DataVXACS Applied Materials & InterfacesPaper
journal article·2019-05-22

Biofouling-Resistant Porous Membranes with a Precisely Adjustable Pore Diameter via 3D Polymer Grafting

Hidenori Kuroki, Alexey Gruzd, Igor Tokarev, Taras Patsahan, Jaroslav Ilnytskyi, Karsten Hinrichs, Sergiy Minko

ACS Applied Materials & Interfaces· Volume 11· Issue 20
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Source abstract

Abstract

A facile route to biofouling-resistant porous thin-film membranes that can be fine-tuned for specific needs in diverse bioseparation, mass flow control, sensors, and drug delivery applications is reported. The proposed approach is based on combining two distinct macromolecular systems-a cross-linked poly(2-vinyl pyridine) network and a 3D-grafted polyethylene oxide (PEO) layer-in one robust porous material whose porosity can be adjusted within a wide range, covering the macroporous and mesoporous size regimes. Notably, this reconfigurable material maintains its antifouling properties throughout the entire range of pore size configurations because of a dense surface carpet of PEO chains with self-healing properties that are immobilized both onto the surface and inside the polymer network through what was termed 3D grafting. Experimental results are supplemented by computer simulations of a coarse-grained model of a porous membrane that shows qualitatively similar pore swelling behavior.
Source: openalex_inverted_index · Quality: baseline

Research context

Polymers

OpenAlex topics: Polymer Surface Interaction Studies · Block Copolymer Self-Assembly · Electrospun Nanofibers in Biomedical Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry and Biomolecular Science, Clarkson University, Potsdam, New York 13699-5810, United States

Laboratory for Chemistry and Life Science, Tokyo Institute of Technology, R1-17, 4259 Nagatsuta, Midori-ku, Yokohama, Kanagawa 226-8503, Japan

Nanostructured Materials Lab, University of Georgia, Athens, Georgia 30602, United States

Department of Computer Simulations of Many-Particle Systems, Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, Lviv 79011, Ukraine

Leibniz-Institut für Analytische Wissenschaften—ISAS—e.V., 12489 Berlin, Germany

Funding

Bundesministerium f?r Bildung und Forschung · European Regional Development Fund · Japan Society for the Promotion of Science · Division of Materials Research · Ministerium f?r Innovation, Wissenschaft und Forschung des Landes Nordrhein-Westfalen · Regierende B?rgermeister von Berlin - Senatskanzlei Wissenschaft und Forschung

References (45)

Show source-provided references
1. 10.1016/j.polymer.2006.01.08410.1016/j.polymer.2006.01.084 ↗
2. 10.1002/adma.20100016510.1002/adma.201000165 ↗
3. 10.1016/j.memsci.2010.03.04610.1016/j.memsci.2010.03.046 ↗
4. 10.1146/annurev-matsci-070511-15504410.1146/annurev-matsci-070511-155044 ↗
5. 10.1002/anie.20171027210.1002/anie.201710272 ↗
6. 10.1039/c7ta07054c10.1039/c7ta07054c ↗
7. 10.1021/acsami.8b2080210.1021/acsami.8b20802 ↗
8. 10.1021/nn200484v10.1021/nn200484v ↗
9. 10.1016/j.memsci.2015.11.03810.1016/j.memsci.2015.11.038 ↗
10. 10.1002/app.4703810.1002/app.47038 ↗
11. 10.1002/marc.20170036410.1002/marc.201700364 ↗
12. 10.1021/acsami.8b0958010.1021/acsami.8b09580 ↗
13. 10.1021/acsmacrolett.7b0027810.1021/acsmacrolett.7b00278 ↗
14. 10.1021/la970866r10.1021/la970866r ↗
15. 10.1002/anie.20046268710.1002/anie.200462687 ↗
16. 10.1021/la060813m10.1021/la060813m ↗
17. 10.1016/j.memsci.2010.01.05210.1016/j.memsci.2010.01.052 ↗
18. 10.1016/j.memsci.2011.04.02810.1016/j.memsci.2011.04.028 ↗
19. 10.1016/0376-7388(95)00140-210.1016/0376-7388(95)00140-2 ↗
20. 10.1021/ma049954q10.1021/ma049954q ↗
21. 10.1021/ja060880310.1021/ja0608803 ↗
22. 10.1039/c2sm26562a10.1039/c2sm26562a ↗
23. 10.1021/ma960519910.1021/ma9605199 ↗
24. 10.1021/ja012648x10.1021/ja012648x ↗
25. 10.1002/adfm.20120125110.1002/adfm.201201251 ↗
26. 10.1016/j.jconrel.2004.02.02610.1016/j.jconrel.2004.02.026 ↗
27. 10.1021/acsami.7b0874010.1021/acsami.7b08740 ↗
28. 10.1039/c5tb02368h10.1039/c5tb02368h ↗
29. 10.1016/j.memsci.2018.01.03910.1016/j.memsci.2018.01.039 ↗
30. 10.1016/s0142-9612(00)00343-410.1016/s0142-9612(00)00343-4 ↗
31. 10.1021/bm060276k10.1021/bm060276k ↗
32. 10.1021/la902110j10.1021/la902110j ↗
33. 10.1002/adfm.20130036310.1002/adfm.201300363 ↗
34. 10.1002/adma.20060128810.1002/adma.200601288 ↗
35. 10.1021/ma062821f10.1021/ma062821f ↗
36. 10.1002/adma.20080161010.1002/adma.200801610 ↗
37. 10.1002/adma.20070288510.1002/adma.200702885 ↗
38. 10.1021/la049359h10.1021/la049359h ↗
39. 10.1021/la901219f10.1021/la901219f ↗
40. 10.1063/1.172637310.1063/1.1726373 ↗
41. 10.1021/acsami.5b0141610.1021/acsami.5b01416 ↗
42. 10.1063/1.47478410.1063/1.474784 ↗
43. 10.1063/1.359256210.1063/1.3592562 ↗
44. 10.5488/cmp.16.1360610.5488/cmp.16.13606 ↗
45. 10.1021/jp075720810.1021/jp0757208 ↗