journal article·2015-07-29

Conjugated Polymers As Molecular Gates for Light-Controlled Release of Gold Nanoparticles

Maria Sanromán-Iglesias, Kai A. I. Zhang, Andrey Chuvilin, Charles H. Lawrie, Marek Grzelczak, Luis M. Liz-Marzán

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Abstract

The remote release of nano-objects from a container is a promising approach to transduce chemical events into an optical signal. The major challenge in the development of such a system involves the use of a suitable molecular gate that retains aggregated particles and releases them upon applying an external stimulus. We show proof-of-concept experiments for the release of gold nanoparticles into an aqueous solution upon photodegradation of conjugated polymer thin films. Gold nanoparticles thus transduce light-induced chemical events into an amplified optical signal with a release rate of 2.5 nM per hour, which can be readily detected by the naked eye.
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Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Molecular Communication and Nanonetworks · Advanced biosensing and bioanalysis techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CIC biomaGUNE, Paseo de Miramón 182, 20009 Donostia-San Sebastián, Spain

Oncology Area, Biodonostia Research Institute, Donostia-San Sebastián, Spain

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

CIC nanoGUNE Consolider, Avenida de Tolosa 76, 20018 Donostia-San Sebastián, Spain

Ikerbasque, Basque Foundation for Science, 48013 Bilbao, Spain

Funding

Instituto de Salud Carlos III · Ekonomiaren Garapen eta Lehiakortasun Saila, Eusko Jaurlaritza · Ministerio de Economía y Competitividad

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