journal article·2024-10-05

Hierarchically Structured Cellulose Acetate@Silk Protein Membrane with Enhanced Mechanical and Electromagnetic Interference Shielding Performances

Xinyu Yao, Yitan Li, Shengjie Li, Yaoqieyu Song, Jiapeng Zhang, Linglu Yang, Zhi Hong Hang, Xiaohua Zhang, Zhaohui Yang

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Abstract

Compared to conventional fibers, electrospun porous nanofibers with hierarchical structures often involve additional active sites, interfaces, and internal spaces which boost the performances of functional materials. Here in this study, coaxial composite cellulose acetate@silk fibroin (CA@SF) fibrous membranes are constructed through an electrostatic spinning technique combining solvent-induced phase separation. Hierarchical core-shell structures on the fibers are achieved, which significantly increases the surface area and benefits the mechanical property, flux, as well as the electroless deposition of Ag nanoparticles. The total electromagnetic shielding efficiency of the sandwiched hierarchical CA@SF@Ag composite membrane with a thickness of only 100 μm reaches up to 100 dB, surpassing around 82% beyond nonhierarchical ones. To be noticed, when post-treated by ethanol, the membrane enables an enhanced tensile strength of up to 10 MPa with a thickness of only 50 μm. Our findings pave the way to the application of electrospun fiber membranes in the field of ultrathin electromagnetic shielding films.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electromagnetic wave absorption materials · Advanced Sensor and Energy Harvesting Materials · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Physical Science and Technology, Soochow University, Suzhou 215006, P. R. China

Center for Soft Condensed Matter Physics and Interdisciplinary Research, Soochow University, Suzhou 215006, P. R. China

National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, P. R. China

Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan 250100, Shandong, P. R. China

Suzhou NanomicroTechnology Co., Ltd., 2 Baichuan Street, Suzhou Industrial Park, Suzhou 215123, P. R. China

Funding

Soochow University · Shandong University · National Natural Science Foundation of China · Priority Academic Program Development of Jiangsu Higher Education Institutions · Specially Appointed Professor Plan in Jiangsu Province

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