journal article·2020-06-22Open access

LaCrO3-Coated La0.6Sr0.4Co0.2Fe0.8O3−δ Core–Shell Structured Cathode with Enhanced Cr Tolerance for Intermediate-Temperature Solid Oxide Fuel Cells

Peng Qiu, Xin Yang, Lu Zou, Tianyu Zhu, Zhihao Yuan, Lichao Jia, Jian Li, Fanglin Chen

Abstract

La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) is a common cathode material for intermediate-temperature solid oxide fuel cells because of its excellent oxygen reduction reaction catalytic activity. However, the Cr-poisoning effect is a severe issue, causing electrochemical performance degradation. For the development of a LSCF-based cathode with excellent Cr tolerance, a LaCrO3-coated LSCF core–shell structured (LCr@LSCF) cathode was prepared via the solution infiltration method. After the cathode was coated with a LCr shell, the long-term stability and Cr tolerance were obviously improved, at the price of sacrificing some electrochemical performance. The development of a LCr@LSCF cathode with eye-catching Cr tolerance is of great significance to the commercialization of LSCF.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Reactor & Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430073, China

School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

Center for Fuel Cell Innovation, School of Materials Science and Engineering, State Key Lab of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, China

Funding

Ministry of Science and Technology of the People's Republic of China · U.S. Department of Energy · National Natural Science Foundation of China

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