Recovery of Pure Methanol from Humid Gas Using Mn–Co Prussian Blue Analogue

Conventional methanol recovery and purification processes are highly energy-intensive; processes using selective adsorbents that consume low energy are preferable. However, conventional adsorbents have low methanol selectivity under humid conditions. In this study, we develop a selective methanol adsorbent, manganese hexacyanocobaltate (MnHCC), which enables the efficient removal of methanol from waste gas and its subsequent reuse. MnHCC adsorbs 4.8 mmol-methanol/g-adsorbent at 25 °C in a humid gas containing 5000 ppmv of methanol, which is five times higher than the adsorption capacity of activated carbon (0.86 mmol/g). Although MnHCC exhibits the simultaneous adsorption of methanol and water, it has a higher adsorption enthalpy for methanol. Thus, pure methanol (95%) was recovered via thermal desorption at 150 °C after dehydration. The estimated energy of this recovery was 18.9 MJ/kg-methanol, approximately half that of existing mass production methods. MnHCC is reusable and stable even after 10 cyclic experiments. Consequently, MnHCC has the potential to contribute to both the recycling of methanol from waste gas and its low-cost purification.