journal article·2023-12-01

In Situ Etching of Multifunctional Three-Dimensional Interfacial Layers for the Construction of Porous Zn Anodes with Enhanced Surface Textures

Zhipeng Shao, Kaiping Zhu, Lin Lin, Shizhuo Liu, Peng Yang, Yaxiong Zhang, Gengde Guo, Chaowei Li, Wenhui Wang, Qichong Zhang, Changjin Wan, Guo Hong, Yagang Yao

Publisher page

Abstract

Aqueous Zn-ion batteries offer the advantages of greater security and lower fabrication costs over their lithium-ion counterparts. However, their further advancement and practical application are hindered by the drastic decay in their performance due to the uncontrollable dendrite growth on Zn anodes. In this study, we fabricated a versatile three-dimensional (3D) interfacial layer (3D PVDF–Zn(TFO) 2 (PVDF: poly(vinylidene fluoride); TFO: trifluoromethanesulfonate), which simultaneously formed porous Zn-metal anodes (PZn) with an enhanced (002) texture, via a in situ etching scheme. The 3D PVDF–Zn(TFO) 2 @PZn symmetrical cells leverage the advantages of surface coating and 3D porous architectures to yield extra-long cyclic lifetimes of over 5300 h (0.1 mA cm –2 ). The fabricated anodes were found to be compatible with MnO 2 cathodes, and the resulting full batteries delivered an outstanding capacity of 336 mAh g –1 at 0.1 A g –1 and exhibited impressive long-term reversibility with a capacity retention of 78.7% for 2000 cycles. The proposed coating strategy is viable for developing porous structures with cutting-edge designs and for textured surface engineering.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced battery technologies research · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China

Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, P. R. China

Henan Key Laboratory of New Optoelectronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, China

Key Laboratory of Multifunctional Nanomaterials and Smart Systems, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China

School of Electronic Science & Engineering and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China

Department of Materials Science and Engineering & Center of Super-Diamond and Advanced Films, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon 999077, Hong Kong SAR ,China

Funding

National Key Research and Development Program of China · Natural Science Foundation of Jiangsu Province

References (60)

Show source-provided references
1. 10.1021/acs.chemrev.9b0053110.1021/acs.chemrev.9b00531 ↗
2. 10.1038/s41563-018-0063-z10.1038/s41563-018-0063-z ↗
3. 10.1021/acs.chemrev.2c0028910.1021/acs.chemrev.2c00289 ↗
4. 10.1126/science.aax687310.1126/science.aax6873 ↗
5. 10.1021/acsenergylett.0c0123510.1021/acsenergylett.0c01235 ↗
6. 10.1021/jacs.0c1175310.1021/jacs.0c11753 ↗
7. 10.1039/D1EE03377H10.1039/D1EE03377H ↗
8. 10.1021/acsami.1c0838810.1021/acsami.1c08388 ↗
9. 10.1016/j.joule.2018.11.00210.1016/j.joule.2018.11.002 ↗
10. 10.1002/adma.20230019510.1002/adma.202300195 ↗
11. 10.1002/anie.20230270110.1002/anie.202302701 ↗
12. 10.1002/aenm.20210323110.1002/aenm.202103231 ↗
13. 10.1002/anie.20221555210.1002/anie.202215552 ↗
14. 10.1002/ange.20210575610.1002/ange.202105756 ↗
15. 10.1002/aenm.20200392710.1002/aenm.202003927 ↗
16. 10.1002/adfm.20220828810.1002/adfm.202208288 ↗
17. 10.1002/adma.20210513310.1002/adma.202105133 ↗
18. 10.1002/adma.20210693710.1002/adma.202106937 ↗
19. 10.1002/advs.20210030910.1002/advs.202100309 ↗
20. 10.1002/adfm.20210385010.1002/adfm.202103850 ↗
21. 10.1002/adma.20200175510.1002/adma.202001755 ↗
22. 10.1002/anie.20230445410.1002/anie.202304454 ↗
23. 10.1038/s41467-022-35630-610.1038/s41467-022-35630-6 ↗
24. 10.1016/j.xcrp.2020.10011910.1016/j.xcrp.2020.100119 ↗
25. 10.1016/j.ensm.2021.06.00210.1016/j.ensm.2021.06.002 ↗
26. 10.1021/acsnano.1c0593410.1021/acsnano.1c05934 ↗
27. 10.1002/aenm.20230093210.1002/aenm.202300932 ↗
28. 10.1002/smll.20220471310.1002/smll.202204713 ↗
29. 10.1016/j.ensm.2022.06.05410.1016/j.ensm.2022.06.054 ↗
30. 10.1016/j.ensm.2020.04.03810.1016/j.ensm.2020.04.038 ↗
31. 10.1002/aenm.20220325410.1002/aenm.202203254 ↗
32. 10.1021/acsnano.2c1135710.1021/acsnano.2c11357 ↗
33. 10.1016/j.cej.2021.12858410.1016/j.cej.2021.128584 ↗
34. 10.1007/s12034-017-1390-410.1007/s12034-017-1390-4 ↗
35. 10.1016/j.nanoen.2016.12.03710.1016/j.nanoen.2016.12.037 ↗
36. 10.1021/la703540710.1021/la7035407 ↗
37. 10.1002/macp.20080050110.1002/macp.200800501 ↗
38. 10.1002/ange.20230727110.1002/ange.202307271 ↗
39. 10.1021/acsenergylett.0c0179210.1021/acsenergylett.0c01792 ↗
40. 10.1016/j.nanoen.2018.12.08610.1016/j.nanoen.2018.12.086 ↗
41. 10.1039/C9EE00596J10.1039/C9EE00596J ↗
42. 10.1002/smll.20230409410.1002/smll.202304094 ↗
43. 10.1149/1.139315610.1149/1.1393156 ↗
44. 10.1016/S0378-7753(02)00310-510.1016/S0378-7753(02)00310-5 ↗
45. 10.1016/j.jpowsour.2010.04.06410.1016/j.jpowsour.2010.04.064 ↗
46. 10.1002/adma.20200741610.1002/adma.202007416 ↗
47. 10.1021/acsenergylett.3c0101710.1021/acsenergylett.3c01017 ↗
48. 10.1021/acsenergylett.1c0063810.1021/acsenergylett.1c00638 ↗
49. 10.1002/adma.20220790810.1002/adma.202207908 ↗
50. 10.1002/adfm.20221453810.1002/adfm.202214538 ↗
51. 10.1016/j.mtener.2022.10109710.1016/j.mtener.2022.101097 ↗
52. 10.1002/anie.20230845410.1002/anie.202308454 ↗
53. 10.1002/adfm.20220775110.1002/adfm.202207751 ↗
54. 10.1002/adfm.20200241410.1002/adfm.202002414 ↗
55. 10.1002/anie.20190783010.1002/anie.201907830 ↗
56. 10.1039/C4RA15536J10.1039/C4RA15536J ↗
57. 10.1021/acsnano.9b0491610.1021/acsnano.9b04916 ↗
58. 10.1002/smll.20190454510.1002/smll.201904545 ↗
59. 10.1021/jacs.7b0447110.1021/jacs.7b04471 ↗
60. 10.1016/j.ensm.2017.06.01210.1016/j.ensm.2017.06.012 ↗