Impact of Chelating Agent Choice on Growth Kinetics and Defect Chemistry in Sol–Gel-Synthesized Li- and Mn-Rich Layered Cathodes
Source abstract
Abstract
EXAFS. These results highlight that oxygen vacancy mobility during cycling dominates the effects of the initial structural order, where different types of defects are present, and plays a decisive role in governing redox pathways and cycling stability. The selection of the precursor allows tailoring introduction of these defects without postsynthesis treatment. This study provides a comprehensive framework for designing high-performance Li- and Mn-rich layered oxide cathodes by tuning synthesis chemistry to engineer beneficial structural disorder and defect dynamics.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Extraction and Separation Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Materials Chemistry, National Institute of Chemistry, Hajdrihova 19, Ljubljana 1000, Slovenia
Faculty of Chemistry and Chemical technology
University of Ljubljana
ALISTORE-European Research Institute
Elettra-Sincrotrone Trieste S.C.p.A., s.s. 14 km 163.5, Basovizza, Trieste 34149, Italy
Funding
HORIZON EUROPE Research Infrastructures · Horizon 2020 Framework Programme · UK Research and Innovation (UKRI) · Swiss State Secretariat for Education, Research and Innovation (SERI) · Slovenian Research and Innovation Agency
References (70)
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