journal article·2025-12-17

Thickness-Induced Crystal Orientation Regulation in a Magnetron-Sputtered GaSb Buffer Layer for High-Performance InAs/GaSb Photodetectors

Junhong Lv, Min Zhang, Yujuan Wu, Feng Lin, Shuailong Zhang, Tinglong Liu, Hanbao Liu, Xueqiang Wu, Chunliu Yang, Yanbin Kang, Hua Wei, Zhuochen Duan, Jie Yang, Jiaxian Han, Feng Qiu, Shikun Pu, Hui Feng, Chong Wang

ACS Applied Materials & Interfaces· Volume 17· Issue 50
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Abstract

High Resolution Image Download MS PowerPoint Slide InAs/GaSb photodetectors (PDs) are of significant interest for high-performance infrared detection, driving the demand for low-cost fabrication of high-quality films. Here, we systematically investigate magnetron sputtering of the InAs/GaSb film and the effects of different growth parameters on the film structure and morphology. It was found that an elevated temperature facilitated Sb diffusion in GaSb thin films, leading to compositional stratification. Rapid thermal annealing at 600 °C significantly suppressed Sb diffusion, while spontaneous crystallization led to island-like growth on the film surface. Substrate-induced crystallization, controlled by sputtering time, suppressed spontaneous crystallization and produced a highly crystalline (100)-oriented GaSb film with a smooth surface. The InAs films deposited on the GaSb buffer layer demonstrate significantly enlarged grain size, collectively reducing nonradiative recombination centers. The fabricated InAs/GaSb PDs were tested at room temperature, demonstrating a dark current density of 1.1 × 10 –3 A/cm 2 . Under 1310 and 1550 nm laser illumination, the device exhibited responsivities ( R ) of 1.32 and 3.46 A/W@–1 V, with corresponding specific detectivities ( D *) of 7.04 × 10 10 and 1.84 × 10 11 Jones, respectively. This work presents a promising approach for fabricating high-performance III–V heterojunction PDs at room temperature by using magnetron sputtering.
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Research context

OpenAlex topics: Advanced Semiconductor Detectors and Materials · Semiconductor Quantum Structures and Devices · solar cell performance optimization

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Affiliations

Yunnan Key Laboratory for Micro/Nano Materials & Technology, School of Materials and Energy

Yunnan University

Yunnan Zhongke Xinyuan Crystal Materials Co., Ltd.

Funding

Major Science and Technology Projects in Yunnan Province · National Natural Science Foundation of China · Science and Technology Special Projects of Southwest United Graduate School and Innovative Team of Yunnan Province · Yunnan Province Fundamental Research Projects · Xingdian Talent Plan of Yunnan Province · Xingdian Creative Industry Talent Project of Yunnan Province

References (40)

Show source-provided references
1. 10.1021/acsphotonics.4c0128110.1021/acsphotonics.4c01281 ↗
2. 10.1021/acsami.3c1271410.1021/acsami.3c12714 ↗
3. 10.1002/adma.20190249210.1002/adma.201902492 ↗
4. 10.1016/j.mattod.2022.11.00310.1016/j.mattod.2022.11.003 ↗
5. 10.1002/adma.20231012210.1002/adma.202310122 ↗
6. 10.1038/s41377-022-00850-410.1038/s41377-022-00850-4 ↗
7. 10.1002/adfm.20180051210.1002/adfm.201800512 ↗
8. 10.1021/acs.chemrev.9b0007510.1021/acs.chemrev.9b00075 ↗
9. 10.1016/j.apsusc.2024.15970710.1016/j.apsusc.2024.159707 ↗
10. 10.1016/j.jallcom.2023.17148510.1016/j.jallcom.2023.171485 ↗
11. 10.1063/1.499907710.1063/1.4999077 ↗
12. 10.1002/adma.20230184210.1002/adma.202301842 ↗
13. 10.1021/acsnano.4c0083910.1021/acsnano.4c00839 ↗
14. 10.1016/j.apsusc.2016.12.11410.1016/j.apsusc.2016.12.114 ↗
15. 10.1016/S0169-4332(00)00227-010.1016/S0169-4332(00)00227-0 ↗
16. 10.1016/j.apsusc.2018.08.06410.1016/j.apsusc.2018.08.064 ↗
17. 10.1016/j.apsusc.2025.16297510.1016/j.apsusc.2025.162975 ↗
18. 10.1063/5.014099210.1063/5.0140992 ↗
19. 10.1016/S1005-0302(12)60033-410.1016/S1005-0302(12)60033-4 ↗
20. 10.1063/1.500010010.1063/1.5000100 ↗
21. 10.1016/j.apsusc.2015.05.18410.1016/j.apsusc.2015.05.184 ↗
22. 10.1116/6.000181010.1116/6.0001810 ↗
23. 10.1021/nn304151j10.1021/nn304151j ↗
24. 10.1016/j.jcrysgro.2008.07.04810.1016/j.jcrysgro.2008.07.048 ↗
25. 10.1016/j.spmi.2015.04.02210.1016/j.spmi.2015.04.022 ↗
26. 10.1063/5.020974010.1063/5.0209740 ↗
27. 10.1021/acsami.3c1097910.1021/acsami.3c10979 ↗
28. 10.1016/j.apsusc.2017.03.09910.1016/j.apsusc.2017.03.099 ↗
29. 10.1016/j.jcrysgro.2016.11.08210.1016/j.jcrysgro.2016.11.082 ↗
30. 10.1016/j.tsf.2007.07.04910.1016/j.tsf.2007.07.049 ↗
31. 10.1007/s10853-023-08735-610.1007/s10853-023-08735-6 ↗
32. 10.1021/acsami.2c1773810.1021/acsami.2c17738 ↗
33. 10.1088/1361-6641/aa637710.1088/1361-6641/aa6377 ↗
34. 10.1142/S021797922050097610.1142/S0217979220500976 ↗
35. 10.1016/j.apsusc.2024.16154310.1016/j.apsusc.2024.161543 ↗
36. 10.1038/3504052610.1038/35040526 ↗
37. 10.1016/j.vacuum.2024.11344510.1016/j.vacuum.2024.113445 ↗
38. 10.1016/j.jcrysgro.2021.12649910.1016/j.jcrysgro.2021.126499 ↗
39. 10.1021/acsanm.4c0255910.1021/acsanm.4c02559 ↗
40. 10.1021/acsphotonics.4c0045010.1021/acsphotonics.4c00450 ↗