Refillable Fuel-Loading Microshell Motors for Persistent Motion in a Fuel-Free Environment

Artificial micro-/nanomotors that harvest environmental energy to move require energy surroundings; thus, their motion generally occurs in fuel solutions or under the real-time stimuli of external energy sources. Herein, inspired by vehicles, a refillable fuel-loading micromotor is proposed based on a 2 μm hemispherical multimetallic shell using catalase or platinum on its concave surface as the engine and the bowl structure as the fuel tank. H2O2 fuel is drawn into the microbowl by capillary action and restricted inside the bowl space through a self-generated O2 bubble cap on the microshell mouth. The periodic growth and burst of the O2 cap cause the enhanced diffusion motion of micromotors. This motion behavior can last for at least 30 min in a fuel-free environment with one H2O2 fueling. Additionally, the micromotor can be refilled repeatedly to achieve permanent motion. This demonstration of a refillable fuel-loading micromotor provides a model design of an energy built-in micromotor.