692 ↗
19. Ruan · J. Phys. Chem. Lett. · 2017 · 8 · 385310.1021/acs.jpclett.7b01657 ↗
20. Ruan · Nanoscale · 2017 · 9 · 725210.1039/C7NR02125A ↗
21. Ruan · Nanoscale · 2018 · 10 · 765810.1039/C8NR00883C ↗
22. Tan · ACS Appl. Mater. Interfaces · 2018 · 10 · 378410.1021/acsami.7b17166 ↗
23. Yao · ACS Omega · 2019 · 4 · 915010.1021/acsomega.9b00464 ↗
24. Liu · ACS Nano · 2017 · 11 · 1037310.1021/acsnano.7b05442 ↗
25. Koh · ChemistrySelect · 2016 · 1 · 347910.1002/slct.201600809 ↗
26. Yang · Adv. Mater. · 2019 · 31 · 190076710.1002/adma.201900767 ↗
27. Zhou · Adv. Mater. · 2016 · 28 · 916310.1002/adma.201602651 ↗
28. Yu · Nanoscale · 2019 · 11 · 910310.1039/C8NR10298H ↗
29. Meyns · ACS Appl. Mater. Interfaces · 2016 · 8 · 1957910.1021/acsami.6b02529 ↗
30. Shen · Chem. Commun. · 2018 · 54 · 280410.1039/C8CC00139A ↗
31. Luo · Adv. Funct. Mater. · 2017 · 27 · 160401810.1002/adfm.201604018 ↗
32. Krieg · ACS Energy Lett. · 2018 · 3 · 64110.1021/acsenergylett.8b00035 ↗
33. Pan · Adv. Mater. · 2016 · 28 · 871810.1002/adma.201600784 ↗
34. Dai · Angew. Chem., Int. Ed. · 2018 · 57 · 575410.1002/anie.201801780 ↗
35. Zhang · ACS Nano · 2015 · 9 · 453310.1021/acsnano.5b01154 ↗
36. Shi · Science · 2015 · 347 · 51910.1126/science.aaa2725 ↗
37. Loiudice · Angew. Chem., Int. Ed. · 2017 · 56 · 1069610.1002/anie.201703703 ↗
38. Kim · ACS Nano · 2017 · 11 · 658610.1021/acsnano.6b07617 ↗
39. Huang · Nat. Commun. · 2017 · 8 · 99610.1038/s41467-017-00929-2 ↗
40. Han · ACS Nano · 2018 · 12 · 880810.1021/acsnano.8b05172 ↗
41. Kim · ACS Nano · 2017 · 11 · 658610.1021/acsnano.6b07617 ↗
42. Qiu · ACS Energy Lett. · 2019 · 4 · 151310.1021/acsenergylett.9b00954 ↗
43. Zhang · ACS Appl. Energy Mater. · 2019 · 2 · 333610.1021/acsaem.9b00186 ↗
44. Huang · Nanoscale Horiz. · 2019 · 4 · 92410.1039/C9NH00066F ↗