Highly (001)-Textured Tetragonal BiFeO₃ Film and Its Photoelectrochemical Behaviors Tuned by Magnetic Field

Highly (001)-textured BiFeO 3 film in tetragonal phase (T-BFO) with a giant c/a ratio was first obtained on quartz/polycrystalline ITO substrate. Our results indicate that the polycrystalline ITO layer with small surface roughness is a critical point to control the growth of T-BFO structure. It should be ascribed to the fact that a Bi-rich phase interlayer (∼5 nm) could be formed on ITO, which acted as a crystal seed layer and thus induced the growth of (001)-textured T-BFO structure. The observed weak room temperature ferromagnetism should be attributed to Fe valence change. Open circuit potential measurements under 360 μW/cm 2 full spectra irradiation show that the open circuit potential and the lifetime of photo-induced carriers increased under applied magnetic field, which reveals that the applied magnetic field can manipulate the photo electrochemical behaviors of BFO film. Our findings offer a simple way to fabricate highly (001)-textured T-BFO film, which make it desirable to obtain extensive applications for these oriented BFO films.