Estimating Internal Stress of an Alteration Layer Formed on Corroded Boroaluminosilicate Glass through Spectroscopic Ellipsometry Analysis
Source abstract
Abstract
Aqueous corrosion of glass may result in the formation of an alteration layer in the glass surface of which chemical composition and network structure are different from those of the bulk glass. Since corrosion occurs far below the glass-transition temperature, the alteration layer cannot fully relax to the new structure with the lowest possible energy. Molecular dynamics simulations suggested that such a network will contain highly strained chemical bonds, which can be manifested as a stress in the alteration layer. Common techniques to measure stress in thin films or surface layers were found inadequate for thick monolithic glass samples corroded in water. Here, we explored the use of spectroscopic ellipsometry to test the presence of internal stress in the alteration layer formed by aqueous corrosion of glass. A procedure for analyses of spectroscopic ellipsometry data to determine birefringence in the alteration layer was developed. Findings with the established fitting procedure suggested that a stress builds up in the corroded surface layer of a boroaluminosilicate glass if there is a change in relative humidity, pH, or electrolyte concentration of the environment to which the glass surface is exposed. A similar process may occur in other types of glass, and it may affect the surface properties of corroded glass objects.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Glass properties and applications · Material Dynamics and Properties · Silicon Nanostructures and Photoluminescence
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, United States
Department of Chemical Engineering and Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802, United States
Department of Mechanical Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, United States
Key Laboratory of Testing Technology for Manufacturing Process, Ministry of Education, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China
Şişecam Science and Technology Center, Şişecam Str., No:2 Çayırova, Kocaeli 41400, Turkey
Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States
Department of Physics and Astronomy, The University of Toledo, Toledo, Ohio 43606, United States
Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, Ohio 43606, United States
CEA, DES, ISEC, DE2D, University of Montpellier, Marcoule, Bagnols sur Cèze F-30207, France
Funding
Basic Energy Sciences
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