A Substrate-Independent Lift-Off Approach for Patterning Functional Surfaces

A lift-off method for creating multifunctional patterned surfaces has been devised. It entails consecutive pulsed plasmachemical deposition of a reactive bottom layer and a protective top release layer. By way of example, a bottom/top layer combination comprising pulsed plasma deposited poly(glycidyl methacrylate)/poly(pentafluorostyrene) has been shown to display selective adhesive lift-off of the latter. Application of a prepatterned adhesive template yields well-defined arrays of reactive epoxide functionality surrounded by a passive fluoropolymer background or vice versa.