Highly Selective Separation of cis - over trans -1,2-Dimethylcyclohexane Isomers by Nonporous Adaptive Crystals of Pillar[ n ]arenes
Source abstract
Abstract
The separation of cis – trans isomers is one of the important research fields in chemical industries. In this work, nonporous adaptive crystals (NACs) based on perethylated pillar[ n ]arenes were used for the adsorption and separation of cis - and trans -1,2-dimethylcyclohexane ( cis - G and trans - G ). NACs of perethylated pillar[5]arene ( EtP5 α ) showed no adsorption of cis - G and trans - G, while NACs of perethylated pillar[6]arene ( EtP6 β ) exhibited high selectivity for cis - G either by solid–vapor adsorption or solid–liquid adsorption with the purity of 96.25 and 97.73%, respectively. Meanwhile, EtP6 β can be recycled five times without loss of selectivity, indicating excellent cycling performance of EtP6 β .
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Zeolite Catalysis and Synthesis · Mesoporous Materials and Catalysis · Catalysis for Biomass Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, College of Sciences
Northeastern University
Key Laboratory of Functional Molecular Solids, Ministry of Education, and School of Chemistry and Materials Science
Anhui Normal University
Funding
State Key Laboratory of Heavy Oil Processing · Key Laboratory of Functional Molecular Solids, Ministry of Education of the People's Republic of China · Northeastern University · Natural Science Foundation of Liaoning Province · Fundamental Research Funds for the Central Universities · National Natural Science Foundation of China
References (59)
Show source-provided references
1. 10.1007/s11746-016-2913-710.1007/s11746-016-2913-7 ↗
2. 10.1016/j.tet.2014.11.06710.1016/j.tet.2014.11.067 ↗
3. 10.1016/j.ces.2003.10.00210.1016/j.ces.2003.10.002 ↗
4. 10.1002/(SICI)1099-1581(199608)7:8<711::AID-PAT574>3.0.CO;2-J10.1002/(SICI)1099-1581(199608)7:8<711::AID-PAT574>3.0.CO;2-J ↗
5. 10.1021/acsami.0c2000010.1021/acsami.0c20000 ↗
6. 10.1021/jacs.3c0617510.1021/jacs.3c06175 ↗
7. 10.1038/s41467-024-45592-610.1038/s41467-024-45592-6 ↗
8. 10.1002/anie.20200943610.1002/anie.202009436 ↗
9. 10.1021/acs.iecr.7b0312710.1021/acs.iecr.7b03127 ↗
10. 10.1093/nsr/nwac02310.1093/nsr/nwac023 ↗
11. 10.1021/cr500566610.1021/cr5005666 ↗
12. 10.1126/science.abe019210.1126/science.abe0192 ↗
13. 10.1021/acsami.2c0522310.1021/acsami.2c05223 ↗
14. 10.1038/s41467-021-27929-710.1038/s41467-021-27929-7 ↗
15. 10.1038/s41586-022-05409-210.1038/s41586-022-05409-2 ↗
16. 10.1016/j.seppur.2023.12414410.1016/j.seppur.2023.124144 ↗
17. 10.1021/acs.chemrev.2c0066710.1021/acs.chemrev.2c00667 ↗
18. 10.1021/acsami.2c0433110.1021/acsami.2c04331 ↗
19. 10.1016/j.ccr.2015.12.01010.1016/j.ccr.2015.12.010 ↗
20. 10.1016/j.cej.2018.08.18410.1016/j.cej.2018.08.184 ↗
21. 10.1039/C8CS00919H10.1039/C8CS00919H ↗
22. 10.1016/j.ccr.2019.21304610.1016/j.ccr.2019.213046 ↗
23. 10.1039/C9CC02490E10.1039/C9CC02490E ↗
24. 10.1021/jacs.9b1074110.1021/jacs.9b10741 ↗
25. 10.1016/j.chempr.2020.08.02110.1016/j.chempr.2020.08.021 ↗
26. 10.1039/D1CC00737H10.1039/D1CC00737H ↗
27. 10.1021/acs.chemmater.3c0188810.1021/acs.chemmater.3c01888 ↗
28. 10.1021/acs.cgd.4c0097710.1021/acs.cgd.4c00977 ↗
29. 10.1016/j.chempr.2018.05.01510.1016/j.chempr.2018.05.015 ↗
30. 10.1016/j.cclet.2024.11010210.1016/j.cclet.2024.110102 ↗
31. 10.1007/s11426-022-1477-x10.1007/s11426-022-1477-x ↗
32. 10.1021/acs.cgd.4c0154710.1021/acs.cgd.4c01547 ↗
33. 10.1021/acs.chemrev.5b0076510.1021/acs.chemrev.5b00765 ↗
34. 10.1002/anie.20251928810.1002/anie.202519288 ↗
35. 10.1038/s41467-023-36131-w10.1038/s41467-023-36131-w ↗
36. 10.1021/acsami.1c0710610.1021/acsami.1c07106 ↗
37. 10.1002/anie.20250002210.1002/anie.202500022 ↗
38. 10.1039/D0CS00341G10.1039/D0CS00341G ↗
39. 10.1016/j.xcrp.2024.10230710.1016/j.xcrp.2024.102307 ↗
40. 10.1016/j.cclet.2023.10874010.1016/j.cclet.2023.108740 ↗
41. 10.1021/acs.accounts.8b0025510.1021/acs.accounts.8b00255 ↗
42. 10.1002/anie.20200699910.1002/anie.202006999 ↗
43. 10.1016/j.xcrp.2023.10163710.1016/j.xcrp.2023.101637 ↗
44. 10.1021/acs.chemmater.3c0296710.1021/acs.chemmater.3c02967 ↗
45. 10.1021/acsami.8b0639610.1021/acsami.8b06396 ↗
46. 10.1002/ange.20191196510.1002/ange.201911965 ↗
47. 10.1021/jacs.9b1354810.1021/jacs.9b13548 ↗
48. 10.1039/D3CS00002H10.1039/D3CS00002H ↗
49. 10.1039/D2CS00856D10.1039/D2CS00856D ↗
50. 10.1021/jacs.9b0618810.1021/jacs.9b06188 ↗
51. 10.1039/D0RA09307F10.1039/D0RA09307F ↗
52. 10.1039/c2cc36027f10.1039/c2cc36027f ↗
53. 10.1002/anie.20180899810.1002/anie.201808998 ↗
54. 10.1126/science.aaf245810.1126/science.aaf2458 ↗
55. 10.1016/j.jece.2022.10830010.1016/j.jece.2022.108300 ↗
56. 10.1016/j.jcis.2023.11.06410.1016/j.jcis.2023.11.064 ↗
57. 10.1021/es101312n10.1021/es101312n ↗
58. 10.1016/j.mattod.2021.01.01010.1016/j.mattod.2021.01.010 ↗
59. 10.1002/anie.20210464610.1002/anie.202104646 ↗